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Analytical Chemistry Analytical Chemistry : The branch of chemistry that deals with the separation, identification and determination of components in a sample. It also traditionally includes coverage of chemical equilibrium and statistical treatment of data. Qualitative analysis
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Analytical Chemistry • Analytical Chemistry: The branch of chemistry that deals with the separation, identification and determination of components in a sample. • It also traditionally includes coverage of chemical equilibrium and statistical treatment of data. • Qualitative analysis • Quantitative analysis
1- Qualitative analysis • Attempting to identify what materials are present in sample.
2- Quantitative analysis • Determining how much of material is present in a sample. The most reaction which is used in qualitative analysis can be used as a principle for quantitative analysis with some changes. • The most important thing in quantitative analysis was purity…… • Always qualitative analysis must be done before quantitative analysis…. • Weight • Volume
Chemical Methods This method depends on making a chemical reaction for the analyte and this reaction must be having some conditions. 1-Spontaneous and fast reaction 2- Irreversible reaction, and completely reacted 3- Equilibrated reaction 4- No side reaction 5- Clear equivalent point 6- Using indicators for measuring the equivalence point
Solutions • Solutions are homogeneous mixtures. • The major component is called solvent, and the minor components are called solute. • If both components in a solution are 50%, the term solute can be assigned to either component. • When gas or solid material dissolve in a liquid, the gas or solid material is called the solute. • When two liquids dissolve in each other, the major component is called the solvent and the minor component is called the solute.
Gravimetric Analysis • By definition, includes all methods of analysis in which the final stage of the analysis involves weighing. *. Volumetric Analysis • Volumetric analysis involves using volumes of liquids to analyse a concentration. To do this we need the following things: • A chemical of a known concentration that will react with our ‘unknown’ concentration chemical • An indicator that will tell us when all the chemical has been reacted • A number of pieces of equipment that we can use to measure volume accurately
Concentration expression 1- Molarity: Number of moles in one liter of solution, expressed as M. • M = (No. of mole of solute) / (volume of solvent by liter (l )). or M = (No. of mmole solute) / (volume of solvent by milliliter(ml)) M = (No. of moles) / (liter of solution) = [(gram of solute) / (M.wt.) / liter of solution]. M= [(mg of solute) / [(milliliter of solution) x M.wt.] These two equations are very important in analytical chemistry especially in preparation of solutions………….