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Complex Equilibria. Metal Complex Monodentate ligands, e.g., NH 3 and Cl -. 3+. 2-. Bidentate ligands:. Chelate complexes (greek. χηλή (chēle): engl: crab, pol: kleszcze, szczypce kraba). Polydentate ligands. Chelate complexes
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Metal Complex Monodentate ligands, e.g., NH3 and Cl- 3+ 2-
Bidentate ligands: Chelate complexes (greek. χηλή (chēle): engl: crab, pol: kleszcze, szczypce kraba)
Polydentate ligands Chelate complexes (greek. χηλή (chēle): engl: crab, pol: kleszcze, szczypce kraba)
The chelate effect • Increase of diorder • Increase of entropy S
The chelate effect • Increase of diorder • Increase of entropy S Gibbs-Helmholtz Equation
The philosophy of conditional constants: Give equilibrium constants for cases deviating from the standard conditions for which the equilibrium constant of a single equilibrium is defined, i.e., give equilibrium constants for “complex conditions”