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Chapter 7 . Eggs. Composition of eggs. Composition of Eggs - egg white (albumen). Water (~88%) CHO (~1%) mainly glucose, may cause brown discoloration in dried eggs and hard cooked eggs (Millard reaction) Fat (trace) . Composition of Eggs - egg white (albumen).
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Chapter 7 Eggs
Composition of Eggs -egg white (albumen) Water (~88%) CHO (~1%) mainly glucose, may cause brown discoloration in dried eggs and hard cooked eggs (Millard reaction) Fat (trace)
Composition of Eggs -egg white (albumen) Proteins (~11%), most are glycoproteins Three primary proteins: ovalbumin (54%)Structure of Baked Products ovotransferrin (12%), Binds metal, Discoloration ovomucoid (11%) Protease Inhibitor ovomucin (1.5%): A Fibrous Protein, contributes to the thickness of the white (4 x more abundant than in yolk), contributes to the stability of egg white foam
Composition of Eggs -egg white (albumen) Proteins (cont’n) globulins (8%): including lysozyme, are important for foaming lysozyme: ability to hydrolyze a polysaccharide in the cell wall of some bacteria to prevent bacterial spoilage others: ovoinhibitor, ovoflavoprotein, ovomicroglobulin, avidin (binds biotin, but is heat sensitive)
Composition of Eggs -egg yolk Proteins (16.4%): plasma (78%): livetin & LDL (protein content ~ 10%) granular fraction: phosvitin (16%, carrier of Fe), lipovitellins (70%) & LDL (12%) Water (48%)
Composition of Eggs -egg yolk Lipids (32 to 34%) triglycerol (66%) phospholipid (28%) including lecithin (has remarkable emulsifying ability) cholesterol (3%, or 250 mg) The color of yolk depends on the presence of carotenoids. xanthophylls not carotene (Lutein and zeaxanthin)
Egg Quality Commercial grading of eggs according to the USDA standards External quality: shell characteristics, shape, soundness, cleanliness, & color Interior quality: size of the air cell, firmness of the white, & the yolk (distinct or flattened during aging) Evaluated by candling
Egg quality during storage The size of the air cell increases water evaporates from the egg through shell The egg white becomes thinner ovomucin undergoes degradation pH of white increases (from ~ 8 to ~9) due to the loss of CO2 through the pores
Egg quality during storage The yolk enlarges and the membrane weakens (water moves from white to yolk, viscosity decreases, yolk becomes flatter and spreads farther) Deterioration of odor & flavor Increased storage temperature accelerates loss of quality
Functionality of Eggs • Coagulation • Emulsification • Foaming
Protein Coagulation • Denaturation: Relaxation of the tertiary structure to the secondary structure, accompanied by decreasing solubility of a protein • Precipitation of protein as molecules aggregate (often as a result of energy input, such as heating or beating) • Process that results in a loss of solubility or a change from a fluid state to a solid state. (Gelation is also used to describe the process.
Functionality of Eggs -coagulation • egg white begins to thicken at ~62oC, yolk at ~65oC. 72oC Firm • The gel firmness depends on time & temperature of heating • Gel hardness dependents on the pH and the concentration of protein • increased pH or protein will increase gel hardness • diluted protein will increase coagulation temperature ∟
Functionality of Eggs -coagulation • Sugar decreases the rate of heat denaturation & increases the coagulation temperature • Salts promote coagulation
Functionality of Eggs -emulsification • Formation of emulsion • mechanical agitation makes it insoluble and stiff or stable • emulsifying agent (Lecithin) • Egg Yolk is an oil-in-water emulsion
Functionality of Eggs - foaming • A colloidal suspension: bubbles surrounded by egg albumen (protein) • globulins have greater foaming ability • ovomucin stabilizes the foam
Functionality of Eggs - factors affecting foaming • Method, time and temperature of beating • as beating time increases, volume and stability of the foam 1st increases then decreases • maximum stability is reached before maximum volume • room temperature vs refrigerator temperature
Functionality of Eggs - factors affecting foaming • Characteristics of the egg white • thin white vs thick white • stored eggs vs fresh eggs • pH • acids or acid salts increases foam stability but delays foam formation
Functionality of Eggs - factors affecting foaming • Water • water increases the foam volume but decreases its stability • fat • oil reduces foam volume • sodium chloride • reduces the foam stability, increases whipping time
Functionality of Eggs - factors affecting foaming • Sucrose • delays foam formation (so beat then add) • produces a more stable foam • egg yolk • decreases the foam volume • additives • surfactants and stabilizers may reduce whipping time, increase foam volume
Functionality of Eggs - factors affecting foaming • Method, time and temperature of beating • characteristics of the egg white • pH • water and fat • sodium chloride • sucrose • egg yolk • additives
Processed Eggs • Frozen eggs • egg whites perform well after freezing & thawing • add 10% (w/w) of sugar or salt to yolks before freezing to control the gelation of frozen yolk • To prevent “syneresis” in frozen cooked egg products: • addition of gums • addition of citric acid • addition of salt
Processed Eggs • Egg substitutes • use of egg white together with a yolk-like mixture containing no cholesterol • fortify with fat-soluble nutrients • addition of carotenoid for giving the yolk color • addition of carboxymethyl-cellulose (CMC) reduces weeping • aroma and flavor are not as good as fresh eggs
Processed Eggs • Dried eggs (spray drying) • products: whole-egg solids, yolk solids, fortified whole-egg solids and whites • growth of microorganisms is inhibited • coagulation is not affected • foaming potential is reduced • add whipping agents (surface active)
Processed Eggs • All liquid eggs should be pasteurized (61C for 3.5 min) to kill salmonella and other potential pathogens. • Ultrapaseurized liquid whole eggs • retain functional properties of fresh shell eggs • are aseptically packaged
Functionality of Eggs: Summary coloring agent (carotenoids in yolk) emulsifier mayonnaise, hollandaise sauce, cream puff thickening agent (coagulation) baked (gel) or stirred (sol) custards, foaming meringues, foam cakes (angel, sponge, and chiffon)
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