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Limiting Reactants and ICE Charts. “Chemistry” Salami Sandwiches Question: If you are given one dozen loaves of bread, a gallon of mustard and three pieces of salami, how many salami sandwiches can you make? Answer : Give reasons. Chemistry Cake. Chemistry Cake
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“Chemistry” Salami Sandwiches Question: If you are given one dozen loaves of bread, a gallon of mustard and three pieces of salami, how many salami sandwiches can you make? Answer: Give reasons
Chemistry Cake You have 20 cups of flour, 8 cups of sugar, 30 litres of milk and 48 eggs in your kitchen. The recipe for chemistry cake is:
Chemistry Cake You have 20 cups of flour, 8 cups of sugar, 30 litres of milk and 48 eggs in your kitchen. The recipe for chemistry cake is: 3 cups of flour 2 cups of sugar 2 litres of milk + 6 eggs = 1 chemistry cake
How many cakes can you make? • Which ingredient ran out first and limited the number of cakes you could make?
How many cakes can you make? • Which ingredient ran out first and limited the number of cakes you could make? • What and how much of each ingredient is left over?
How many cakes can you make? • Which ingredient ran out first and limited the number of cakes you could make? • What and how much of each ingredient is left over? • What does this assignment have to do with chemistry?
In the chemical reaction: 2 Al + 3 Br2 2 AlBr3
In the chemical reaction: 2 Al + 3 Br2 2 AlBr3
In the chemical reaction: 2 Al + 3 Br2 2 AlBr3 2 moles of Al require 3 moles of Br2 to produce 2 moles of AlBr3
In the chemical reaction 2 Al + 3 Br2 2 AlBr3 2 moles of Al require 3 moles of Br2 to produce 2 moles of AlBr3 What if Al and Br2 are not present in a perfect 2 : 3 ratio?
Answer: One reactant runs out:
Answer: One reactant runs out: There is a reactant left over:
Answer: One reactant runs out: Limiting Reactant There is a reactant left over:
Answer: One reactant runs out: Limiting Reactant There is a reactant left over: Excess Reactant
Answer: One reactant runs out: Limiting Reactant There is a reactant left over: Excess Reactant We use an ICE chart to find out how much reactant in excess is left over and how much product is produced.
Answer: One reactant runs out: Limiting Reactant There is a reactant left over: Excess Reactant We use an ICE chart to find out how much reactant in excess is left over and how much product is produced. I = Initial moles (unreacted reactants)
Answer: One reactant runs out: Limiting Reactant There is a reactant left over: Excess Reactant We use an ICE chart to find out how much reactant in excess is left over and how much product is produced. I = Initial moles (unreacted reactants) C = Change in moles (reactants consumed & products produced)
Answer: One reactant runs out: Limiting Reactant There is a reactant left over: Excess Reactant We use an ICE chart to find out how much reactant in excess is left over and how much product is produced. I =Initial moles (unreacted reactants) C = Change in moles (reactants consumed & products produced) E = End moles
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made.
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I C E Write down the INITIAL moles given in the question. If grams given we need to convert to moles.
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C E
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C E Now CALCULATE the moles of each reactant needed for the reaction. Start with whichever element you want.
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C E 12.0 mol O2
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C E 12.0mol O2 x 2 mol Ca 1 mol O2
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C E 12.0 mol O2 x 2 mol Ca = 24.0 mol Ca 1 mol O2
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C E 12.0 mol O2 x 2 mol Ca = 24.0 mol Ca 1 mol O2 Don’t have enough Ca!
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C E 12.0 mol O2 x 2 mol Ca = 24.0 mol Ca 1 mol O2 Don’t have enough Ca ! 12.0 mol Ca x 1 mol O2 = 6.00 mol of O2 2 mol Ca Yahooooo! Enough O2 !!! This means for all 12 moles of Ca to be used up we need 6 moles of O2.
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C 12.0 mol 6.0 mol E
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C 12.0 mol 6.0 mol E Since the limiting reagent determines how much product is formed we use the moles of limiting reagent to determine the moles and mass of product
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C 12.0 mol 6.0 mol E 12.0mol Ca
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C 12.0 mol 6.0 mol E 12.0mol Ca x 2 mol CaO 2 mol Ca
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C 12.0 mol 6.0 mol E 12.0mol Ca x 2 mol CaO= 12.0 mol CaO 2 mol Ca
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C 12.0 mol 6.0 mol 12.0 mol E
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C -12.0 mol -6.0 mol +12.0 mol E Now complete the ICE chart by filling in the END amounts of each species.
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C -12.0 mol -6.0 mol +12.0 mol E 0 mol
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C -12.0 mol -6.0 mol +12.0 mol E 0 mol 6.0 mol
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C -12.0 mol -6.0 mol +12.0 mol E 0 mol 6.0 mol 12.0 mol
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C -12.0 mol -6.0 mol +12.0 mol E 0 mol 6.0 mol 12.0 mol Limiting Reactant
12.0 mole Ca and 12.0 mole O2 react. Find the limiting reactant, the amount of excess reactant and the amount of product made. 2 Ca + 1 O2 2 CaO I 12.0 mol 12.0 mol 0 C -12.0 mol -6.0 mol +12.0 mol E 0 6.0 mol 12.0 mol Limiting Excess Reactant Reactant
24.0 mole of Al reacts with 24.0 mol of Br2. Find the limiting reactant, the amount of the excess reactant and the amount of product made.
24.0 mole of Al reacts with 24.0 mol of Br2. Find the limiting reactant, the amount of the excess reactant and the amount of product made. 2 Al + 3 Br2 2 AlBr3
24.0 mole of Al reacts with 24.0 mol of Br2. Find the limiting reactant, the amount of the excess reactant and the amount of product made. 2 Al + 3 Br2 2 AlBr3 I C E Write down the INITIAL amounts given in the question
24.0 mole of Al reacts with 24.0 mol of Br2. Find the limiting reactant, the amount of the excess reactant and the amount of product made. 2 Al + 3 Br2 2 AlBr3 I 24.0 mol 24.0 mol 0 mol C E
24.0 mole of Al reacts with 24.0 mol of Br2. Find the limiting reactant, the amount of the excess reactant and the amount of product made. 2 Al + 3 Br2 2 AlBr3 I 24.0 mol 24.0 mol 0 mol C E Now CALCULATE the moles of each reactant needed for the reaction. Start with whichever element you want.