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Carboxylic Acids. Presented by Leticia Bonita Prince Newcastle University 4 th Year MChem Student. Aims of Today. Increase your understanding of carboxylic acids. Increase your spatial skills and awareness using software designed by the CCDC. What are Spatial Skills?.
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Carboxylic Acids Presented by Leticia Bonita Prince Newcastle University 4th Year MChem Student
Aims of Today • Increase your understanding of carboxylic acids • Increase your spatial skills and awareness using software designed by the CCDC
What are Spatial Skills? • The ability to mentally manipulate 2-dimensional and 3-dimensional figures. • Important in chemistry, biology, medicine, mathematics, physics and everyday life.
Carboxylic Acids • They have the general formula RCOOH (R= H, CH3, CH2CH3etc). • Good Hydrogen bond DONORS and ACCEPTORS.
Nomenclature • Look at the R group and add “-oic acid” to it. • If there are two carboxylic acid functional groups, you will add –dioic acid to it.
Salts • Carboxylic acids are more acid than alcohols because their conjugate base is resonance stabilised. • This anion can form a salt by bonding ionically with a metal such as sodium.
Boiling Points • Carboxylic acids have higher boiling points than alcohols. • They dimerise through hydrogen bonding creating a bigger molecule which has larger van der Waals’ – more energy to overcome.
Solubility • In water, the carboxylic acid will form hydrogen bonds with water instead of dimerisingwhich is why some are soluble. • HOWEVER, if there is a large alkyl chain (5 carbons +) the carboxylic won’t dissolve due the hydrophobic nature of the R group.
Reactions Alcohols Esters Amides Acyl Chlorides Acid Anhydrides Carboxylate Salts
The WebCSD • Type in http://webcsd.ccdc.cam.ac.uk/teaching_database_demo.php • Answer the questions by typing the refcodes into the “find entry” box
THANK YOU! ENJOY THE REST OF YOUR DAY!