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Heat, Energy and Phase Change. Chemistry Lowell High School 2006-2007. 3/5/07 to …. Agenda. FYI’s Survey Extra Credit Acid Base Titration Lab Energy Concepts Phase Diagrams. Monday, March 5, 2007. FYI. Science Survey 3/7 Wednesday (check website)
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Heat, Energy and Phase Change Chemistry Lowell High School 2006-2007 3/5/07 to …
Agenda • FYI’s • Survey • Extra Credit • Acid Base Titration Lab • Energy Concepts • Phase Diagrams Monday, March 5, 2007
FYI • Science Survey 3/7 Wednesday (check website) • Preambles 3/8 Thursday • Acid/Base Lab 3/8 Thursday • RLog 10/14 3/12 Monday • QP 10 (1-35 odd) 3/19 Monday • QP 14 (1-41 odd) 3/26 Monday • RLog 19 3/29 Thursday Monday, March 5, 2007
Extra Credit (bring 1 or 2) • Gloves (50) M or L • Distilled Water (1 Gallon) • Medicine cups (5) • 1 pack Food coloring • 1 box baking soda • 1 25 lb bag of salt (Costco) • Sponges • 1 pack of balloons (12”) (20-25/pack) • 1 hour of work after school for Ms. Rotter • Bring these supplies M-F of this week, they will apply to this marking period • 1 10lb bag of sugar • Straws (100) • box of Alka-Seltzer • Bottle of Borax • 1 large match box Monday, March 5, 2007
Acid Base Titration Lab • Attach the peer review sheet to the front of your team’s report and put your team name on it • Exchange your copy of the report with another team. Make sure that your team’s copies all end up at DIFFERENT tables. • Write your name on the peer review sheet and look over the criteria and form Monday, March 5, 2007
Acid Base Titration Lab • Addition to the lab: • The correct concentration of the sulfuric acid was 1.8 M • In your conclusion section add a calculation of percent error with a small discussion (put in your error discussion area) • % error = measured - true x 100% true • Everyone will return the peer reviews tomorrow to the original teams. • The final lab will be due on Thursday Monday, March 5, 2007
Triple Point Super- Critical Fluid Solid Liquid Normal Pressure (kPa) Critical point Gas Temperature (K)
Triple Point Super- Critical Fluid Liquid Abnormal Solid Pressure (kPa) Critical point Gas Temperature (K)
Phase Diagrams • On the back, you will find data for another substance • Work with your teammates to determine the graph and answer the questions Monday, March 5, 2007
Agenda • FYI’s • Survey • Extra Credit • Phase Diagrams Tuesday, March 6, 2007
FYI • Science Survey 3/7 Wednesday • Preambles 3/8 Thursday • Acid/Base Lab 3/8 Thursday • RLog 10/14 3/12 Monday • Test (Chap 15/16) 3/15 Thursday • QP 14 (1-41 odd) 3/19 Monday • QP 10 (1-35 odd) 3/26 Monday • RLog 19 3/29 Thursday Tuesday, March 6, 2007
Extra Credit (bring 1 or 2) • Gloves (50) M or L • Distilled Water (1 Gallon) • Medicine cups (5) • 1 pack Food coloring • 1 10lb bag of sugar • box of Alka-Seltzer • Bottle of Borax • 1 large match box • 1 25 lb bag of salt (Costco) • 1 pack of balloons (12”) (20-25/pack) • 1 hour of work after school for Ms. Rotter • Bring these supplies M-F of this week, they will apply to this marking period Tuesday, March 6, 2007
Triple Point Super- Critical Fluid Solid Liquid Normal Pressure (kPa) Critical point Gas Temperature (K)
Triple Point Super- Critical Fluid Liquid Abnormal Solid Pressure (kPa) Critical point Gas Temperature (K)
Phase Diagrams + Lab • Finish the front and the back of the phase diagram sheet • Turn in the sheet in the back of the classroom when you are finished. • Any extra time is for your team to review the peer review sheets and prepare your lab for Thursday Tuesday, March 6, 2007
Agenda • FYI’s • Extra Credit • Temperature and Phase Changes • Heat worksheet • Preamble 12 Wednesday, March 7, 2007
FYI • Science Survey 3/7 Wednesday • Preambles 3/8 Thursday • Acid/Base Lab 3/8 Thursday • RLog 10/14 3/12 Monday • Test (Chap 15/16) 3/15 Thursday • QP 14 (1-41 odd) 3/19 Monday • QP 10 (1-35 odd) 3/26 Monday • RLog 19 3/29 Thursday Wednesday, March 7, 2007
Extra Credit (bring 1 or 2) • Gloves (50) M or L • Distilled Water (1 Gallon) • Medicine cups (5) • 1 pack Food coloring • 1 10lb bag of sugar • box of Alka-Seltzer • Bottle of Borax • 1 large match box • 1 25 lb bag of salt (Costco) • 1 pack of balloons (12”) (20-25/pack) • 1 hour of work after school for Ms. Rotter • Bring these supplies M-F of this week, they will apply to this marking period Wednesday, March 7, 2007
