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Maja Šumar - Ristović a , Vlada Blagojević b , Maja Gruden-Pavlović a , Katarina Anđelković a ,

Kinetics and mechanism of thermal degradation of Zn(II) complex with N - benzyloxycarbonyl glycinato ligand. Maja Šumar - Ristović a , Vlada Blagojević b , Maja Gruden-Pavlović a , Katarina Anđelković a , Dejan Poleti c , Dragica M. Minić b a Faculty of Chemistry,

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Maja Šumar - Ristović a , Vlada Blagojević b , Maja Gruden-Pavlović a , Katarina Anđelković a ,

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  1. Kinetics and mechanism of thermal degradation of Zn(II) complex with N-benzyloxycarbonylglycinatoligand Maja Šumar-Ristovića, Vlada Blagojević b, Maja Gruden-Pavlovića, Katarina Anđelkovića, Dejan Poletic, Dragica M. Minićb aFaculty of Chemistry, University of Belgrade, Serbia bFaculty of Physical Chemistry, University of Belgrade, Serbia cFaculty of Technology and Metallurgy, University of Belgrade, Serbia Thermal Stability Kinetics and Mechanism Changes of the activation energies with conversion degree indicate complex processes involving more than one step First Principle Calculations The most stable conformation of starting complex (Ea = 714 kJ/mol) Calculated enthalpies changes indicate one step decomposition of intermediate. Calculated Ea of intermediate [Zn(OOCCH2NHC·O)2] is 458 kJ/mol.

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