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We have been talking about minerals primarily in the earth’s crust What About the rest??. dicontinuities. Harzburgite (80%olv 20%OPX). lithosphere. Lherzolite (60%olv 40%OPX, grt). MOHO. asthenosphere. Pyrolite (lherzolite-like). Upper mantle. Olivine b -spinel. 410. Pyroxene
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We have been talking about minerals primarily in the earth’s crust • What About the rest??
dicontinuities Harzburgite (80%olv 20%OPX) lithosphere Lherzolite (60%olv 40%OPX, grt) MOHO asthenosphere Pyrolite (lherzolite-like) Upper mantle Olivine b-spinel 410 Pyroxene b-spinel + stishovite 660 Spinel perovskite + periclase Lower mantle Mantle composition (rheology)
discontinuities Harzburgite (80%olv 20%OPX) lithosphere Lherzolite (60%olv 40%OPX, grt) MOHO asthenosphere Pyrolite (lherzolite-like) Upper mantle Olivine b-spinel 410 Pyroxene b-spinel + stishovite 660 Spinel perovskite + periclase Lower mantle Upper Mantle Minerals • Olivine (60%), Pyroxene (30%), Garnet (10%) • Rest is compositionally homogeneous • What’s different??
Upper Mantle Olivine • Olivine – Thought to be about 10-12% Fe in upper mantle • At pressures around the 410-km discontinuity, Fo-rich olivine transforms to a ccp structure called wadsleyite. • Iron rich olivines do not undergo this transformation. At higher pressures, both the Fa-rich olivine and wadsleyite transform to a spinel structure, (Mg,Fe)2SiO4, called ringwoodite. • This occurs when the pressure forces the structure to become as closest-packed as it can get in order to become more dense it must transform to a new phase.
Garnet, Pyroxene • As pressure increases Pyroxene Garnet (primarily pyrope) • Increases from 50 to 520 km • Past 520 km, Garnet Ca-perovskite • Past 720 km, more Mg rich Garnets begin to form Mg-perovskite
Lower Mantle Minerals • Perovskite ((Mg, Fe)SiO3, Magnesio-wüstite: ((Mg,Fe)O), and Stishovite (SiO2) • ~80% Perovskite, ~20% Magnesio-wustite, minor stishovite (which doesn’t form if Mg or Fe are around) • At these high pressures, all Si is 6-coordinate (SiO6 subunits; Octahedral coordination)
Perovskite • (Mg, Fe)SiO3 • As the major mineral in the lower mantle, possibly the most abundant earth material!
Do we have any Lower Mantle Minerals?? • NO • How do we know they are there? • METEORITES!?!?!?! • P-S waves tell us something about composition • Nuclear chemistry also tells us something about composition • EXPERIMENTS – simulate P-T see what you get…
Core • Outer Core • Liquid – made of Iron (Fe) and Nickel (Ni) (about 4%) and some S, Si, and O (enough to make the density less than Fe and Ni alone) • Movement of this liquid is responsible for earth’s magnetic field • Inner Core • Solid, Hexagonally-closest packed Fe and Ni
Geodynamo • The inner core spins – what happens when a solid is spun inside a liquid containing ions?? • Generate an electromagnetic field! • The polarity of that field has flopped many times in earth’s history Model of a magnetic reversal taking ~1,000 years… http://www.es.ucsc.edu/~glatz/geodynamo.html
The electromagnetic field also protects the planet from solar sourced ionic particles (solar wind) • The geodynamo is additionally responsible for the position of magnetic north