Team Evaluations • On a half sheet of paper, write your name and team name and answer the following questions. 1 = Yes/Great, 5 = No/Horrible • How well is your team working together? • Is everyone contributing to your team? • How much have you contributed to your team? • Do you want your team to stay together? • If you could pick one person for your team, who would it be? (no guarantees) • If there was one person you would *not* want to be with, who would it be? Wednesday, March 7, 2007
Heating/Cooling • When heating/cooling a substance, there are two options. • Temperature change in the substance • Phase change in the substance • When you heat cold liquid water, the temperature rises, but it remains liquid. • But when you reach the temperature of 100 degrees C, the water starts to boil, undergoing phase change (L G) • What is the highest temperature liquid water can reach? Wednesday, March 7, 2007
Phase Changes Gas Sublimation Condensation Boiling Deposition Melting Solid Liquid Freezing Wednesday, March 7, 2007
Phase Changes • During phase changes, bonds BETWEEN molecules break. These are called intermolecular bonds • In the middle of phase change, there is no temperature change, as all energy is going either to make or break bonds • The terms used for phase changes are fusion and vaporization (melting and boiling) Wednesday, March 7, 2007
Temperature Changes • When the phase is NOT changing, additional heat or loss of heat results in temperature change of the substance. • When the temperature changes, the speed of the molecules changes, which results in a change in kinetic energy • Overall, no bonds break during temperature changes in a substance Wednesday, March 7, 2007
Agenda • FYI’s • Extra Credit • Preamble 12 • Turn in Labs and Heat/Phase Change wkst • Phases of Matter • Heat Thursday, March 8, 2007
FYI • Preambles TODAY • Acid/Base Lab TODAY • RLog 10/14 3/12 Monday • Test (Chap 15/16) 3/15 Thursday • QP 14 (1-41 odd) 3/19 Monday • QP 10 (1-35 odd) 3/26 Monday • RLog 19 3/29 Thursday Thursday, March 8, 2007
Extra Credit (bring 1 or 2) • Distilled Water (1 Gallon) • Medicine cups (5) • 1 pack Food coloring • 1 10lb bag of sugar • box of Alka-Seltzer • Bottle of Borax • 1 large match box • 1 25 lb bag of salt (Costco) • 1 pack of balloons (12”) (20-25/pack) • 1 hour of work after school for Ms. Rotter • Bring these supplies M-F of this week, they will apply to this marking period Thursday, March 8, 2007
Preamble 12 • Make sure each of your preambles has the number and date highlighted and in order. (If not in order, indicate where out of order preambles are) • Star your best preamble and answer the following: • How does the preamble showcase your scientific thinking and reasoning skills? • What were some problems you had, and what did you learn in the course of doing that preamble? Thursday, March 8, 2007
Phases • Solid: • most intermolecular bonds • lowest kinetic energy • Fixed form/shape and volume • Liquid: • intermediate intermolecular bonds • medium kinetic energy • fluid form/shape, fixed volume • Gas: • least intermolecular bonds • highest kinetic energy • fluid form/shape and volume • Supercritical Fluid: • properties of gas and liquid • Pictures • Video Thursday, March 8, 2007
Heat • The system = reaction/chamber/thing • The surroundings = everything else (often you) • The system and surroundings have opposite reactions in terms of heat • Adding heat to the system is an endothermic process (surroundings lose, feel colder) • Heat leaving the system is an exothermic process (surroundings gain, feel warmer) Thursday, March 8, 2007
Agenda • FYI’s • Extra Credit • Hydrogen Energy Videos Friday, March 9, 2007
FYI • RLog 10/14 3/12 Monday • Test (Chap 15/16) 3/15 Thursday • QP 14 (1-41 odd) 3/19 Monday • QP 10 (1-35 odd) 3/26 Monday • RLog 19 3/29 Thursday Friday, March 9, 2007
Extra Credit (bring 1 or 2) • Distilled Water (1 Gallon) • Medicine cups (5) • 1 pack Food coloring • 1 10lb bag of sugar • box of Alka-Seltzer • Bottle of Borax • 1 large match box • 1 25 lb bag of salt (Costco) • 1 pack of balloons (12”) (20-25/pack) • 1 hour of work after school for Ms. Rotter • Bring these supplies M-F of this week, they will apply to this marking period Friday, March 9, 2007
Hydrogen Energy • You will be doing a reading log on the videos that we watch • Take down information that is new to you, surprising, or just interesting. • Most of the videos are fairly short, but packed with information. Pay close attention Friday, March 9, 2007
