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GLYCEROL: TERMS, PROPERTIES, CONSTANTS , FORMULAS

Comprehensive guide on glycerol's key data, including properties, formulas, and constants. Useful for pharmaceutical and research purposes. Covers terminology and structures related to glycerol.

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GLYCEROL: TERMS, PROPERTIES, CONSTANTS , FORMULAS

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  1. Saratov State University Optics & Biomedical Physics Department GLYCEROL:TERMS, PROPERTIES,CONSTANTS, FORMULAS Mikhail M. Stolnitz Saratov State University, Saratov, Russia

  2. Saratov Fall Meeting 2016

  3. Itroduction “Our aim in this compilation is to present the more important of the available data on glycerine and its aqueous solutions for ready reference...” [1] Saratov Fall Meeting 2016

  4. Nomenclature Glycerol is a simple polyol (sugar alcohol) compound. It is a colorless, odorless, viscous liquid that is widely used in pharmaceutical formulations. Glycerol has three hydroxyl groups that are responsible for its solubility in water and its hygroscopic nature [2]. IUPAC name: propane-1,2,3-triol Other names: glycerin, glycerine, propanetriol, 1,2,3-trihydroxypropane Glycerine (sometimes glycerin) is the term most often applied to the commercial product, which usually contains a small percentage of water. Glycerol (chemically, also 1,2,3-propanetriol) refers to the chemical compound and content in a formulation. specifically to the trihydric alcohol C3H5(OH)3. Structure of glycerol, skeletal formula Saratov Fall Meeting 2016

  5. Glycerolin Internet DataBases Saratov Fall Meeting 2016

  6. Glycerolin Internet DataBases Saratov Fall Meeting 2016

  7. References Physical Properties of Glycerine and Its Solutions. ‒ New York: Glycerine Producers' Association, 1963. ‒ 27 с. From Wikipedia, the free encyclopedia. https://en.wikipedia.org/wiki/Glycerol Quantities, Units and Symbols in Physical Chemistry. ‒ 3d Ed. ‒ Cambridge: IUPAC & RSC Publishing, 2007. ‒ 251 p. Abbas S. A., Sharma V. K., Patapoff T. W., Kalonia D. S. Solubilities and Transfer Free Energies of Hydrophobic Amino Acids in Polyol Solutions: Importance of the Hydrophobicity of Polyols // Journal of Pharmaceutical Sciences. ‒ 2011. ‒ Vol. 100, № 8. ‒ P. 3096-3104. Abe S., Takahashi H. A comparative study of the effects of dimethylsulfoxide and glycerol on the bicontinuous cubic structure of hydrated monoolein and its phase behavior // Chemistry and Physics of Lipids. ‒ 2007. ‒ Vol. 147, № 2. ‒ P. 59-68. Aberg C., Pairin C., Costa-Balogh F. O., Sparr E. Responding double-porous lipid membrane: Lyotropic phases in a polymer scaffold // Biochimica Et BiophysicaActa-Biomembranes. ‒ 2008. ‒ Vol. 1778, № 2. ‒ P. 549-558. Adamenko I. I., Bulavin L. A., Ilyin V., Zelinsky S. A., Moroz K. O. Anomalous behavior of glycerol-water solutions // Journal of Molecular Liquids. ‒ 2006. ‒ Vol. 127, № 1-3. ‒ P. 90-92. Adamenko I. I., Zelinsky S. O., Korolovich V. V. Thermodynamic Properties of Glycerol-Water Solution // Ukrainian Journal of Physics. ‒ 2007. ‒ Vol. 52, № 9. ‒ P. 855-859. Aghtar M., Strumpfer J., Othrich C., Schulten K., Kleinekathofer U. The FMO Complex in a Glycerol-Water Mixture // Journal of Physical Chemistry B. ‒ 2013. ‒ Vol. 117, № 24. ‒ P. 7157-7163. Aioanei D., Brucale M., Tessari I., Bubacco L., Samori B. Worm-Like Ising Model for Protein Mechanical Unfolding under the Effect of Osmolytes // Biophysical Journal. ‒ 2012. ‒ Vol. 102, № 2. ‒ P. 342-350. Aioanei D., Tessari I., Bubacco L., Samori B., Brucale M. Observing the osmophobic effect in action at the single molecule level // Proteins: Structure Function and Bioinformatics. ‒ 2011. ‒ Vol. 79, № 7. ‒ P. 2214-2223. Akinkunmi F. O., Jahn D. A., Giovambattista N. Effects of Temperature on the Thermodynamic and Dynamical Properties of Glycerol-Water Mixtures: A Computer Simulation Study of Three Different Force Fields // Journal of Physical Chemistry B. ‒ 2015. ‒ Vol. 119, № 20. ‒ P. 6250-6261. Alber C., Buraczewska-Norin I., Kocherbitov V., Saleem S., Loden M., Engblom J. Effects of water activity and low molecular weight humectants on skin permeability and hydration dynamics - a double-blind, randomized and controlled study // International Journal of Cosmetic Science. ‒ 2014. ‒ Vol. 36, № 5. ‒ P. 412-418. Albert S., Bauer T., Michl M., Biroli G., Bouchaud J. P., Loidl A., Lunkenheimer P., Tourbot R., Wiertel-Gasquet C., Ladieu F. Fifth-order susceptibility unveils growth of thermodynamic amorphous order in glass-formers // Science. ‒ 2016. ‒ Vol. 352, № 6291. ‒ P. 1308-1311. Albro M. B., Petersen L. E., Li R., Hung C. T., Ateshian G. A. Influence of the Partitioning of Osmolytes by the Cytoplasm on the Passive Response of Cells to Osmotic Loading // Biophysical Journal. ‒ 2009. ‒ Vol. 97, № 11. ‒ P. 2886-2893. Alekseev S. I., Szabo I., Ziskin M. C. Millimeter wave reflectivity used for measurement of skin hydration with different moisturizers // Skin Research and Technology. ‒ 2008. ‒ Vol. 14, № 4. ‒ P. 390-396. Saratov Fall Meeting 2016

