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1.7 AMINES AND AMIDES

1.7 AMINES AND AMIDES. AMINES. Amines are derivatives of ammonia molecules that contain a nitrogen atom bonded to one or more alkyl groups on each molecule. Many amines have strong, unpleasant odours. ex. putrescine cadaverine. COMMON AMINES. NAMING PRIMARY AMINES.

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1.7 AMINES AND AMIDES

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  1. 1.7 AMINES AND AMIDES

  2. AMINES Amines are derivatives of ammonia molecules that contain a nitrogen atom bonded to one or more alkyl groups on each molecule. Many amines have strong, unpleasant odours. ex. putrescine cadaverine

  3. COMMON AMINES

  4. NAMING PRIMARY AMINES Take the “e” off the end of the alkane name and add the suffix “amine.” ex. CH3NH2 is methanamine An aromatic compound with NH2 attached to a benzene ring is aniline.

  5. NAMING SECONDARY AND TERTIARY AMINES • begin with an amine name based on the longest alkyl group • use the locator, N, to indicate the attachment of additional chains to the N atom ex. N-ethyl-N-propylbutan-1-amine

  6. EXAMPLE 1: NAME EACH OF THE FOLLOWING AMINES. a) b)

  7. naming cont’d c) d)

  8. EXAMPLE 2: Draw each of the following amines with ethyl as the attached alkyl groups. Then name each structure. a) a primary amine

  9. EXAMPLE 2 cont’d b) a secondary amine c) a tertiary amine

  10. PROPERTIES OF AMINES • small amines are soluble in water • N-C and N-H bonds are polar • causes more VDW forces and more energy needed to break bonds • higher MP and BP than their corresponding hydrocarbon compounds • primary amines have higher BP’s than secondary bc they can form 2 H bonds. • secondary amines can form 1 H bond and tertiary cannot form any

  11. AMIDES Amides are structurally similar to esters except the two chains are joined by a nitrogen atom next to a carbonyl group instead of an oxygen atom.

  12. NAMING AMIDES three parts: • the first part from the amine • the second part from the acid • the ending -amide

  13. EXAMPLE 3: NAME EACH OF THE FOLLOWING AMIDES. a) b)

  14. EXAMPLE 4: Draw the structure of N-ethylpropanamide

  15. PROPERTIES OF AMIDES • small amides are soluble b/c the N-H groups form H bonds with water • the longer the carbon chain, the less soluble the amide

  16. PREPARATION OF AMINES 1. alkyl halide + ammonia ---> primary amine ex. iodoethane + ammonia ---> ethanamine

  17. PREPARATION OF AMINES 2. alkyl halide + 1 amine ---> 2 amine ex. iodoethane + ethanamine ---> N-ethylethanamine

  18. PREPARATION OF AMINES 3. alkyl halide + 2 amine ---> 3 amine ex. iodoethane + N-ethylethanamine ---> N,N-diethylethanamine

  19. SYNTHESIS OF AMIDES - involves a condensation reaction of a carboxylic acid and ammonia OR a primary or secondary amine.

  20. HOMEWORK: p. 58 #1, 2 p. 60 #1, 2 p. 62 #1 - 5

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