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Bond & Group Enthalpies. The standard entahlpy change associated with breaking the bond in a diatomic molecule in the gas phase: N N (g) -------> 2 N (g) D H [N N] = + 946 kJ / mole of N N bonds
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Bond & Group Enthalpies The standard entahlpy change associated with breaking the bond in a diatomic molecule in the gas phase: N N (g) -------> 2 N (g) DH [N N] = + 946 kJ / mole of N N bonds is a measure of the strength of that bond (in this case the N N triple bond) and is refered to as a bond enthalpy or sometimes less rigorously as a bond energy. At 298 K what strictly speaking is the bond energy of a N N triple bond? Note that energy had to be transferred into the N N bond in order to break it and bond breaking is always an endothermic process. Is bond formation endothermic or exothermic? The standard enthalpy of formation of oxygen atoms in the gas phase is + 247.5 kJ / mole of oxygen atoms. What is the bond enthalpy of an O = O double bond? 18.1
Defining bond enthalpies in polyatomic molecules is more ambiguous! Consider the N-H single bond energies in NH3. Spectroscopic studies have allowed us to determine the enthalpies of the following three bond breaking processes: NH3 (g) -----> NH2 (g) + H (g) DH = + 460 kJ/mole NH2 (g) -----> NH (g) + H (g) DH = + 399 kJ/mole NH (g) -----> N (g) + H (g) DH = + 314 kJ/mole Which one of these three values should we use for the N-H bond enthalpy? What is actually done is to use the average of these three values as measure of the average N-H bond enthalpy in NH3. DHN-H average = + 391 kJ/mole of N-H bonds The utility of bond enthalpies is that at a certain level of approximation they are transferable from one compound to another. For example we can use the N-H bond enthalpy that we already know to calculate the N=N double bond enthalpy in the compound diimine: The enthalpy change for completely dissociating diimine into constituent atoms in the gas phase is: H N=N (g) -------> 2 N (g) + 2 H (g) DH= +1,200 kJ/mole H DH= +1,200 kJ/mole = (1 mol) DH [N=N] + (2 mol) DH [N-H] = (1 mol) DH [N=N] + (2 mol) (+391 kJ/mole) from which we calculate the N=N double bond enthalpy as: DH [N=N] = + 418 kJ/mole 18.2
In this manner tables of bond enthalpies can be constructed: DH [N - N] + 391 kJ/mole DH [N = N] + 418 kJ/mole DH [N N] + 946 kJ/mole How are bond order (i.e., whether a bond is single, double, triple, etc.) and bond enthalpy related? A partial table of single bond enthalpies is shown below: H-H 436 kJ/mole H-F 563 kJ/mole C-C 348 kJ/mole H-Cl 432 kJ/mole N-N 161 kJ/mole H-Br 366 kJ/mole O-O 139 kJ/mole H-I 299 kJ/mole F-F 153 kJ/mole C-N 292 kJ/mole Cl-Cl 243 kJ/mole C-O 351 kJ/mole Br-Br 193 kJ/mole C-S 259 kJ/mole I-I 151 kJ/mole C-F 441 kJ/mole C-H 413 kJ/mole C-Cl 328 kJ/mole N-H 391 kJ/mole C-Br 276 kJ/mole S-S 213 kJ/mole C-I 240 kJ/mole O-H 463 kJ/mole S-H 339 kJ/mole A partial table of multiple bond enthalpies is shown below: C=C 615 kJ/mole C=S 477 kJ/mole C=N 615 kJ/mole N=N 418 kJ/mole O=O 495 kJ/mole C=O 728 kJ/mole C=O 686 kJ/mole (formaldehyde) C=O 715 kJ/mole (other aldehydes) CC 946 kJ/mole NN 946 kJ/mole CN 891 kJ/mole (nitriles) CN 866 (HCN) 18.3
Note that bond enthalpies are associated with a process in which the reactants and products are in the gas phase. If other phases are present, then other enthalpy changes have to be included in the overall enthalpy change. Use bond enthalpies to estimate the standard enthalpy of formation of CO2 (g). In addition to data that can be found in the preceeding table of bond enthalpies you will need the heat of sublimation of graphite which is +713.0 kJ/mole. Bond enthalpies can be used to estimate the heats of reactions that might otherwise be difficult to measure. For example we can use bond enthalpies to estimate the standard heat of formation of hydrogen azide, HN3 (g), an explosive compound. We will proceed by breaking all the bonds in the reactants (an endothermic process) to form a collection of atoms in the gas phase that we will then reassemble into the products (an exothermic process): H 1/2 H2 (g) + 3/2 N2 (g) --------> N=N=N (g) - 2 DH [N=N] - 1 DH [N-H] = -2 (+ 418 kJ) - 1 (391 kJ) = -1,227 kJ 1/2 DH [H-H] = 1/2 (+ 436 kJ) = + 218 kJ 3/2 DH [N N] = 3/2 (+ 946 kJ) = + 1,419 kJ [ H (g) + 3 N (g) ] DHof [HN3 (g)] = (+ 218 kJ) + (+1,429 kJ) + (-1,227 kJ) = + 410 kJ 18.4
Use bond enthalpies to estimate the heat of isomerization of cyclopropane to propene in the gas phase: H H C --------> CH3CH=CH2 (g) C C H H (g) H H The experimental value is -32.88 kJ. Why do you think the experimental value and the value calculated from bond enthalpies are so different? Could you use the value you calculated and the experimental value to estimate the strain enthalpy in cyclopropane? The standard enthalpy of formation of ozone, O3 (g), is +142.7 kJ/mole. Estimate the strength of an oxygen oxygen partial double bond, O O. 18.5
- DHof, - CH - = - 6.19 kJ/mol DHof, - CH2 - = - 20.7 kJ/mol CH3CH2CHCH3 CH3 DHof, - CH3= - 42.17 kJ/mol Group enthalpies provide an alternative and slightly more reliable way to estimate heats of formation and ultimately heats of reaction. Standardgroup enthalpiesof formationare defined as the contribution that a specific chemical group makes to the standard enthalpy of formation for some compound in the gas phase. For example consider 2-methylbutane in the gas phase: The standard enthalpy of formation of gaseous 2-methylbutane would then be calculated as: DHof, 2-methylbutane (g) = 3 DHof, - CH3 + 1 DHof, - CH2 + 1 DHof, - CH = (3 mols) (- 42.17 kJ / mol) + 1 (- 20.7 kJ) + 1 (- 6.19 kJ) = - 153.0 kJ Use the on-line NIST Web Book to compare this result with a literature value. 18.6
CH3CHCH2CH3 (g) CH3CHCH2Cl (g) Cl CH3 Tables of standard group enthalpies of formation for compounds in the gas phase can be found in Sydney W. Benson’s Thermochemical Kinetics, McGraw-Hill, New York (1976): DHof, 298.2 K (kJ / mol) C(H)3(C) => - CH3 - 42.17 C(H)2(C)2 - 20.7 C(H)(C)3 - 6.19 C(C)4 + 8.16 C(Cl)(H)2(C) - 65.7 C(Br)(H)2(C) - 22 C(I)(H)2(C) + 37 C(Cl)(H)(C)2 - 60.2 C(Br)(H)(C)2 - 9.7 C(Cl)(C)3 - 53.1 Use Benson’s standard group enthalpies of formation to estimate the enthalpy change for the gas phase isomerization of 1-chloro-2-methylpropane to 2-chlorobutane: What value would an estimate based on bond enthalpies have given? 18.7