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  10. References Beierlein F. R., Krause A. M., Jager C. M., Fita P., Vauthey E., Clark T. Molecular Dynamics Simulations of Liquid Phase Interfaces: Understanding the Structure of the Glycerol/Water-Dodecane System // Langmuir. ‒ 2013. ‒ Vol. 29, № 38. ‒ P. 11898-11907. Bellavia G., Paccou L., Guinet Y., Hedoux A. How Does Glycerol Enhance the Bioprotective Properties of Trehalose? Insight from Protein-Solvent Dynamics // Journal of Physical Chemistry B. ‒ 2014. ‒ Vol. 118, № 30. ‒ P. 8928-8934. Bello J., Bello H. R. Chemical modification and cross-linking of proteins by impurities in glycerol // Archives of Biochemistry and Biophysics. ‒ 1976. ‒ Vol. 172, № 2. ‒ P. 608-610. Bendler J. T., Shlesinger M. F. Generalized Vogel law for glass-forming liquids // Journal of Statistical Physics. ‒ 1988. ‒ Vol. 53, № 1. ‒ P. 531-541. Benson J. D., Chicone C. C., Critser J. K. Exact solutions of a two parameter flux model and cryobiological applications // Cryobiology. ‒ 2005. ‒ Vol. 50, № 3. ‒ P. 308-316. Benson J. D., Chicone C. C., Critser J. K. Analytical Optimal Controls for the State Constrained Addition and Removal of Cryoprotective Agents // Bulletin of Mathematical Biology. ‒ 2012. ‒ Vol. 74, № 7. ‒ P. 1516-1530. Bentefour E. H., Glorieux C., Chirtoc M., Thoen J. Thermal relaxation of glycerol and propylene glycol studied by photothermal spectroscopy // Journal of Chemical Physics. ‒ 2004. ‒ Vol. 120, № 8. ‒ P. 3726-3731. Bhaganna P., Volkers R. J. M., Bell A. N. W., Kluge K., Timson D. J., McGrath J. W., Ruijssenaars H. J., Hallsworth J. E. Hydrophobic substances induce water stress in microbial cells // Microbial Biotechnology. ‒ 2010. ‒ Vol. 3, № 6. ‒ P. 701-716. Birge N. O. Specific-heat spectroscopy of glycerol and propylene glycol near the glass transition // Physical Review B. ‒ 1986. ‒ Vol. 34, № 3. ‒ P. 1631-1642. Bjorklund S., Andersson J. M., Pham Q. D., Nowacka A., Topgaard D., Sparr E. Stratum corneum molecular mobility in the presence of natural moisturizers // Soft Matter. ‒ 2014. ‒ Vol. 10, № 25. ‒ P. 4535-4546. Bjorklund S., Engblom J., Thuresson K., Sparr E. Glycerol and urea can be used to increase skin permeability in reduced hydration conditions // European Journal of Pharmaceutical Sciences. ‒ 2013. ‒ Vol. 50, № 5. ‒ P. 638-645. Blazhnov I. V., Magazu S., Maisano G., Malomuzh N. P., Migliardo F. Macro- and microdefinitions of fragility of hydrogen-bonded glass-forming liquids // Physical Review E. ‒ 2006. ‒ Vol. 73, № 3. ‒ P. 0312011-031201-7. Blazhnov I. V., Malomuzh N. P., Lishchuk S. V. Temperature dependence of density, thermal expansion coefficient and shear viscosity of supercooled glycerol as a reflection of its structure // Journal of Chemical Physics. ‒ 2004. ‒ Vol. 121, № 13. ‒ P. 6435-6441. Blazhnov I. V., Malomuzh N. P., Lishchuk S. V. Dielectric permittivity of glycerol in the high viscosity region // Chemical Physics Letters. ‒ 2006. ‒ Vol. 418, № 1-3. ‒ P. 230-234. Bloksgaard M., Neess D., Faergeman N. J., Mandrup S. Acyl-CoA binding protein and epidermal barrier function // Biochimica Et Biophysica Acta-Molecular and Cell Biology of Lipids. ‒ 2014. ‒ Vol. 1841, № 3. ‒ P. 369-376. Boral S., Bohidar H. B. Effect of Water Structure on Gelation of Agar in Glycerol Solutions and Phase Diagram of Agar Organogels // Journal of Physical Chemistry B. ‒ 2012. ‒ Vol. 116, № 24. ‒ P. 7113-7121. Saratov Fall Meeting 2016

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