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THERMOCHEMISTRY

This chapter covers the basic principles of thermodynamics, including the laws of conservation of energy, spontaneous processes, entropy, and the second and third laws of thermodynamics.

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THERMOCHEMISTRY

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  1. THERMOCHEMISTRY Prepared by: Nor FatihahbintiNawi Matrix no: A132797 Programme: sarjanamudapendidikandengankepujian (mathematics)

  2. CHAPTER OUTLINE 18.1 INTRODUCTION TO THERMODYNAMICS 18.2 SPONTANEOUS PROCESSES 18.3 ENTROPY (S) 18.4 THE SECOND LAW OF THERMODYNAMICS 18.4 THE THIRD LAW OF THERMODYNAMICS FURTHER INFORMATION

  3. 6.1 INTRODUCTION TO THERMODYNAMICS • The First Law of Thermodynamics • Based on the law of conservation of energy , states that energy can be converted from one to another but cannot be created or destroyed. • Therefore the total energy of the universe is a constant. • Test the validity of first law by measuring the change in the internal energy. E = Ef – Ei E: energy change Ef: final energy Ei: initial energy

  4. 6.1 INTRODUCTION TO THERMODYNAMICS • The Second Law of Thermodynamics • Explain why chemical processes tend to favor one direction • The Third Law of Thermodynamics • An extension of the second law

  5. 18.2 SPONTENUOS PROCESSES • A reaction that does occur under the given set of condition • The processes occur spontaneously in one direction cannot under the same condition. • Examples of physical and chemical processes in every day: • A waterfall runs downhill but never up spontaneously • Heat flows from a hotter object to a colder one, but the reverse never happens spontaneously. • Iron exposed to water and oxygen forms rust, but rust does not spontaneously change back to iron.

  6. 18.2 SPONTENUOS PROCESSES

  7. 18.3 ENTROPY (S) • A measure of how spread out or dispersed the energy of a system is among the different possible ways that system can contain energy. • Entropy can be thought of as a measure of the randomness of a system. • It is related to the various modes of motion in molecules. • Therefore, S = SfinalSinitial

  8. 18.3 ENTROPY (S) • For a process occurring at constant temperature (an isothermal process): qrev= the heat that is transferred when the process is carried out reversibly at a constant temperature. T = temperature in Kelvin.

  9. 18.3 ENTROPY (S) • STANDARD ENTROPY • Entropy is obtained by calorimetric method. • These are molar entropy values of substances in their standard states. • Standard entropies tend to increase with increasing molar mass.

  10. 18.3 ENTROPY (S) • CHANGES IN ENTROPY • A system with fewer microstates(smaller W) among which to spread its energy(small dispersal) has a lower entropy. • A system with more microstates (large W) among which to spread its energy (large dispersal) has a higher entropy.

  11. 18.4 THE SECOND LAW OF THERMODYNAMICS • The entropy of the universe increases in a spontaneous process and remains unchanged in an equilibrium process. • Spontaneous process: • Equilibrium process:

  12. 18.4 THE THIRD LAW OF THERMODYNAMICS • The entropy of a perfect crystallinessubtances is zero at the absolute zero of temperature.

  13. 18.4 THE THIRD LAW OF THERMODYNAMICS • Entropy: Smiles for stab wounds 2004 No stereotypes, labels, or genres can rationalize this. Fueled by the decay of the world, order and chaos unite, Entropy is born... Music to make your head explode

  14. FURTHER INFORMATION • You can get more information on this topic by other power point presentation as below: http://search.sweetim.com/search.asp?src=6&q=thermodynamic+powerpoint+presentation

  15. THE END THANK YOU

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