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Sébastien R. Goudreau

Enantioselective Carbometallation of Unactivated Olefins. Sébastien R. Goudreau. Literature Meeting. September 16 th , 2008. Introduction: Formation of C-C Bonds. Carbonyl Chemistry. Olefines Chemistry. Carbometallation. Regioselectivity. Diastereoselectivity. Enantioselectivity.

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Sébastien R. Goudreau

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  1. Enantioselective Carbometallation of Unactivated Olefins Sébastien R. Goudreau Literature Meeting September 16th, 2008

  2. Introduction: Formation of C-C Bonds Carbonyl Chemistry Olefines Chemistry

  3. Carbometallation Regioselectivity Diastereoselectivity Enantioselectivity Ziegler et al. Chem. Ber.1928, 61, 253

  4. Enantioslective Carbometallation of Unactivated Olefines Zn, Cu, Mg, Al, Li Pd and Ni will not be included Marek Perkin Trans. 11999, 535

  5. Zinc E. Nakamura The University of Tokyo J. F. Normant Université P. et M. Curie I. Marek Technion-Israel Institute of Technology

  6. Addition of Zinc Enolate Marek, Normand et al. JOC1998, 63, 2442

  7. Synthesis of Proline Derivative Marek, Normand et al. JOC1998, 63, 2442

  8. Allylation of Alkene Marek, Normand et al. TL1998, 39, 4821

  9. Allylation of Alkene Marek, Normand et al. TL1998, 39, 4821

  10. Allylation of Alkene Marek, Normand et al. Seances Acad. Sci., Ser. II1998, 621 10

  11. Allylation of Alkene Marek, Normand et al. Seances Acad. Sci., Ser. II1998, 621

  12. Allylation of Alkene Marek, Normand et al. TL1998, 39, 4821 12

  13. Allylation of Cyclopropene Nakamura et al. JACS1993, 115, 5867

  14. Allylation of Cyclopropene Nakamura et al. JACS1993, 115, 5867

  15. Allylation of Cyclopropene ent ent Nakamura et al. JACS1995, 117, 1179

  16. Allylation of Cyclopropene Nakamura et al. JACS1995, 117, 1179

  17. Addition on Cyclopropene: Enders’ Hydrazone Nakamura et al. JOC1997, 62, 792

  18. Addition on Alkene: Enders’ Hydrazone Nakamura et al. Angew1997, 36, 2491

  19. Copper E. Nakamura The University of Tokyo

  20. Addition on Cyclopropene Nakamura et al. JACS1990, 112, 7428

  21. Addition on Cyclopropene Nakamura et al. JACS1990, 112, 7428

  22. Addition on Cyclopropene Nakamura et al. JACS1990, 112, 7428

  23. Magnesium A. H. Hoveyda, Boston College

  24. Addition of Grignard on Cyclopropene Fox et al. JACS2006, 128, 5600

  25. Mg: Zr Catalysis ethylene-1,2-bis(η5-4,5,6,7-tetrahydro-1-indenyl)zirconium dichloride Hoveyda et al. JACS1993, 115, 6997

  26. Mg: Zr Catalysis Hoveyda et al. JACS1996, 118, 4291

  27. Mg: Zr Catalysis Hoveyda et al. JACS1996, 118, 4291

  28. Mg: Zr Catalysis Hoveyda et al. JACS1993, 115, 6997

  29. Mg: Zr Catalysis Hoveyda et al. JACS1993, 115, 6997

  30. Mg: Zr Catalysis Hoveyda et al. JACS1993, 115, 6997

  31. Mg: Zr Catalysis Hoveyda et al. JACS1996, 118, 4291

  32. Synthesis of Sch 38516 Aglycon Macrolactam Hoveyda et al. JACS1997, 119, 10302 Hoveyda et al. JACS1995, 117, 2943

  33. Synthesis of Sch 38516 Aglycon Macrolactam Hoveyda et al. JACS1997, 119, 10302 Hoveyda et al. JACS1995, 117, 2943

  34. Kinetic Resolution of Pyrans Hoveyda et al. JACS1996, 118, 4291 Hoveyda et al. JACS1994, 115, 3123

  35. Kinetic Resolution of Pyrans Hoveyda et al. JACS1996, 118, 4291 Hoveyda et al. JACS1994, 115, 3123

  36. Kinetic Resolution of Pyrans Hoveyda et al. JACS1996, 118, 4291 Hoveyda et al. JACS1994, 115, 3123

  37. Kinetic Resolution of Furans Hoveyda et al. Tetrahedron1995, 51, 4383

  38. Kinetic Resolution of Furans Hoveyda et al. Tetrahedron1995, 51, 4383

  39. Kinetic Resolution of Furans Hoveyda et al. Tetrahedron1995, 51, 4383

  40. Kinetic Resolution of Allylic Ethers Hoveyda et al. JACS1996, 118, 3779

  41. Kinetic Resolution of Allylic Ethers Hoveyda et al. JACS1996, 118, 3779

  42. Synthesis of Nebivolol Hoveyda et al. JACS1998, 120, 8340

  43. Synthesis of Nebivolol Hoveyda et al. JACS1998, 120, 8340

  44. Synthesis of Nebivolol Hoveyda et al. JACS1998, 120, 8340

  45. Addition on Alkene Whitby et al. TL1996, 39, 7139

  46. Aluminium Ei-ichi Negishi Perdue University

  47. Methylation of Alkene Negishi et al. JACS1995, 117, 10771

  48. Methylation of Alkene Negishi et al. JACS1995, 117, 10771

  49. Methylation of Alkene Negishi et al. JACS1996, 118, 1577

  50. Lithium J. F. Normant Université P. et M. Curie I. Marek Technion-Israel Institute of Technology

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