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Hazard Communication (HAZCOM). Course Number NSTC-05 Revised 7-2013. Introduction. Goal. To ensure participants can recognize the health and physical hazards of chemicals used in the workplace and take steps to control those hazards in accordance with OSHA 29 CFR 1910.1200. Objectives.
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Hazard Communication (HAZCOM) Course Number NSTC-05 Revised 7-2013
Goal To ensure participants can recognize the health and physical hazards of chemicals used in the workplace and take steps to control those hazards in accordance with OSHA 29 CFR 1910.1200.
Objectives Participants will be able to: Explain the purpose of the 2012 Hazard Communication Standard. Explain the components of a hazard communication program. Use hazard classifications, product labeling, safety data sheets, and other resources to identify and control the physical and health hazards of chemicals used in the workplace.
Hazardous Chemical The OSHA definition of a hazardous chemical is any chemical which is classified as a physical or health hazard, a simple asphyxiant, combustible dust, pyrophoric gas, or hazard not otherwise classified. OSHA, 29 CFR 1910.1200(c)
Hazard Communication Standard • The Hazard Communication Standard (OSHA 29 CFR 1910.1200) requires employers to establish hazard communication programs to transmit information on the hazards of chemicals in the workplace. • This standard emphasizes that all employees havea "right-to-know" the hazards and identities of the chemicals in the workplace. • The intent is to reduce the incidence of chemically—related occupational illnesses and injuries. OSHA 29 CFR 1910.1200
2012 Hazard Communication Standard: An Update • The purpose of the 2012 Hazard Communication Standard (OSHA 29 CFR 1910.1200) is to update the regulationto be consistent with the provisions of the United Nations Globally Harmonized System of Classifying and Labeling of Chemicals (GHS). • This modified standard provides a single set of harmonized criteria for classifying chemicals according to their health and physical hazards. • It specifies new requirements for labeling and safety data sheets while maintaining the purpose of the original standard. OSHA 29 CFR 1910.1200
Changes to the HAZCOM Standard • Hazard Classification: Expanded hazard classification for chemical manufacturers and importers. • Labels: New labeling requirements. • Safety Data Sheets or SDS: (formerly Material Safety Data Sheets or MSDS) • Information and Training: Workers must be trained by December 1, 2013 on the new label requirements and SDS formats in addition to current training requirements. OSHA 29 CFR 1910.1200
HAZCOM Communication Responsibilities OSHA 29 CFR 1910.1200
HAZCOM Program Elements • Employee training • Hazardous chemicals list • Provide SDS for employees • Labeling • Communication with employees BP ASH page 22; ASH, page 8
Health Hazard Classification OSHA, 29 CFR 1910.1200, Appendix A
Physical Hazard Classification OSHA, 29 CFR 1910.1200, Appendix B
Basic Toxicology • Acute vs. Chronic Health Effects • Local vs. Systemic Health Effects • Routes of Entry • Inhalation • Absorption (skin and eyes) • Ingestion (dust and liquids) • Injection • Dose / Response
Container Label Requirements • Product identifier • Signal word • Hazard statement(s) • Pictogram(s) • Precautionary statement(s) • Name, address, and telephone number of the chemical manufacturer, importer or other responsible party OSHA 29 CFR 1910.1200 (g)
Product Identifier and Signal Word • The product identifier is the name or number used for a hazardous chemical on a label or Safety Data Sheet Name of the chemical or • The signal word is an alert that indicates the relative level of severity of the hazardous chemical. “Danger” is used for most severe hazards and “Warning” is used for less severe hazards. OSHA 29 CFR 1910.1200 (c )
Hazard Statements • Hazard statements describe the nature of the hazard such as: • Fatal if swallowed • May cause allergic skin reaction • May cause genetic defects • May cause cancer • Causes drowsiness or dizziness • Explosive, severe fire, blast or projection hazard OSHA 29 CFR 1910.1200 (c ); Appendix C
Pictograms • Black hazard symbol on a white background • Placed within a red square frame set on a point • Different hazard symbol for each of the 9 hazard classes • Eight mandatory pictograms • One non-mandatory pictogram Environment Non-mandatory Acquatic Toxicity OSHA 29 CFR 1910.1200, Appendix C
Pictograms (Mandatory) Flame Exclamation Mark Exploding Bomb Flame Over Circle OSHA 29 CFR 1910.1200, Appendix C
Pictograms (Mandatory) Corrosives Health Hazard Skull and Crossbones Gases Under Pressure OSHA 29 CFR 1910.1200, Appendix C
Types of Precautionary Statements • Prevention: Wash hands thoroughly after handling. • Response: “If swallowed, immediately call a poison center/doctor….” • Storage: “Store in a well-ventilated place. Keep container tightly closed.” • Disposal: “Dispose of contents/container to…in accordance with local, regional, national, international regulations (to be specified). OSHA 29 CFR 1910: 1200, Appendix C
Sample Label OSHA 29 CFR 1910.1200 (g)
Sample Label OSHA 29 CFR 1910.1200 (g)
NFPA Diamond Exercise What does each color, number and symbol in this placard mean?
