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Temperature jump relaxation method - PowerPoint PPT Presentation

Determining rate constants with relaxation method

Determining rate constants with relaxation method. After applying a perturbation, the system ( A ? B) MAY have a new equilibrium state. Assuming the distance between the current state and the new equilibrium state is x, one gets [A] = [A] eq + x; [B] = [B] eq - x;

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Lecture 14

Lecture 14. 25.5 The temperature dependence of reaction rates. Arrhenius equation: A is the pre-exponential factor; E a is the activation energy. The two quantities, A and E a , are called Arrhenius parameters . In an alternative expression ln k = ln A -

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Temperature jump relaxation method - PowerPoint PPT Presentation

Determining rate constants with relaxation method

Lecture 14