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January 4, 2011 Objectives Define molecule Discuss the relationship of the physical and chemical properties of the molecules to the properties of the atoms from which they are made (They’re different!) Explain what covalent bonds are and why they are formed.
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January 4, 2011 Objectives Define molecule Discuss the relationship of the physical and chemical properties of the molecules to the properties of the atoms from which they are made (They’re different!) Explain what covalent bonds are and why they are formed. Draw a Lewis Dot diagram for any covelent molecule, indicating the number of valence electrons on each atom in the diagram.
What is a covalent bond? • What holds a molecule together? Covalent bond • Force of attraction that results from valence electrons being attracted to two nuclei. • Valence electrons being shared between two nuclei • Core electrons are not involved in bonding • Valence electrons are shared between the two nuclei
Ways to represent shared electrons H:H H..H H-H
The Octet Rule • Remember for the representative elements the Roman Numeral group number tells you the number of valence electrons. • He is the only exception. Why? • Formula for Water and Methane.
Practice • What is the formula for ammonia? • What is the formula for carbon and chlorine?
Lewis Dot diagrams • Show an atom’s valence electrons • The number of dots is equal to the group number • Pairs of dots(electrons) are electron pairs • Single electrons are unpaired electrons
I II III IV V VI VII VIII Transition metals Metalloids Nonmetals Metal
Steps to drawing dot diagrams • Count up how many valence electrons will be in the final diagram (PCl3) (CO) • Connect the atoms with single bonds. Assume first non hydrogen atom is the central atom (PCl3) • Put the remaining dots in as lone pairs. First on the terminal atoms then on the central atom. Don’t use more electrons then you have.
Steps to drawing dot diagrams • (CO ) Remember every atom needs an octet. Lone pairs to the rescue. Only from adjacent atoms.
Multiple Covalent Bonds O2 N2
Multiple Covalent Bonds CO2 C2H2