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有机合成反应. 唐 勇 金属有机化学国家重点实验室. 烯烃的反应 - 基本反应. § 1-5 Olefin Hydrogenation. Relevant Review articles: Angew. Chem. Int. Edit. 26, 190-203 (1987). Historically, primary stereochemical control designed around analysis of steric environment in vicinity of C=C. 烯烃的反应 - 基本反应.
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有机合成反应 唐 勇 金属有机化学国家重点实验室 Shanghai, China
烯烃的反应-基本反应 § 1-5 Olefin Hydrogenation Relevant Review articles: Angew. Chem. Int. Edit. 26, 190-203 (1987). Historically, primary stereochemical control designed around analysis of steric environment in vicinity of C=C. Shanghai, China
烯烃的反应-基本反应 § 1-5-1The influence of polar effects-Pd Thompson, J.Org. Chem. 36, 2577 (1971) Shanghai, China
烯烃的反应-基本反应 Polar functional groups may play a role in controlling the diastereoselectivity of the hydrogenation process; however, the control elements were not well-defined. J. E. McMurry et al. Tetrahedron Lett.. 3731 (1970) Shanghai, China
烯烃的反应-基本反应 Shanghai, China
烯烃的反应-基本反应 The first rational attempt to identify those FGs which will direct the reaction H. Thopson JACS 1973,95,838. Shanghai, China
烯烃的反应-基本反应 § 1-5-2The influence of polar effects-Cationic Catalysts Shanghai, China
烯烃的反应-基本反应 The first rational attempt to associate catalyst with substrate H. Thopson JACS 1974,96,6232. Shanghai, China
烯烃的反应-基本反应 Mechanism of Hydrogenation Cationic Rhodium-(I) Catalysts. Shanghai, China
烯烃的反应-基本反应 Mechanism of Hydrogenation Cationic Rhodium-(I) Catalysts. That H atom lying parallel to the pi-system (HA) should migrate preferentiallyif the dihydride is an intermediate. Shanghai, China
烯烃的反应-基本反应 Shanghai, China
烯烃的反应-基本反应 Shanghai, China
烯烃的反应-基本反应 Polar functional groups other than OH may also direct the process Shanghai, China
烯烃的反应-基本反应 Shanghai, China
烯烃的反应-基本反应 Shanghai, China
烯烃的反应-基本反应 Shanghai, China
烯烃的反应-基本反应 Shanghai, China
烯烃的反应-基本反应 Shanghai, China
烯烃的反应-基本反应 Shanghai, China
Homoallylic Alcohols Evans, Morrissey Tetrahedron Lett. 26 6005 (1985) Shanghai, China
§ 1-6 Olefin Bromination-1 § 1-6-1 Introduction Shanghai, China
Furst-Plattner Rule: A rigid cyclohexene oxide system: those stereoelectronic effects that operate in ring cleavage also influence ring formation. Shanghai, China
§ 1-7 Olefin Oxymercuration-1 Shanghai, China
Problems of the day: Shanghai, China
§ 1-7 Related Olefin Addition Rxns: Halogen Electrophiles Shanghai, China