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acid ionization constant K a. HX ↔ X - + H + [ X - ] [ H + ] K a = ------------------ [ HX ]. base ionization constant K b. X + H 2 0 ↔ HX + + OH - [ HX + ] [ OH - ] K b = ------------------ [ X ].
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acid ionization constant Ka HX ↔ X- + H+ [X-] [H+] Ka = ------------------ [HX]
base ionization constant Kb X + H20 ↔ HX++ OH- [HX+] [OH-] Kb = ------------------ [X]
Write ionization equations and acid ionization constant expressions for the following acids.
HF HF ↔ H++ F-
HF HF ↔ H++ F- [F-][H3O+] Ka = ------------------ [HF]
HF HF ↔ H++ F- [F-][H+] Ka = ------------------ [HF]
HCN HCN ↔ H++ CN-
HCN HCN ↔ H++ CN- [CN-][H3O+] Ka = ------------------ [HCN]
HCN HCN ↔ H++ CN- [CN-][H+] Ka = ------------------ [HCN]
Write ionization equations and base ionization constant expressions for the following bases.
CH3NH2 CH3NH2+ H2O↔ CH3NH3+ + OH-
CH3NH2 CH3NH2+ H2O↔ CH3NH3+ + OH- [CH3NH3+ ][OH-] Kb = ------------------------- [CH3NH2]
Quick Work Use the next ten minutes to do problems 10 & 11 on pages 605 & 606
HClO2 HClO2↔ H++ ClO2-
HClO2 HClO2↔ H++ ClO2- [ClO2-][H3O+] Ka = ------------------ [HClO2]
HClO2 HClO2↔ H++ ClO2- [ClO2-][H3O+] Ka = ------------------ [HClO2]
HNO2 HNO2↔ H++ NO2-
HNO2 HNO2↔ H++ NO2- [NO2-][H3O+] Ka = ------------------ [HNO2]
HNO2 HNO2↔ H++ NO2- [NO2-][H3O+] Ka = ------------------ [HNO2]
HIO HIO↔ H++ IO-
HIO HIO↔ H++ IO- [IO-][H3O+] Ka = ------------------ [HIO]
HIO HIO↔ H++ IO- [IO-][H3O+] Ka = ------------------ [HIO]
C6H13NH2 C6H13NH2+ H2O↔ C6H13NH3+ + OH-
C6H13NH2 C6H13NH2+ H2O↔ C6H13NH3+ + OH- [C6H13NH3+ ][OH-] Kb = ------------------------- [C6H13NH2]
C6H13NH2 C6H13NH2+ H2O↔ C6H13NH3+ + OH- [C6H13NH3+ ][OH-] Kb = ------------------------- [C6H13NH2]
C3H7NH2 C3H7NH2+ H2O↔ C3H7NH3+ + OH-
C3H7NH2 C3H7NH2+ H2O↔ C3H7NH3+ + OH- [C3H7NH3+ ][OH-] Kb = ------------------------- [C3H7NH2]
C3H7NH2 C3H7NH2+ H2O↔ C3H7NH3+ + OH- [C3H7NH3+ ][OH-] Kb = ------------------------- [C3H7NH2]
CO32- CO32- + H2O↔ HCO3- + OH-
CO32- CO32- + H2O↔ HCO3- + OH- [HCO3-][OH-] Kb = ------------------------- [CO32-]
CO32- CO32- + H2O↔ HCO3- + OH- [HCO3- ][OH-] Kb = ------------------------- [CO32-]
HSO3- HSO3-+ H2O↔ H2SO3+ OH-
HSO3- HSO3-+ H2O↔ H2SO3+ OH- [H2SO3][OH-] Kb = ------------------------- [HSO3-]
HSO3- HSO3-+ H2O↔ H2SO3+ OH- [H2SO3][OH-] Kb = ------------------------- [HSO3-]