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Light, Matter and Energy. Topics. Review Basic Units and Powers of Ten The Spectrum Light as Waves Light as Particles Atoms Summary. Basic Units. Distance Meter m Mass Kilogram kg Time Second s or sec Energy Joule J (kg m 2 / s 2 ) Power Watt 1 J / s. Powers of Ten.
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Topics • Review • Basic Units and Powers of Ten • The Spectrum • Light as Waves • Light as Particles • Atoms • Summary
Basic Units • Distance • Meter m • Mass • Kilogram kg • Time • Second s or sec • Energy • Joule J (kg m2 / s2) • Power • Watt 1 J / s
White light is a mixture of light of different colors The Spectrum Red Orange Yellow Green Blue Indigo Violet Virtual Physics Lab – Colors Fig. 2-1, p. 22
Light as Waves Virtual Physics Lab – Double Slit Interference
Light as Waves – II p. 23
Speed of Wave = Wavelength x Frequency c = l n c speed of light l wavelength n frequency Example: Tallahassee radio station: 99.9 fm n = 99.9 x 106cycles per second (Hz) c = 3 x 108meters per second (m/s) Therefore, λ = c / n = 3 x 108 / 108= 3 m
The Electromagnetic Spectrum 10-12 m 10-7 m 102 m http://www.chemheritage.org/EducationalServices/FACES/env/readings/photon.htm Virtual Physics Lab - Electromagnetics
- - - - - - - Photoelectric Effect No current flows however Intense the light A current flows only if the light is of sufficiently high frequency http://lectureonline.cl.msu.edu/~mmp/kap28/PhotoEffect/photo.htm
Light as Particles • In 1905, Albert Einstein suggested that light is a huge collection of packets of energy, he called photons • Each photon has energy • h = 6.6261 x 10-34 J . sis Planck’s constant E = h n = h c / l
Fraunhofer Lines Dark lines in solar spectrum discovered by Joseph von Fraunhofer (1787 – 1826) Fig. 2-4, p. 24
The Balmer Series of Hydrogen 10 Ångström = 1 nanometer (nm) Balmer Formula (1885) n = 3, 4, … Johann Balmer (1825 – 1898) 1/R = 91.16 nm R is the Rydberg constant Fig. 2-11, p. 28
The Bohr Model of Atoms (1913) Fig. 2-5, p. 26
Atomic Transitions Fig. 2-10, p. 27
Bohr Model of the Hydrogen Atom Ha n = 3 to n = 2
Hb Paschen Ha Lyman Energy Levels of Hydrogen E∞ = 0 eV n = ∞ n = 4 n = 3 n = 2 Balmer E1 = -13.6 eV n = 1
Example: Hydrogen-alpha (Ha) Line • Energy of Photon • E = hc / l = 1240 (eV . nm) / l (nm) • Energy Change (from level n = 3 to n = 2) • E = 13.6 (1/22 – 1/32) = 1.89 eV • Wavelength • 1240 / l = 1.89 • l = 656.5 nm
Neutral Atoms Net charge is zero Fig. 2-13, p. 29
Ionized Atoms Net charge is +1 unit Fig. 2-13, p. 29
Molecule Atom Nucleon n n Nucleus p d u u Quantum Theory of Matter Hydrogen Orbitals
Matter Proton Neutron d u u d u d Photon g Electron Electron Neutrino e ne
Spectra: continuous, emission, absorption Fig. 2-7, p. 26
Black Body Radiation Radiation from an object at temperature T A hot object emits a continuous spectrum of colors Wien’s Law T = 3 x 106 / lmax T in Kelvin lmax in meters p. 25
Doppler Effect Fig. 2-14, p. 30
Discovery of Extrasolar Planets Fig. 2-16, p. 31
Summary • Electromagnetic Radiation • Radio, microwaves, light, x-rays, gamma rays differ only in wavelength (and therefore in energy). • Photons • Light behaves like a huge ensemble of particles. • Photons can be emitted, and absorbed, by atoms and molecules. • Atoms and Molecules • Can be identified by their unique emission (or absorption) spectra.