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Bonding and Nomenclature. Ionic. Valence Electrons. Electrons in the highest occupied energy levels of an atom Number of valence electrons largely determines the chemical properties of an element. Octet Rule. A stable atom contains 8 valence electrons
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Bonding and Nomenclature Ionic
Valence Electrons • Electrons in the highest occupied energy levels of an atom • Number of valence electrons largely determines the chemical properties of an element
Octet Rule • A stable atom contains 8 valence electrons • Atoms will try to achieve this stable configuration
Cations • Any atom or group of atoms with a positive charge • Neutral atoms loses electrons • Group I and group II metals, other metals, transition and inner transition metals and Al Group 1 form +1 ion Group 2 form +2 ions Al forms +3 ion Ag forms +1 ion Cd forms + 2 ion Zn forms +2 ion
Anions • Atoms or group of atoms with a negative charge • Neutral atom gains electrons • Group VII, VI, V • Non-metals
Lewis Electron Dot Diagrams • Show only the valence electrons • Valence electrons are represented as dots • Which group of the periodic table does Li belong to? • Write the electron configuration for Li • 1s22s1
Draw Electron Dot Diagrams • Na K Be Mg • Ca Cl F Br • O S Se
Determine Valence Electrons • ELEMENT#valence electonsgroup # • Rb • Calcium • Al • Iodine • Bromine • O • F • Sodium
Determine Valence Electrons • ELEMENT#valence electonsgroup # • Rb 1 1 • Calcium 2 2 • Al 3 3 • Iodine 7 7 • Bromine 7 7 • O 6 6 • F 7 7 • Sodium 1 1
Existence Of Ions • Predict whether the following ions are likely to exist. • H- H+ Sr2+ Al3+ • Xe- Zn6- Zn2+
Ionic Compounds • Composed of a cation and an anion • Cation is always written first • Cation donates electrons and the anion takes electrons so that all atoms have 8 electrons in their valence shell
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Formula Unit • ·Is a chemical formula that shows the kinds and numbers of atoms in an ionic substance • ·The lowest whole number ration of ions in a compound • ·The compound has a neutral charge
Writing Formula Units • Cation(+) first • Anion(-) last • Subscripts after anion and/or cation to indicate how many are necessary to create a neutral compound
Naming Ionic Compounds Binary ionic compound: cation name remains the same, anion ending changes to “ide” NaCl MgCl2 AlF3
Write The Formulas • Rubidium chloride • Barium nitride • Aluminum sulfide • Sodium fluoride • Magnesium oxide
Naming Ionic Compounds • Ternary ionic compound: cation name remains the same, anion is the same as the polyatomic ion • Na2CO3 • Al2(SO4)3
Naming Ionic Compounds • Transition and other metals: use a roman numeral after the cation to specify the ionic charge of the cation • CuSO4 • Cr2O3 • Fe(CN)2
Classical Name • Formula Stock Name Classical Name • Cu+ copper(I) ion Cuprous ion • Cu2+ copper(II) ion Cupric ion • Fe2+ iron(II) ion Ferrous ion • Fe3+ iron(III) ion Ferric ion • Exceptions: Ag+, Cd2+, Zn2+
Naming Acids • Anion • EndingAcid NameExample 1. -ide begins with hydro, HCl ends with -ic and acid 2. –ite ends with –ous and acid H2SO3 3. –ate ends with –ic and acid H2SO4
Common Acids • HCl Hydrochloric Acid • H2SO4 Sulfuric Acid • HNO3 Nitric Acid • HC2H3O2 Acetic Acid • H3PO4 Phosphoric Acid • H2CO3 Carbonic Acid
Properties of Ionic Compounds Hard crystalline solids High melting points Conduct electricity in solution or molten
Naming Ionic Compounds • Silver nitrate 12. Copper(II) sulfate • Iron(II) phosphate 13. Cobalt(II) iodide • Chromium(III) oxide 14. Cesium phosphate • Nickel(II) fluoride 15. Magnesium acetate • Copper(I) nitrate 16. Potassium oxide • Lead(II) carbonate 17. Strontium nitrate • Iron(II) fluoride 18. Aluminum sulfate • Iron(III) hydroxide 19. Calcium chlorate • Zinc phosphate 20. Rubidium cyanide • Potassium chlorate 21. Tin(IV) oxide • Ammonium chromate 22. Titanium(II) iodide
Ionic Formulas • BaCl2 10. FeCl3 • Pb(NO3)2 11. Ca(CN)2 • TiI3 12. Cu2S • NH4OH 13. Ag2CO3 • K2CrO4 14. Cd(ClO)2 • CoO 15. SnO2 • Mg(ClO4)2 16. NaHCO3 • CuSO4 17. Al(C2H3O2)3 • Na2SO3 18. Ni3(PO4)2
Quest: Ionic Compounds • If anion is a non-metal, then change ending to –ide. • If anion is a polyatomic ion, then simply use name of polyatomic ion. • If cation is a transition metal or other metal, then need roman numeral to clarify the charge of the cation. Exceptions: Ag, Zn, Cd, Al. • Acid formulas always have H+ as the cation. Know the six acids in your notes.