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States of Matter. Chap. 13. Gases. State of matter in which particles are separated by large distances. Gases. Gas properties. Gases. Gas properties. Gases have mass. Gases. Gas properties. Gases have mass Gases occupy space. Gases. Gas properties. Gases have mass
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States of Matter Chap. 13
Gases State of matter in which particles are separated by large distances.
Gases • Gas properties
Gases • Gas properties • Gases have mass
Gases • Gas properties • Gases have mass • Gases occupy space
Gases • Gas properties • Gases have mass • Gases occupy space • Gases completely fill their containers
Gases • Gas properties • Gases have mass • Gases occupy space • Gases completely fill their containers • Gases have low density
Gases • Gas properties • Gases can be compressed & expanded
Gases • Gas properties • Gases can be compressed & expanded • Gases exert pressure
Gases • Gas properties • Gases can be compressed & expanded • Gases exert pressure • Gases diffuse & effuse
Gases • The Kinetic Molecular Theory (KMT) An explanation of why gases behave the way they do.
Gases • The Kinetic Molecular Theory (KMT) • Gases consist of tiny particles in constant motion
Gases • The Kinetic Molecular Theory (KMT) • Gases consist of tiny particles in constant motion • Gas particles travel in straight line until they collide with other particles or the container
Gases • The Kinetic Molecular Theory (KMT) • Gas particles are separated by relatively large spaces
Gases • The Kinetic Molecular Theory (KMT) • Gas particles are separated by relatively large spaces • The kinetic energy of gas particles depends on the temperature KE = ½ mv2
Gases • Diffusion Spreading out of particles (high to low concentration)
Gases • Diffusion • Diffusion depends on how fast particles travel.
Gases • Diffusion • Diffusion depends on how fast particles travel. • Cold particles travel _____ than warm particles.
Gases • Diffusion • Diffusion depends on how fast particles travel. • Cold particles travel slower than warm particles. • Small particles travel _____ than small particles.
Gases • Diffusion • Diffusion depends on how fast particles travel. • Cold particles travel slower than warm particles. • Small particles travel faster than small particles.
Gases • Diffusion • Diffusion depends on how fast particles travel. • Graham found that the diffusion rate was inversely proportional to the square root of the molar mass.
Graham’s Law √ RateA Molar mass B = RateB Molar mass A
Measuring Gases • Gas Pressure
Measuring Gases • Gas Pressure • Pressure is force per area P = F/A
Measuring Gases • Gas Pressure • Pressure is force per area • The atmosphere exerts pressure
Measuring Gases • Gas Pressure • Pressure is force per area • The atmosphere exerts pressure • Pressure units
Equivalent Pressure units 1.00 atmosphere (atm) 101325 pascals (Pa) 101.325 kilopascals (kPa) 760 __________ (mm Hg) 760 torricelli (torr) 14.7 pounds per square inch (___)
Measuring Gases • Gas Pressure • Pressure is force per area • The atmosphere exerts pressure • Pressure units • Converting pressure
Self Check – Ex. 1 A container of gas has a pressure of 50 atm. What is this pressure in psi?
Self Check – Ex. 2 What is the pressure in pascals of a gas sample that is 140 kPa?
Measuring Gases • Instruments
Measuring Gases • Instruments • Barometer Measures atmospheric pressure.
Measuring Gases • Instruments • Barometer • Mercury Image: Dr. Leon L. Combs Atmosphere ‘holds up’ a column of mercury
Measuring Gases • Instruments • Barometer • Mercury • Aneroid Image: Australian BOM Name means ‘without liquid’
CO2 22 mm Hg • Measuring Gases • Instruments • Barometer • Manometer Measures pressure of an enclosed gas
Measuring Gases • Instruments • Barometer • Manometer • Example calculations
Self Check – Ex. 3 What is the pressure of the CO2 gas pictured below? Atmospheric pressure is 755 mmHg. CO2 22 mm Hg
65 mm He Hg Self Check – Ex. 4 What is the pressure of the helium gas pictured below? Atmospheric pressure is 1.1 atm.