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The study of two previous papers in REMPI sepectra. Jingming Long 2010.03.29.
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The study of two previous papers in REMPI sepectra Jingming Long 2010.03.29
Agust Kavran, Huasheng Wang, Ashildur Logadottir. Resonance enhanced multiphoton ionization of hydrogen halides: rotational structure and anomalies in Rydberg and ion-pair states of HCL and HBr[J]. J.Chemical Physics. 2000,112(24):10811-10820. Support Conform • Agust Kavran, Huasheng Wang, Kristian Matthiasson, et al. Two-dimensional (2+n) resonance enhanced multiphoton ionization of HCl: photorupture channels via the F 1∆2 Rydberg state and ab initio spectra[J]. J.Chemical Physics. 2008,129:164313.
Repulsion Compression
Resonance Interaction: • HCl b) HBr
Perturbed Unperturbed From experiment data From theory calculation W12
What can we use? TECHNOLOGY: REMPI-TOF ANALYSIS METHOD: Power Dependence Theory Simulation 2D(m+n), m=2,3. n=1,2.. What do we mainly do? • Find new states. • Derive the energy of vibrational and rotational levels • Simulate relevant spectra. • Compare experiment data with theory result and obtain spectroscopic parameters. • Interpret photodissociation and photoionization mechanism.