100 likes | 468 Views
Dendritic polymer systems. (see Prosa, Bauer, Amis, Tomalia, & Scherrenberg, J. Polymer Sci. B. Polymer Physics (1997) 35 , 2913-2924. A SAXS study of the internal structure of dendritic polymer systems ) Increased branching density Dendrimers Hyperbranched polymers.
E N D
Dendritic polymer systems (see Prosa, Bauer, Amis, Tomalia, & Scherrenberg, J. Polymer Sci. B. Polymer Physics (1997) 35, 2913-2924. A SAXS study of the internal structure of dendritic polymer systems) Increased branching density Dendrimers Hyperbranched polymers
Dendritic polymer systems (see Prosa, Bauer, Amis, Tomalia, & Scherrenberg, J. Polymer Sci. B. Polymer Physics (1997) 35, 2913-2924. A SAXS study of the internal structure of dendritic polymer systems) Polyamidoamine (PAMAM) dendrimers in 1% MeOH solns From saxs, get Rg ––> size, shape info
Dendritic polymer systems (see Prosa, Bauer, Amis, Tomalia, & Scherrenberg, J. Polymer Sci. B. Polymer Physics (1997) 35, 2913-2924. A SAXS study of the internal structure of dendritic polymer systems) Polyamidoamine (PAMAM) dendrimers in 1% MeOH solns From saxs, get Rg ––> size, shape info Zimm plot: lim (Kc/I(q,c)) = 1/(Mw P(q) = (1/Mw) (1 + (1/3) <Rg2>2 q2 + ….) P(q) = form or shape factor c–>0
Dendritic polymer systems Polyamidoamine (PAMAM) dendrimers in 1% MeOH solns
Dendritic polymer systems Polyamidoamine (PAMAM) dendrimers in 1% MeOH solns
Dendritic polymer systems Polyamidoamine (PAMAM) dendrimers in 1% & 26% MeOH solns
Dendritic polymer systems Dendrimers & hyperbranched polymers