一、主授 Lecture ：方泰山教授 , Prof. Tai-Shan Fang,

1. 高等物理化學專論(一)Special Topic on Advanced Physical Chemistry: Advanced Photochemistry 國立台灣師範大學化學研究所Ph.D. Program of Department of Chemistry九十五學年度上學期 1st Semester of 2006 Academic Year 一、主授Lecture：方泰山教授, Prof. Tai-Shan Fang, e-mail: chetsf@scc.ntnu.edu.tw http://icho.chem.ntnu.edu.tw/fang/index.htm 二、地點Class Location：C304教室 三、時間：星期三，下午2:00--5:00

4. [95 1]語音:2698(CMD0021 )課程: 高等物理化學專論（一）, 教師: 方泰山(三 7-9 Ｃ304,), 共 7人選修 (Updated Oct. 12, 2006)

5. [95 1]語音:2698(CMD0021 )課程: 高等物理化學專論（一）, (續)教師: 方泰山(三 7-9 Ｃ304,), 共 7人選修 (Updated Oct. 12, 2006)

6. 主授內容與參考資料 Lecture Contents and References為宣傳校園尊重智慧財產權，並落實保護智慧財產權執行成效，請老師輔導、提醒同學勿非法影印書籍、教材，以免侵害他人著作權。 • (1) Modern Molecular Photochemistry of Organic Molecules by Nicholas J. Turro, V. Ramamurthy, and Juan Scaiano, Forthcoming in 2007! (University Science book) Chapt. 13 and 14.(Contrained Medium Effect and Oxygen in Photochemistry) , review basic organic photochemistry • (2) Chemical Kinetics and Reaction Dynamics by Paul L. Houston, McGraw-Hill Higher Education , Chapter 7. Photochemistry (exercise) • (3) Modern Physical Organic Chemistry by Eric V. Anslyn and Dennis A. Dougherty, 2005 (University Science book), Chapter 17. Electronic Organic Materials, Solutions (exercise) • (4) Recent Literatures and Journals

7. 準備參加五個年度盛會 • 1."中研院化學所及化學中心生物無機化學小組將於十月六日及七日於舉辦2006台灣生物無機化學研討會（網址為http://www.sinica.edu.tw/chem/TBIC/TBIC.htm），自即日起開始接受投稿及報名，截稿日期及報名截止日期為八月二十日。煩請代為周知貴系與領域相關的老師與學生踴躍投稿及報名。Green Bay Howard Hotel (翡翠灣福華飯店) ;Speakers ;Programposter;Registration ;Transportation; Origin] • 2. 第一屆亞洲尖端有機化學研討會-The 1st International Conference of Cutting-Edge Organic Chemistry in Asia (ICCEOCA-1)定於10月16至10月20日於日本舉行。其ICCEOCA-1會後會定於10月21日至10月24日將在台灣新竹煙波飯店舉行; Abstract Submission (Abstract Deadline: September 15, 2006); Registration[1"十月六日及七日台灣生物無機化學研討會]; • 3.淡江大學將於95 年11/25-26 日舉辦化學年會; • 4.12月10~ 15日國際研討會：『化學動態學新趨勢：從小分子到生物體系; • 5.Dec.14-16中華民國第22屆科學教育學術研討會:

8. 95高等物理化學專論（一）by 方泰山Advanced Photochemistry化博(選修)(半)星期三, 14:00-17:00 C304 Syllabus : Modern Molecular Photochemistry of Organic Molecules Nicholas J. TurroColumbia UniversityV. RamamurthyTulane UniversityJuan ScaianoUniversity of Ottawa The course will involve a discussion of modern molecular organic photochemistry with emphasis on mechanisms. Useful texts and references

9. Forthcoming in 2007!Old Ed. 1992, OK!! • With two new co-authors, V. Ramamurthy and J.C. Scaiano, Nick Turro has completely revised and updated the 1992-edition of his benchmark text, Modern Molecular Photochemistry. The text will present, at a level understandable by seniors and first year graduate students, the first totally integrated theory of organic photochemistry, including the first visualization of the role of electron spin at all levels. In addition, chapters describing how experiment and theory can be applied to an understanding of the fundamental chromophors of organic chemistry will be presented. • If you would like to receive an e-mail announcement when this book is published, click here to send a . Please be sure to mention the title of the forthcoming book or books you would like to receive publication notification of.

