210 likes | 454 Views
Properties of Gases. Gases. We use gases in our everyday live Fridges, fuel, deep sea diving (ok not everyday) Force due to gas is called pressure SI unit Pa = 1 Newton/metre 2 Atmospheric pressure is the amount of pressure exerted by air – at sea level about 101 kPa. Units. Pg. 149.
E N D
Gases • We use gases in our everyday live • Fridges, fuel, deep sea diving (ok not everyday) • Force due to gas is called pressure • SI unit Pa = 1 Newton/metre2 • Atmospheric pressure is the amount of pressure exerted by air – at sea level about 101 kPa.
Units Pg. 149
Relationship between Pressure and Volume • We can see that if we increase the volume the pressure decreases, and if we decrease the volume the pressure increases. • Pressure and volume have an inverse relationship • All other conditions are left the same, temperature, amount of substance
Boyle’s Law P1V1 = P2V2 • As the pressure on a gas increases, the volume of the gas decreases proportionally, provided that the temperature and chemical amount of gas remain constant.
Relationship between Temperature and Volume • Jacques Charles observed that there is a relationship between temperature and volume when doing experiments using hot air balloons. • Units of temperature (˚C) or kelvin (k). • Absolute zero is 0 k nothing can be colder.
Charles’ Law V1 / T1= V2/ T2 • As the temperature of a gas increases, the volumes increases proportionally, provided that the pressure and chemical amount of gas remain constant • This needs to be done in kelvin • T (K) = t (˚C) + 273
Combined Gas Law • Boyle’s Law PV = constant • Charles’ Law V/T = constant • We are able to combine both to give P= constant
Summary P1V1 = P2V2 • STP: 0 ˚ C and 101.325 kPa • SATP: 25 ˚ C and 100. kPa • 101.325 kPa = 1 atm = 760 mm Hg • T (K) = t (˚ C) + 273 V1 / T1= V2/ T2 P= constant
Properties of Gases • Kinetic molecular theory explains a lot about the properties of gases • Gases are compressible - the distance between the molecules • Gas pressure – the amount of collisions that occur • Boyle’s Law • Charles’ Law
Combining volumes • Law of combining gases • when measured at the same temperature and pressure, volumes of gaseous reactant and products of chemical reactions are always in simple ratios of whole numbers • Avogadro’s Theory • Equal volumes of gases at the same temperature and pressure contain equal numbers of molecules
Example • H2 + Cl2 -> 2HCl • Since the ratio is 1:1:2 then if 1.0 L of hydrogen combined with 1.0 L of Chlorine it would give 2.0 L of hydrogen chloride. • These ratios hold true for coefficients, chemical amounts, and volumes
Molar Volume of Gases • The volume that one mole occupies at a specified temperature and pressure • Combining the laws we have learnt previously • Given the symbol Vm • V = nVm OR n = V/Vm • The relationship of chemical amount (n), volume (V) and molar volume (Vm) • At STP one mole has a volume of 22.4 L • At SATP one mole has a volume of 24.8 L
The Ideal Gas Law • Law based on how gases will interact within a system. • Hypothetically all gas follow this law • Need to make a few assumptions from the real world
Ideal Gas Law • If we recall Boyle’s Law • Charles’ Law • Avogadro’s theory • Can combine all these to give: • - constant • -universal gas constant
Application • http://jersey.uoregon.edu/Piston/
Partial Pressure • The pressure inside a closed container is maybe up of the pressure of each of the gases would have in the same volume contained within it. • P = P1 + P2 + P3 + … • Example: • H2(g)+ Cl2(g)-> 2HCl(g) • P = PH2 + PCl2 + PHCl