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Below are several Lewis dot diagrams, all having errors. Find the errors, explain why they are errors, and correct them. •. •. •. •. Al. •. N. •. •. He. •. •. •. •. •. •. •. •. •. •. Do Now. Lewis Dot Diagrams. Write element symbol Determine # of valence electrons
E N D
Below are several Lewis dot diagrams, all having errors. Find the errors, explain why they are errors, and correct them. • • • • Al • N • • He • • • • • • • • • • Do Now
Write element symbol • Determine # of valence electrons • Equal to group # • Draw dots around symbol • # of dots = # of valence electrons • Put 1 dot per side before you pair dots up Reviewing Lewis Diagrams
B 4 8 7 1 5 3 6 2 Lewis Symbols
Cl Lewis Symbols
In compounds, atoms tend to achieve noble gas electron configurations • Metals lose to achieve octet in lower energy level • Non-metals gain to get 8 if combine with metal • or can share with other non-metals • Metal cation + non-metal anion = ionic bond (chapter 7) • 2 non-metals = covalent bond (chapter 8) • 2 metals = metallic bond (also chapter 7) Octet Rule Review
Between non-metals • Electrons are shared between atoms • Neutral • Makes molecules Covalent Bonds
Chemical formula = molecular formula • Not lowest whole number, just actual number of atoms of each element • Properties • Comprised of two or more non-metals • Not good conductors of heat and electric current • Lower melting and boiling points than ionic • Diatomic molecules • Molecule of 2 identical atoms • H2 O2 N2 Cl2 Br2 I2 F2 Molecular compounds
Draw the Lewis dot diagrams for all the atoms in CH4 • Draw 1 carbon diagram • Draw 4 hydrogen diagrams How Covalent Bonds Form
C H H H H Bonding in Methane
C H H H H Bonding in Methane
H C H H H Bonding in Methane
H C H H H Bonding in Methane
H C H H H Bonding in Methane
H H C H H Bonding in Methane
H H C H H Bonding in Methane
H H C H H Bonding in Methane
H H H C H Bonding in Methane
H H H C H Bonding in Methane
H H H H C Bonding in Methane
H C H H H Bonding in Methane
PCl3 H2O SF2 AlCl3 Draw the following compounds:
Get out your homework to be stamped and be prepared to answer: • What is a covalent bond? • What types of elements do covalent bonds form between? • What are valence electrons? • How many electrons are in a bond? Do Now:
Two electrons are shared between two atoms • 1 electron pair • Represented by 1 line between the atoms Single Bond
Let’s Make F2 F F
Let’s Make F2 F F
Let’s Make F2 F F
Four electrons are shared between two atoms • 2 electron pairs • Represented by 2 lines between the atoms Double Bond
O O Let’s Make O2
O O Let’s Make O2
O O Let’s Make O2
O O Let’s Make O2
Draw the Lewis dot diagram for • O3 • CO2 • CF2S Double bonds Try It!
Six electrons are shared between two atoms • 3 electron pairs • Represented by 3 lines between the atoms Triple Bond
N N Let’s Make N2
N N Let’s Make N2
N N Let’s Make N2
Let’s Make N2 N N Let’s Make N2
N N Let’s Make N2
Draw the Lewis Dot Diagram for • HCN • N2O • C2H2 Triple bonds Try It!
Place shared electrons between the 2 symbols either as pair of dots or dashes • Ex H-H or :Ö=Ö: or :N≡N: • Each dash represents a single covalent bond • Unshared pairs / lone pairs / non-bonding pairs = valence e- pairs not in covalent bond • Structural formulas use dashes, but also show spatial arrangement of atoms • Oriented to maximize distance between e- pairs (bonded or unshared) Lewis Structures summary
Covalently bonded • With additional or removed electrons • Cations lose and anions gain in e- count NO31- SO32- PO43- CN1- Polyatomic Ions
Atom that has gained or lost electrons • Cation (+) • Anion (-) Ion Na Cl
Transfer of electrons between atoms • Opposite charges formed • Creates attraction between the ions • Called electrostatic force Ionic Bonds
Cl Na