10. Contents 1. Introduction and Overview2. Electronic, nuclear and spin state of electronically excited states3. Transitions between states4. Radiative transitions between states5. Radiationless transitions between states6. Theoretical organic photochemistry7. Energy and electron transfer processes8. Mechanistic organic photochemistry9. Photochemistry of carbonyl compounds10. Photochemistry of olefins11. Photochemistry of enones12. Photochemistry of aromatics13. Medium effects on photochemical processes: organized and constraining media14. Oxygen in photochemistryIndex

11. Chapter 7: Photochemistry • Paul L. Houston, “ Chemical Kinetics and Reaction Dynamics” 1st Ed. (2001) , McGraw-Hill Higher Education • This textbook, designed for upper level undergraduates and beginning graduate students, was published by WCB/McGraw-Hill but is no longer available in printed form. A few copies are left at the publisher, which will run off a separate printing if there is demand, and a few copies are left at Amazon. A separate book containing the problems and solutions to this text is also available. As soon as the rights to the text are transferred back to the author from McGraw-Hill, the text will be made available by another publisher. I am pleased that Dover has agreed to publish it. With luck, we may have copies available for the Fall semester of 2006 at a price students may be better able to afford • To obtain a copy of this book for review please visit theAmazon.com • For a (favorable) review, see Krenos, John R. J. Chem. Educ. 2001 78 1466 • Errata

12. Customer ReviewsAverage Customer Review by Yummy, December 16, 2005 • Chemical kinetics and reaction dynamics are not easy subjects, demanding quite a lot of physics in some complicated settings. Thus, it is all the more impressive that Paul Houston has managed to write this extraordinarily clear and concise text that is accessible to an advanced undergraduate. Do not get me wrong; the prerequisites for this book are extensive. A good grasp of basic newtonian mechanics, quantum mechanics, spectroscopy, and statistical thermodynamics are musts. But nothing is needed beyond what can be expected from a good, stiff one-year course in physical chemistry. From the first chapter on the kinetic theory of gases, Houston's focus on the physics - on keeping derivations short and clear, on connecting formulae with sound physical intuition - is striking. It does not lag as the book goes on. Houston continues with a clean exposition of empirical chemical kinetics and how to integrate and/or simplify the resulting differential equations. The grungy business of theoretical kinetics - how to kludge your way to a theoretical gas-phase reaction rate constant - is well treated after that. In the third chapter, Houston delivers an elegant and unified flux-driven treatment of transport phenomena. He gets the basic equations correct up to a numerical factor with a minimum of effort. This is beautiful; I wish chemical engineers would read this before beginning their own transport travails! There are then several chapters on the chemistry of more complicated systems, like solution-phase, solid surface-phase, and photochemical reactions. While I haven't read these, I am sure they are wonderful. The high point, in my opinion, is the final chapter on reaction dynamics. Its ongoing tacit motivation is the question, "How does a hydrogen fluoride laser work?" Read, and you will learn. In doing so, you will also become acquainted with the basic concepts in gas-phase reaction dynamics: the details of the crossed-beam molecular scattering experiment, the concept of a potential energy surface, and what these can tell us about reaction mechanisms. Throughout Houston, the emphasis on looking up from the math and seeing the physical big picture prevents the blind and frustrating equation-crunching which is all too common in the quantitative sciences. This little book is really amazing. It takes you from a good undergraduate background to the forefront of modern chemical physics research with minimal pain and maximal excitement. Read it.

