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Outer sphere mechanism - PowerPoint PPT Presentation

Principal mechanisms of ligand exchange in octahedral complexes

Principal mechanisms of ligand exchange in octahedral complexes. Dissociative. Associative. MOST COMMON. Dissociative pathway (5-coordinated intermediate). Associative pathway (7-coordinated intermediate). Experimental evidence for dissociative mechanisms.

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1.26k views • 47 slides

Schedule

Schedule. Lecture 7: M-M bonds d -bonds and bonding in metal clusters. Lecture 8: Rates of reaction Ligand-exchange reactions, labile and inert metal ions. Lecture 9: Redox reactions Inner and outer-sphere reactions. Summary of Last Lecture. Ligand substitution reactions

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519 views • 20 slides

Confirmation of the Nanopore Inner-Sphere Enhancement (NISE) Effect

Confirmation of the Nanopore Inner-Sphere Enhancement (NISE) Effect Using Nuclear Magnetic Resonance Spectroscopy and Calorimetry Daniel R. Ferreira * Cristian P. Schulthess Marcus V. Giotto Nadine J. Kabengi

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281 views • 1 slides

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Outer sphere mechanism - PowerPoint PPT Presentation

Principal mechanisms of ligand exchange in octahedral complexes

Schedule

Confirmation of the Nanopore Inner-Sphere Enhancement (NISE) Effect