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Second Derivative Differential Electrolytic Potentiometry for Oxidation – Reduction Reactions

Second Derivative Differential Electrolytic Potentiometry for Oxidation – Reduction Reactions

For the first time, second derivative differential electropotentiometry SDEP is applied for detection of oxidationreduction reactions, and is utilized for determination of 1-100 ppm iron(II) pure solutions using 5x10 -3-M cerium ammonium sulfate as an oxidant in 1-M sulfuric acid, and a couple of protected platinum electrodes as an indicating system. No excipient was found to pose any interference, thus rendering the method suitable for determination of iron(II) in pharmaceutical preparations. The results of this study were favorably compared statistically with those obtained with the first derivative differential lectropotentiometry FDEP method and direct lectropotentiometric EP method.

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120 views • 8 slides
Reductimetric determination of Nitroso-R-Salt with Iron(II) in buffer medium and in presence of oxalate and the speciati

Reductimetric determination of Nitroso-R-Salt with Iron(II) in buffer medium and in presence of oxalate and the speciati

Simple, rapid and accurate reductimertric titration methods (potentiometric and visual ) have been developed for<br>the detetermination of Nitroso-R-Salt (a high potential chromogenic reagent ) using iron(II) as a reducing agent in<br>buffer medium ( pH 4.0-5.0 ) and in presence of sodium oxalate (0.05M) and a small amount of methylene blue<br>which acts as a catalyst as well as a redox indicator. Nitroso-R-Salt (NRS ) in the range 15-60mg has been<br>determined with an accuracy of ±0.5% and ±0.7% in t he case of potentiometric and visual end-point methods<br>respectivesy. The precision in both the methods has been determined by computing pooled standard deviation and<br>95% confident limits. In this method NRS is reduced to its corresponding amino compound by iron(II) in a four<br>electron reduction step. The formal redox potentials of the oxidant and reductant systems under the optimum<br>titration conditios have been measured. Based on these potentiials,a satisfactory explanation for the observed redox<br>reaction has been offered. Since oxalate is an iron chelator, a species distribution diagram indicating the extent of<br>formation of various species in iron(III) – oxalate system has been generated using a computer program kown as<br>HYSS. <br>

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95 views • 7 slides
Reductimetric determination of Nitroso-R-Salt with Iron(II) in buffer medium and in presence of oxalate and the speciati

Reductimetric determination of Nitroso-R-Salt with Iron(II) in buffer medium and in presence of oxalate and the speciati

Simple, rapid and accurate reductimertric titration methods (potentiometric and visual ) have been developed for the detetermination of Nitroso-R-Salt (a high potential chromogenic reagent ) using iron(II) as a reducing agent in buffer medium ( pH 4.0-5.0 ) and in presence of sodium oxalate (0.05M) and a small amount of methylene blue which acts as a catalyst as well as a redox indicator. Nitroso-R-Salt (NRS ) in the range 15-60mg has been determined with an accuracy of ±0.5% and ±0.7% in t he case of potentiometric and visual end-point methods respectivesy. The precision in both the methods has been determined by computing pooled standard deviation and 95% confident limits. In this method NRS is reduced to its corresponding amino compound by iron(II) in a four electron reduction step. The formal redox potentials of the oxidant and reductant systems under the optimum titration conditios have been measured. Based on these potentiials,a satisfactory explanation for the observed redox reaction has been offered. Since oxalate is an iron chelator, a species distribution diagram indicating the extent of formation of various species in iron(III) – oxalate system has been generated using a computer program kown as HYSS.

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109 views • 7 slides

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