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Amines

Amines. Nomenclature Properties Preparation reactions Characteristic reactions Spectroscopy. Nomenclature and Properties of Amines. Preparation Reactions of Amines. Reduction reactions Rearrangements Nucleophilic substitution reactions. Amines via Reduction.

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Amines

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  1. Amines • Nomenclature • Properties • Preparation reactions • Characteristic reactions • Spectroscopy

  2. Nomenclature and Properties of Amines

  3. Preparation Reactions of Amines • Reduction reactions • Rearrangements • Nucleophilic substitution reactions

  4. Amines via Reduction • Reduction of nitro compounds • Reduction of nitriles • Reduction of amides • Reduction of imines/enamines • Reductive amination of aldehydes/ketones

  5. Amines via Reduction: A Summary

  6. Amines via Rearrangement • Hofmann rearrangement (degradation) • Curtius rearrangement

  7. Amines via Bimolecular Nucleophilic Substitution

  8. Amine Reactions • Reaction as Bases: Salt Formation • Amide Formation • Alkylation • Reaction with Nitrous Acid

  9. Amine Reactions with Nitrous Acid • Primary amines: Diazotization • Secondary Amines: Nitrosamine formation • Tertiary Amines: C-nitroso compounds

  10. Mechanism of Diazonium salt formation

  11. Diazonium Salt Reactions

  12. Reactions of Phenols • Salt formation via strong base or active metal • Williamson ether synthesis • Ester formation • Friedel-Crafts acylation: Fries rearrangement • Halogenation • Coupling with diazonium salts • Kolbe-Schmitt Carboxylation • Reimer-Tiemann reaction

  13. Phenol Reactions: A Summary

  14. Halogenation of Phenols

  15. Reimer-Tiemann Reaction Mechanism

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