13. Modern Physical Organic Chemistry • Dennis A. DoughertyCalifornia Institute of Technology Eric V. AnslynThe University of Texas, Austin Chapter 17: Electronic Organic Materials, Solutions

14. Dennis A. Dougherty, below, received a PhD from Princeton with Kurt Mislow, followed by a year of postdoctoral study with Jerome Berson at Yale. In 1979 he joined the faculty at the California Institute of Te chnology, where he is now George Grant Hoag Professor of Chemistry. Dougherty's extensive research interests have taken him to many fronts, but he is perhaps best known for development of the cation-π interaction, a novel but potent noncovalent binding interaction. More recently, he has addressed molecular neurobiology, developing the in vivo nonsense suppression method for unnatural amino acid incorporation into proteins expressed in living cells. This powerful new tool enables “physical organic chemistry on the brain” - chemical-scale studies of the molecules of memory, thought, and sensory perception and the targets of treatments for Alzheimer's disease, Parkinson's disease, schizophrenia, learning and attention deficits, and drug addiction. His group is now working on extensive experimental and computational studies of the bacterial mechanosensitive channels MscL and MscS, building off the crystal structures of these channels recently reported by the Rees group at Caltech. Eric V. Anslyn, right, received his PhD in Chemistry from the California Institute of Technology under the direction of Robert Grubbs. After completing post-doctoral work with Ronald Breslow at Columbia University, he joined the faculty at the University of Texas at Austin, where he became a Full Professor in 1999. He currently holds four patents and is the recipient of numerous awards and honors, including the Presidential Young Investigator, the Alfred P. Sloan Research Fellow, the Searle Scholar, the Dreyfus Teacher-Scholar Award, and the Jean Holloway Award for Excellence in Teaching. He is also the Associate Editor for the Journal of the American Chemical Society and serves on the editorial boards of Supramolecular Chemistry and the Journal of Supramolecular Chemistry. His primary research is in physical organic chemistry and bioorganic chemistry, with specific interests in catalysts for phosphoryl and glycosyl transfers, receptors for carbohydrates and enolates, single and multi-analyte sensors – the development of an electronic tongue, and synthesis of polymeric molecules that exhibit unique abiotic secondary structure.

15. CONTENTS • Chapter 1: Introduction to Structure and Models of Bonding, Solutions • Chapter 2: Strain and Stability, Solutions • Chapter 3: The Thermodynamics of Solutions and Noncovalent Binding Forces, Solutions • Chapter 4: Molecular Recognition and Supramolecular Chemistry, Solutions • Chapter 5: Acid-Base Chemistry, Solutions • Chapter 6: Stereochemistry, Solutions • Chapter 7: Energy Surfaces and Kinetic Analyses, Solutions • Chapter 8: Experiments Related to Thermodynamics and Kinetics, Solutions • Chapter 9: Catalysis, Solutions • Chapter 10: Organic Reaction Mechanisms Part 1: Reactions Involving Additions and/or Eliminations, Solutions • Chapter 11: Organic Reaction Mechanisms Part II: Substitutions at Aliphatic Centers and Thermal Isomerizations/Rearrangements, Solutions • Chapter 12: Organotransition Metal Reaction Mechanisms and Catalysis, Solutions • Chapter 13. Organic Materials Chemistry, Solutions • Chapter 14. Advanced Concepts in Electronic Structure Theory, Solutions Chapter 15: Thermal Pericyclic Reactions, Solutions • Chapter 16: Photochemistry, Solutions • Chapter 17: Electronic Organic Materials, Solutions • Appendix

