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Chapter 13. solutions. Homogeneous Particle size- atoms, ions, molecules Does not separate on standing Cannot be separated by filtration Does not scatter light. Colloids. Heterogeneous Very large particles Does not separate on standing Cannot be separated by filtration
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solutions • Homogeneous • Particle size- atoms, ions, molecules • Does not separate on standing • Cannot be separated by filtration • Does not scatter light
Colloids • Heterogeneous • Very large particles • Does not separate on standing • Cannot be separated by filtration • Scatters light- Tyndal effect
Suspensions • Heterogeneous • Very large particles • Particles settle out • Can be separated by filtration • May or may not scatter light
Electrolyte- a solution that conducts electricity—must have ions present • What system in the body uses electrolytes?
Solute- substance being dissolved • Solvent- substance (medium) doing the dissolving
Substances that are mutually soluble- the smaller amount is the solute
Random facts Water is the universal solvent Air is the solvent for all evaporated substances Alloy- mixture of 2 metals BRASS- zinc and copper 14 carat gold- gold and silver
Foams and emulsions are colloids • (mayo, shaving cream)
What type of mixture is Fog? What is fog made of? • Why do you drive with your lights on dim?
Increase Rate of dissolving • 1. heat- particles collide faster and more often • 2. agitation- same as above 3. surface area- more area exposed to the solvent (crushing, grinding)
solubility • Amount of solute that can be dissolved in a specific amount of solvent
Formation of a solution • Solute breaks apart (endo) • Solvent breaks apart (endo) • Solute and solvent form and attraction(exo) • Overall depends on which is greater- exo or endo
Solubility of a substance depends on: • bonding, pressure, temperature.
Bonding effect • Like dissolves like • Polar dissolves polar • Nonpolar dissolves nonpolar • Review terms: miscible, immiscible
Why can oxygen gas O2 (nonpolar) dissolve in water (polar)? (This is an IMF question)
Why drink red wine with red meat? • Red meat is very fatty and this fat coats the tongue • When the skin of the grape undergoes fermentation, tannic acid is produced • Tannic acid has a polar end and a nonpolar end. The nonpolar end dissolves the fat off of the tongue
White wine(no grape skins) does not contain tannic acid, has a milder taste and is used with low fat meat(chicken)
Can I drink Welch’s grape juice and get the same effect as red wine?
Soap and Detergent • Water is polar Grease is nonpolar • Soap is a long carbon chain compound that has a polar end and a nonpolar end. • Nonpolar end sticks into the grease and the polar end can dissolve in water • Soapy water forms a colloid and is washed down the drain
Soaps form precipitates with “hard water”. Water that contains ions such as Ca+2, Fe+3 • Detergents do not form precipitates so they wash away cleaner
Pressure • Effects gases • Increase in pressure, increases solubility of gas • Decrease in pressure, decreases solubility of gas • Effervescence- rapid escape of a gas
What is the “bends” to a scuba diver? • A diver will have more gases dissolved in their blood. A diver has to pause when coming up to allow for the gases to be exhaled. Too fast ascent and the gases cannot be exhaled
Temperature • Increase in heat– increases solubility of a solid and liquid • Decrease in heat- increases solubility of a gas
Which goes flat faster? • A opened Coke in the refrigerator or the coke left on the counter
Boiling water • Bubbles at the bottom of beaker- what are they and why did they appear?
Concession Stands • Trailer type- no electricity- how does the carbon dioxide get dissolved in the drinks? • Resturant type- has electricity- how does the carbon dioxide get dissolved in the drinks?
Saturated- max amount of solute • Unsaturated- less than max amount of solute
Supersaturated- using heat, the solute was dissolved and the solution was slowly cooled- contains more than the max amount of solute at the lower temperature.
What temperature is needed to dissolve 50 grams of potassium nitrate in 100 ml? • How many grams of potassium chloride is needed to make a saturated solution at 80c? • If a supersaturated solution was made with 80 grams of KNO3 and cooled to 40c. How many grams of solute came out of solution when a seed crystal was added?
Looking at the graph, which substance is a gas based on the solubility graph? • Which substance has the highest solubility at 10c? • What 2 substance has the same solubility at 72c?
Expressing Concentration • Be able to work the (blue) problem page completely and we should test next week.