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Kinetic Overpotential Hydrogen. Revisi. Rommy Iman Sulaiman 071430 9 April 20 10. Outline. Kinetic Overpotential Hydrogen Kinetic Overpotential Hydrogen Referen ce. Kinetic. Kinetic (Kinetika) membahas tentang laju reaksi dan mekanisme terjadinya reaksi. Overpotential Hydrogen.
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Kinetic Overpotential Hydrogen Revisi Rommy Iman Sulaiman 071430 9April 2010
Outline • Kinetic • Overpotential Hydrogen • Kinetic Overpotential Hydrogen • Reference
Kinetic Kinetic (Kinetika) membahas tentang laju reaksi dan mekanisme terjadinya reaksi
Overpotential Hydrogen Adanya gerakan ion (kinetik) yang lambat menyebabkan potensial yang menyimpang dari nilai Nernst Pada Hydrogen : 2H+ + 2e- = H2
Kinetic Overpotential Hydrogen • Mass Transfer-Controlled Reaction-Concentration Overpotential
Kinetic Overpotential Hydrogen • Interfacial Reaction Rate Control-Activation Overpotential
Kinetic Overpotential Hydrogen • Difusi H3O+dariBulk Solution menujudouble layer • H3O+melewatiDouble Layer • Dehidrasi ion H3O+ H2O + e • a) Electrochemical H3O+ + M + e- M-H + H2O (pelepasan ion) b) Pembentukanmolekul-molekulHydrogen 2 M-H 2M + H2
Kinetic Overpotential Hydrogen • Desorpsi gas H2 darielektroda • Difusi gas H2keluar/menjauhielektroda
Reference • Habashi, Fathi. Principles of Extractive Metallurgy. New York : Gordon and Breach, Science Publishers, Ltd • H. S. Ray A. Ghosh. 1991. Principles of Extractive Metallurgy : New Age International • Rosenqvist, Terkel. 1983. Principles of Extractive Metallurgy . Tokyo : McGraw Hill Kogakusha Ltd.