16. "A REMARKABLE ACHIEVEMENT" • "Spectacular! Congratulations! I plan to recommend it to all of my research group members and to those students in my class who are getting hooked on organic chemistry. This is going to be a winner."--Peter Vollhardt, University of California at Berkeley"Anslyn and Dougherty have done an admirable and scholarly job to put the essence of this important subject between the covers of a single text. I can enthusiastically recommend the text for anyone who is teaching a course dealing with the essentials of physical organic chemistry and more."--Nicholas J. Turro, Columbia University • “The text will certainly inspire those coming to physical organic chemistry as a first love, as well as those coming from a bordering discipline who wish to acquire the insight that physical organic chemistry can provide.”--Barry Carpenter, Cornell University • “This much needed text places physical organic chemistry in its most modern context as the foundation of not only organic chemistry, but as the basis for understanding the most current research in supramolecular chemistry, organic materials science, catalysis, and organometallics. This book is the new authoritative physical organic resource that will benefit researchers, students, and teachers alike.”--Timothy M. Swager, Massachusetts Institute of Technology • "By building the text from the ground up, the authors have managed to incorporate modern applications of the theories of physical organic chemistry throughout, in a way that no revision of an existing text can hope to accomplish."–Thomas Poon, Claremont Colleges • "This is a high quality book that fills a real need in our field, and that makes every other book in this area immediately obsolete. Congratulations to the authors on a remarkable achievement!"–David I. Schuster, New York UniversityThis is the first modern textbook, written in the 21st century, to make explicit the many connections between physical organic chemistry and critical fields such as organometallic chemistry, materials chemistry, bioorganic chemistry, and biochemistry. In the latter part of the 20th century, the field of physical organic chemistry went through dramatic changes, with an increased emphasis on noncovalent interactions and their roles in molecular recognition, supramolecular chemistry, and biology; the development of new materials with novel structural features; and the use of computational methods. Contemporary chemists must be just as familiar with these newer fields as with the more established classical topics. • This completely new landmark text is intended to bridge that gap. In addition to covering thoroughly the core areas of physical organic chemistry – structure and mechanism – the book will escort the practitioner of organic chemistry into a field that has been thoroughly updated . The foundations and applicabilities of modern computational methods are also developed. • Written by two distinguished researchers in this field, Modern Physical Organic Chemistry can serve as a text for a year-long course targeted to advanced undergraduates or first-year graduate students, as well as for a variety of shorter courses on selected aspects of the field. It will also serve as a landmark new reference text, and as an introduction to many of the more advanced topics of interest to modern researchers. An accompanying Student Solutions Manual will become available.

17. Student Solutions Manualto accompany Modern Physical Organic Chemistry • The Author sMichael B. Sponsler earned his PhD from the California Institute of Technology in 1987, working as an NSF Graduate Fellow with Dennis A. Dougherty. He did research as an NIH Post-doctoral Fellow with Robert G. Bergman at the University of California, Berkeley and then accepted a faculty position at Syracuse University in 1989, where he is now Associate Professor. His research involves physical organic studies in the diverse areas of conjugated organometallic complexes and liquid crystalline holographic recording materials. The organometallic studies include synthesis and characterization of both mixed-valence complexes with polyenediyl bridges and related polymers. Applications in molecular electronics and nanotechnology are under investigation. The holographic studies are focused on new strategies for producing electrically switchable holograms. • Bios for Eric V. Anslyn and Dennis A. Dougherty can be found by linking to the page for their textbook,Modern Physical Organic Chemistry

18. PhotochemistryInvited Lecturers : Yuan-Pern Lee (chairperson), National Chiao-Tung UniversityChi-Kung Ni, Institute of Atomic and Molecular Sciences, Academia Sinica , Arthur G. Suits, Wayne State University Mitchio Okumura (chairperson), California Institute of Technology, Robert E. Continetti, University of California, San Diego Cheuk-Yiu Ng, University of California, Davis

19. 考試及成績計算 Exams and Evaluation （1）Advanced Photochem Exam 50% (closed book 2 hours exam, Nov.15) （2）Term Paper 25%（Reviews on the subject in your research field） (3）Seminar Presentation 25% (your research and proposal for future)