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Soft Transducer Materials For Energy Conversion. CONTENTS. Properties. Piezoelectricity. Pyroelectricity. Ferroelectricity. Conclusion. PIEZOELECTRICITY. What is piezoelectricity ?. Response of applied mechanical stress on the material . Mechanical Stress Electric Potential.
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CONTENTS Properties Piezoelectricity Pyroelectricity Ferroelectricity Conclusion
What is piezoelectricity? Response of applied mechanical stress on the material
MECHANISM In the crystal +ve and –ve charges gets aligned symmetrically so each of the side forms an electric dipole. when a mechanical Stress is applied this symmetry is disturbed and voltage is generated
Materials used in piezoelectricity Natural crystals Man-made crystals Man-made ceramics Lead free piezoceramics Polymers
1. Berlinite(AlPO4), a rare phosphatemineral that is structurally identical to quartz 2. Cane sugar 3. Quartz 4. Rochelle salt 5. Topaz 6. Tourmaline-group minerals
crystals:- 1.quartz :- hexagonal structure, pure and contains traces of other elements Al3+, fe3+,Ti4+,P5+, H+, Li+, Na+, K+. Density=2.65gm/cm3 Shows piezoelectric effect perpendicular to prism axis.
2]aluminium orthophosphate:- Rhombic crystal, Density: 2560 kg/m³ Mol mass: 121,95 g/mol
[3]gallium orthophosphate:- colourless trigonal crystal system, similar structure to that of Quartz. It is not naturally found as the Quartz. Its piezoelectric effect is twice to that of Quartz
Barium titanate (BaTiO3)—Barium titanate was the first piezoelectric ceramic discovered. • Lead titanate (PbTiO3) • Lead zirconate titanate • Potassium niobate (KNbO3) • Lithium niobate (LiNbO3) • Lithium tantalate (LiTaO3) • Sodium tungstate (Na2WO3)
1.Gallium orthophosphate (GaPO4), a quartz analogic crystal 2.Langasite (La3Ga5SiO14), a quartz analogic crystal
Polyvinylidenefluoride (PVDF) Typical PVDF Applications • Pressure Pick Ups: distribution of pressure on surfaces, accelerometers, keyboards. • Acoustic Components: microphones, ultrasonic detectors, hydrophones, sonar • Optical Devices: laser diameter measurement,
1.electric cigarette lighter 2.Piezoelectric transformer 3.Sensor 4.Loudspeaker 5.Microphone 6.Inkjet printers 7.DANCE FLOOR
pyroelectric Materials Single Crystal Ceramics Polymers
1. TriglycineSulphate • (TGS) or ((NH2 CH2COOH)3H2SO4) • TGS has been extensively studied for • thermal imaging applications and is well known for its use in infrared detectors. • 2.LiTaO3 (Lithium Tantalate) • 3. LiNbO3 (Lithium Niobate) • 4. Sr1-x BaxNb2O6 (Strontium Barium Niobate)
1. lead zirconium titanate (PZT) • 2.Mn-doped lead • zirconate-lead-titanate-lead magnesium niobate (Pb(Mg1/3Nb2/3)O3-PbTiO3-PbZrO3)
1.Ferroelectric poly(vinylidene fluoride) [p(VdF), PVDF • or PVF2)]
1.Flame and Fire Detectors 2.IR Detector 3.Radiometers 4.Thermometers 5.Imaging
1.Spontaneous Polarization 2.Reorientation of Polarization
FERROELECTICMATERIALS 1.Tungston-Bronze group 2.Oxygen Octahedral group 3.Pyroshlore group 4.Bismth-layer Structure group
Oxygen Octahedral group ABO3perovskite type A=Pb2+ and La3+ ions B=Zr4+ and Ti4+ ions
1.Piezo- & Pyroelectricity 2.Capacitor 3.Ferroelctric Memory Technology 4.FeFET
CONCLUSION It has very large importance in our daily life as we have seen the electricity generation by soft transducer material is very easy and at very low cost
http://www.imit.kth.se/info/SSD/KMF/2B1750/07_Pyro.ppt http://www.ims.uconn.edu/~alpay/Courses/MMAT317/Ferroelectrics http://eng-sci.udmercy.edu/courses/e478/dass/courses/E452-SensorsActuators/projects/heat%20sensor.ppt http://bayes.wustl.edu/etj/articles/ferroelectricity.pdf http://eng.sut.ac.th/ceramic/old/images_news/217.pdf http://butane.chem.illinois.edu/murphycj/chem204spring2011/handouts/FerroelectricReview.pdf http://theory.caltech.edu/~politzer/supplements/ferroelectricity.pdf http://r8---sn-o097zuel.c.youtube.com/videoplayback?algorithm=throttle-factor&burst http://www.lboro.ac.uk/research/iemrc/documents/EventsDocuments/2012%20conference/presentations/whatmore.pdf BIBLIOGRAPHY
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There should be not any pores or air space. • There should not be any impurities. • There should be perfectly homogeneous material. • Leakage current should be minimum. • Insulators should be able to withstand over voltage and normal working voltage. • It should be mechanically strong to bear the conductor load.
It can assists the transmission of power across: • Densely populated urban areas • Areas where land is unavailable or planning consent is difficult . • Rivers and other natural obstacles • Land with outstanding natural or environmental heritage. • Areas of significant or prestigious infrastructural development.
It can assists the transmission of power across: • Densely populated urban areas. • Areas where land is unavailable or planning consent is difficult . • Rivers and other natural obstacles • Land with outstanding natural or environmental heritage. • Areas of significant or prestigious infrastructural development.
For harmonic variation • V(z, t)=v e^(-αz)cos(wt-βz) • I(z, t)=I e^(- αz)cos(wt-βz)
For harmonic variation • V(z, t)=V’ e^(-αz)cos(wt-βz) • I(z, t)=I’ e^(- αz)cos(wt-βz) • Where • V=voltage across z-axis • I=current across z-axis • V’=maximum voltage • I’=maximum current • α= Attenuation factor • β= phase factor