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Reactions of Alcohols

Reactions of Alcohols. Reaction Summary: 4. Hydration: Alkene + water --> alcohol 7. Dehydration: Alcohol + heat --> alkene + H 2 8. Oxidation: Pri. Alcohol + (O) --> aldehyde 9. Oxidation: Sec. Alcohol + (O) --> ketone 9B. Oxidation: Tert. Alcohol + (O) --> no reaction

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Reactions of Alcohols

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  1. Reactions of Alcohols • Reaction Summary: • 4. Hydration: Alkene + water --> alcohol • 7. Dehydration: Alcohol + heat --> alkene + H2 • 8. Oxidation: Pri. Alcohol + (O) --> aldehyde • 9. Oxidation: Sec. Alcohol + (O) --> ketone • 9B. Oxidation: Tert. Alcohol + (O) --> no reaction • 10.Oxidation: Aldehyde + (O) --> Acid • 11. Ether Synthesis: Alcohol + alcohol --> ether + HOH

  2. 4. Hydration Reaction • Alkene + HOH --> alcohol • HOH molecule adds to carbons with double bond.

  3. 7. Dehydration of Alcohol to Alkene • Subtraction: Remove -OH from alcohol carbon • Remove -H from a neighbor carbon

  4. Reactions of Alcohols

  5. 8. Oxidation of Primary Alcohol to Aldehyde • Subtraction: Remove -H from alcohol group • Remove -H from alcohol carbon

  6. Reactions of Alcohols

  7. 9. Oxidation of Secondary Alcohol to Ketone • Subtraction: Remove -H from alcohol group • Remove -H from alcohol carbon

  8. Reactions of Alcohols

  9. Reactions of Alcohols

  10. Reactions of Alcohols

  11. Reactions of Alcohols

  12. Reactions of Alcohols

  13. 10. Oxidation of Aldehyde to Acid • Add oxygen from oxidizing agent • Insert O between H of carbon double oxygen

  14. 11. Ether synthesis from 2 alcohols • Subtraction: Remove -H from one alcohol group • Remove -OH from other alcohol carbon • Join two parts

  15. Reactions of Alcohols

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