Agenda • FYI’s • Preamble 1 • Reading Report 10/14 • Enthalpy, Entropy and Energy Monday, March 12, 2007
FYI • RLog 10/14 TODAY • Test (Chap 15/16) 3/15 Thursday • QP 14 (1-41 odd) 3/19 Monday • QP 10 (1-35 odd) 3/26 Monday • RLog 19 3/29 Thursday Monday, March 12, 2007
Preamble 1 (5 min) • Write out the reaction discussed in the videos that uses hydrogen to make water. Is energy produced or consumed in this reaction? • What other reactions of hydrogen were discussed in the videos? • What are some of the complications you see with the use of hydrogen energy now and in the future? • What are some possible ways that those problems can be overcome? Monday, March 12, 2007
Important Reading Log Report • On your whiteboard, construct a reading report for chapter 10/14 (8 min) • Include 3 bullet points and cite section # Interconnected Interesting Incomprehensible Clarification Tuesday, February 20, 2007
Enthalpy and Entropy • DH – Enthalpy – heat energy of a reaction • if constant pressure, DH = q • negative DH = favored reaction, exothermic positive DH = not favored, endothermic • DS – Entropy – measure of disorder in the system • higher DS = more disorder, lower DS = ordered • negative DS = unfavored, positive DS = favored Monday, March 12, 2007
Energy • DG = DH – TDS (reaction at constant temperature) • Gibbs free energy – combines two driving forces on a reaction • If data is collected at standard state, a pressure of 1 bar, the driving forces can be compared. The 1 bar is arbitrary, but allows reference between all other materials and their standard states. DG° = DH° – TDS° • If DG° = negative, reaction is favored • If DG° = positive, reaction is unfavored Monday, March 12, 2007
Agenda • FYI’s • Enthalpy, Entropy and Energy • Preamble 2 Tuesday, March 13, 2007
FYI • Retakes 3/14-3/16 W-F • Test (Chap 15/16) 3/15 Thursday • QP 14 (1-41 odd) 3/19 Monday • RLog Asimov (online) 3/22 Thursday • QP 10 (1-35 odd) 3/26 Monday • RLog 19 3/29 Thursday • QP 19 • STAR Test (online) Tuesday, March 13, 2007
Enthalpy and Entropy • DH – Enthalpy – heat energy of a reaction • if constant pressure, DH = q • negative DH = favored reaction, exothermic positive DH = not favored, endothermic • DS – Entropy – measure of disorder in the system • higher DS = more disorder, lower DS = ordered • negative DS = unfavored, positive DS = favored Tuesday, March 13, 2007
Energy • DG = DH – TDS (reaction at constant temperature) • Gibbs free energy – combines two driving forces on a reaction • If data is collected at standard state, a pressure of 1 bar, the driving forces can be compared. The 1 bar is arbitrary, but allows reference between all other materials and their standard states. DG° = DH° – TDS° • If DG° = negative, reaction is favored • If DG° = positive, reaction is unfavored Tuesday, March 13, 2007
Activation Energy • Even though a reaction is favored, it may not proceed. This is due to activation energy • All reactions require some input of energy in order to get started, regardless of whether the reaction overall releases or absorbs energy. • A catalyst can be used to lower the activation energy of a reaction Tuesday, March 13, 2007
Diagram 1 Tuesday, March 13, 2007
Diagram 2 Tuesday, March 13, 2007
Agenda • FYI’s • Metal Hydrides Wednesday, March 14, 2007
FYI • Retakes 3/14-3/16 W-F • Test (Chap 15/16) 3/15 Thursday • QP 14 (1-41 odd) 3/19 Monday • RLog Asimov (online) 3/22 Thursday • QP 10 (1-35 odd) 3/26 Monday • RLog 19 3/29 Thursday • QP 19 (1-45 odd) • STAR Test (online) over spring break Wednesday, March 14, 2007
Metal Hydrides • You have sets of data for 9 metals • Properties • Thermodynamic • The goal is to rank the metals in order of which should be used as a storage metal for hydrogen powered cars • Come up with criteria for what thermo data is “good” and what properties would be “good” Wednesday, March 14, 2007
Metal Hydrides • You need to evaluate all of the data and write up a group report on the 9 metals. • Draw an activation energy diagram for each metal • Give a detailed explanation of the factors involved in your decision for each metal (discuss properties and thermo data) • Each person in the group should assume responsibility for at least 2 metals, and they must write that section of the report Wednesday, March 14, 2007