HEALTH FLAMMABILITY REACTIVITY PERSONAL PROTECTION Hazardous Materials Identification System (HMIS) Developed by the National Paint and Coatings Association • Health Hazard (BLUE) - possibility of injury • 4 = could cause death or irreversible injury • 3 = could cause serious temporary or irreversible injury • 2 = could cause temporary incapacitation • 1 = could cause irritation • 0 = no health hazard. • Flammability (RED) - possibility of ignition • 4 = flammable vapor or gas which burns readily • 3 = flammable liquid or solid which can be readily ignited • 2 = must be heated for ignition • 1 = must be preheated before ignition can occur • 0 = no fire hazard • Reactivity(YELLOW) - possibility of reaction • 4 = readily capable of detonation or explosive reaction • 3 = may detonate when exposed to heat of initiating source • 2 = readily capable of nonexplosive reaction • 1 = may become unstable at high temperatures • 0 = stable materials
DOT Placards* *HAZWOPER Module 2012 ERG, pages 16-17
NFPA Diamond 0–4 = Increasing severity of hazard 4 colors = Hazard types Posted on buildings and containers NFPA vs. DOT Placards DOT Placard • 1–9 = Hazard classes • Colors and color combinations = Hazard classes • 4 digit ID number or code = Specific hazardous substance • Posted on railroad cars, trucks, trailers, and tanks 2012 ERG, pages 16-17
Safety Data Sheet (SDS) • The best source for information about the product • Core element of the HAZCOM Program • Different formats and forms • Employer must have one for each product in the workplace • Use the latest version
Accessing an SDS • Hard Copies • Supervisor • Safety Department • Industrial Hygienists • Safety Coordinator • Company Database
Sections of an SDS • Section 1: Identification • Product identifier, manufacturer’s name, address, emergency number • Section 2: Hazards Identification • All hazards regarding chemical; required label elements • Section 3: Composition & Information on Ingredients • Chemical ingredients and trade secret claims • Section 4: First Aid Measures • Symptoms and effects; required treatment OSHA 29 CFR 1910.1200, Appendix D
Sections of an SDS • Section 5: Firefighting Measures • Basic firefighting and extinguishing methods • Section 6: Accidental Release Measures • Emergency procedures; protective equipment, methods of containment and cleanup • Section 7: Handling and Storage • Procedures for safe handling and storage OSHA 29 CFR 1910.1200, Appendix D
Sections of an SDS • Section 8: Exposure Controls and PPE • Permissible exposure and threshold limits, appropriate engineering controls and PPE • Section 9: Physical and Chemical Properties • Characteristics of the chemical • Section 10: Stability and Reactivity • Chemical stability and hazardous reactions • Section 11: Toxicological Information • Routes of exposure, symptoms, toxicity OSHA 29 CFR 1910.1200, Appendix D
Sections of an SDS Additional sections regulated by other agencies and not enforced by OSHA • Section 12: Ecological Information • Section 13: Disposal Considerations • Section 14: Transport Information • Section 15: Regulatory Information • Section 16: Other Information OSHA 29 CFR 1910.1200, Appendix D
Physical Agent Data Sheets (PADS) • The State of Alaska regulates 8 physical hazards in the workplace. • The State provides data sheets related to those hazards called PADS. • The physical hazards covered by the PADS are:
State of Alaska: PADS http://www.labor.state.ak.us/lss/pads/pads.htm
SDS Exercise The purpose of this exercise is to become familiar with how to read and understand an SDS. Working in small groups of 2–5, use the sample SDS to answer the questions in the handout. Let the instructor know when you are finished. Groups will report back and discuss their answers.
Hazard Control Measures • Engineering Controls (detection, ventilation, shielding) • Administrative Controls (substitution, employee rotation, training) • Personal Protective Equipment (PPE) (goggles, gloves, boots) ASH page 1; BP ASH, page 39
Hazard Communication Summary Identify hazards before you start the job Read labels and SDS/PADS Follow warnings and instructions Use correct PPE Label containers
Objectives Participants will be able to: Describe methods for detecting the presence or release of hazardous chemicals. (Omit)
Hazardous Substance The OSHA definition of a hazardous substance is any biological agent and other disease-causing agent which after release into the environment and upon exposure, ingestion, inhalation, or assimilation into any person...will or may reasonably be anticipated to cause death, disease, behavioral abnormalities, cancer, genetic mutation, physiological malfunctions...or physiological deformations in such persons or their offspring. OSHA, 29 CFR 1910.120 (a) (3)
Container Label Exercise • Working with a partner seated next to you, read the label on the container provided by the instructor and see if you can find the elements listed on the next slide. • The container that you are using may not have all the requirements listed. OSHA 29 CFR 1910.1200 (f)
Pictograms Health Hazard Flame Exclamation Mark Gas Cylinder Corrosion Exploding Bomb Environment Skull and Crossbones Flame Over Circle OSHA 29 CFR 1910.1200, Appendix C