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Biochar Properties. is biochar a nutrient?. is biochar a fertilizer?. In soil, charcoal breaks down very slowly. – not in months, but decades, even centuries. Compost. Pyrolysis. not affected by weathering, oxidation & digestion. 500+°C. 100. Biochar isn ’ t consumed by soil life.
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Biochar Properties is biochar a nutrient? is biochar a fertilizer? In soil, charcoal breaks down very slowly – not in months, but decades, even centuries Compost Pyrolysis not affected by weathering, oxidation & digestion 500+°C 100 Biochar isn’t consumed by soil life Fresh from a burner, biochar is sterile, with no biological activity – no microbes – and hydrophobic – it repels water Adding only raw charcoal to soil Dr. Johannes Lehman ? 50 retards plant growth 1 or 2 years Centuries? Carbon remaining (%) Biochar Fertilizers must be added with charcoal Millennia? Biochar supplies three important soil services: Uncharred Biomass : Habitat and housing for microbes Sponge : Absorb, hold & conserve soil water 10 Humus Storehouse : Adsorp nutrient ions (C.E.C. & A.E.C.) 5 4 3 2 1 Substrate Years
Biochar Properties Physical Properties • Particle size • Particle size • Surface area • Residence Time • Structural density • Micropore density • Moisture content • Water Absorption • Ion Adsorption • CEC • pH • Microbial Activity • Micropore density • Water Absorption & AEC & AEC • CEC • Microbial Activity
Biochar Properties Particle Size Surface area External:square inches vs. square miles Internal: micropores Varied sizes varied purposes: broadcast, seed drill, potting mix, hydroponics Gravel Rice grain Powder & Dust Water soluble: lowest molecular weight Micronize: Nature’s nanotechnology Brittle: easy to crush Dusty: easily blows away Variable: with feedstock Woody vs. Weedy Screen: separate sizes Intimate mix: at cellular and molecular scales PHOTO: Bob Cirino, University of Delaware S4700 3.0kV 11.9mm x 300 SEM 12/2/13
Biochar Properties Residence Time Pyrolysis Resists chemical & weathering action Resists microbial digestion & decay Sequestration = at least 100 years Dr. David Laird, USDA Tilth Lab: 1600 year half-life • Recalcitrant 100 • 1 to 5% loss Tar & Resins Residues (VOC & PAH) Hydrophobic (oily hydrocarbons) 50 1−5% Carbon remaining (%) 35−50% Biochar • Vary with production process Temperature: 500-700°C (energy only: up to 1500°C) Pressure, Length of Time, Steam Gasification vs. Pyrolysis (burning vs. baking) Torrefication, Fast Pyrolysis, Flash Pyrolysis, Microwave Composted Biomass 10 Humus 10−15% 4 1 5 2 3 Years