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Physical Science Applications in Agriculture. Unit Physical Science Systems. Problem Area. Agricultural Production Systems. Testing Common Substances for pH. Lesson. Ever see limestone being applied on a grower’s field?. What is so important about this powdery substance?
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Physical Science Applications in Agriculture Unit Physical Science Systems
Problem Area Agricultural Production Systems
Ever see limestone being applied on a grower’s field? • What is so important about this powdery substance? • What does it do for the soil? • Does the composition or type of limestone (liquid, dry, palletized) make a difference in its effectiveness? .acadianashell.co.com/OFFLOADING3.JPG
Which plant looks healthier? • Examine the pictures or actual plants that have received different levels of fertilizer. • Which plant looks healthier? • Which plant would produce better and more product? • How much fertilizer do they apply to get optimum growth of our vegetable plants? • Is there a way to determine this? How?
Learning Objectives • Define pH and discuss its role in plant nutrition. • Explain how soils become acidic. • Explain how soil pH is measured. • Explain why lime is applied to acid soils. • Discuss the effectiveness of lime on acidic soils.
Terms • Acid • Calcium carbonate equivalent • Cation • Cation exchange capacity • Lime requirement • Percent base saturation • pH scale • Soil pH
What is pH? • Soil pH is the measure of acidity or alkalinity of the soil.
What is the pH scale? • The pH scale is a fourteen point scale used to measure pH. • A neutral pH is 7.0. • A solution with a pH between zero and 6.9 is considered acid. • A solution with a pH between 7.1 and 14.0 is considered alkaline or base. • The scale is expressed in logarithmic terms. • Each unit change in pH corresponds to a tenfold change in acidity or alkalinity. • A pH of 6.0 is 10 times more acidic than a pH or 7.0.
How does pH affect plant nutrition? • The pH value of soil is important to agriculturalists because certain nutrients become unavailable to plants if the pH value is too high or too low. • The amount of nutrients that are available is dependent upon soil pH.
How do soils become acidic? • pH is determined by the concentration of hydrogen (H+) ions and hydroxyl ions (OH-) in the soil solution.
How do soils become acidic? • A sample of pure water has an equal number of H+ and OH- and is neutral. • An acid is a substance that releases hydrogen ions. • When saturated with H+, a soil behaves as a weak acid. • The more H+ held on the exchange complex, the greater the soil’s acidity.
Several factors influence soil pH. • Soil organic matter is continuously being decomposed by micro organisms into organic acids, carbon dioxide, and water, forming carbonic acid. • Carbonic acid reacts with Ca and Mg carbonates in the soil to form more soluble bicarbonates, which are leached away, leaving the soil more acid.
Several factors influence soil pH. • As water from rainfall passes through the soil, basic nutrients such as calcium and magnesium are leached. • They are replaced by acidic element including aluminum, hydrogen, and manganese. www.goeverett.com/misticbev/assets/images
Several factors influence soil pH. • Soils formed under forest vegetation tend to be more acidic than those developed under grasslands. www.itc.nl/personal/.../t1765e0s.htm
Several factors influence soil pH. • Soils often become more acidic when crops are harvested because bases are • removed. • Legumes generally contain higher levels of bases than grasses. • Legumes also release H+ ions into their rhizosphere when actively fixing atmospheric N.
Several factors influence soil pH. • Nitrogen from fertilizer, organic matter, manure, and legume N fixation produces acidity. • Nitrogen fertilization speeds up the rate at which acidity develops. • At lower N rates, acidification rate is slow, but is accelerated as N fertilizer rates increase.
How is soil pH measured? • The two most commonly accepted methods of measuring soil pH are indicator dyes and the pH meter. ltpwww.gsfc.nasa.gov...globe/pvg/19-5ph.jpg
Indicators are frequently used in the field to make a rapid pH determination and must be used by a trained hand to avoid major error. The more accurate and widely used method is the pH meter used in soil testing laboratories. How is soil pH measured? www.bbc.net.uk/garde...asics/soil_test7.jpg
Why is lime applied to acidic soils? • Since various plants require different pH levels for optimum growth, growers must attempt to adjust soil pH to suit the crop or plant being grown. • This involves the use of limestone to raise pH or the use of alum to lower pH. • Lime requirement is the amount of agricultural limestone needed to establish the desired pH range.
Why is lime applied to acidic soils? • Soil pH is an excellent single indicator of soil acidity, it does not determine lime requirement. • Lime requirement of a soil is not only related to the pH but also to its buffer capacity or cation exchange capacity. • Cation exchange capacity is the total number of exchangeable cations, an ion with a positive charge, a soil can adsorb. • The relative amount of the cation exchange capacity filled with basic cations is called percent base saturation. • Soil pH is a measure of the percent base saturation.
Why is lime applied to acidic soils? • Lime replaces hydrogen and aluminum on the cation exchange sites with calcium and changes hydrogen ions to water. www.imdexminerals.com.au/ag.asp
Factors to figure how much lime is required • the present pH • the desired pH • the cation exchange capacity of the soil • the liming material to be used www.hort.wisc.edu/.../soiltest/soiltest.htm
The effectiveness of lime on soil. • The effectiveness of lime depends on: • Purity • Fineness • Rate it dissolves • Measured as the calcium carbonate equivalent
What determines the effectiveness of lime on acid soils? • The neutralizing power of lime depends upon its purity, measured as the calcium carbonate equivalent. • Neutralizing values of all liming materials are determined by comparing them to the neutralizing value of pure claim carbonate. • Setting the neutralizing value of calcium carbonate at 100, a value for other materials can be assigned.
What determines the effectiveness of lime on acid soils? • When a given quantity of lime is mixed with the soil, its reaction rate and degree of reactivity are affected by particle size. • Coarse live particles react more slowly and less fully. • Fine lime particles react more rapidly and much more completely. • Cost of lime increases with the fineness of grind. • The goal is a material that requires a minimum of grinding, yet contains enough fine material to cause a rapid pH change.
Other important factors determining the effectiveness of lime • Placement for maximum contact with the soil in the tilled layer is essential. • Even when properly mixed with the soil, lime will have little effect on pH if the soil is dry. • Moisture is essential for lime-soil reaction to occur. • The full benefit of lime is not seen until the second or third year after application. • Lime does not react with acidic soil very far from the lime particle.
Review/Summary • What is pH and how does it affect plant nutrition? • How do soils become acidic? • How is soil pH measured? • Why is lime applied to acidic soils? • What determines the effectiveness of lime on acid soils?