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Announcements Tuesday, May 3. FINAL When: Tuesday, May 10, 7:30 – 9:30 Where: in our usual room. BRING YOUR 5” x 7” card with notes. BRING “problem” exams (misgraded, etc.) HELP SESSIONS: JUST DROP IN FOR HELP!!!! Wednesday at 5 pm, here Next Monday at 7 pm, TBA
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AnnouncementsTuesday, May 3 FINAL When: Tuesday, May 10, 7:30 – 9:30 Where: in our usual room. BRING YOUR 5” x 7” card with notes. BRING “problem” exams (misgraded, etc.) HELP SESSIONS: JUST DROP IN FOR HELP!!!! Wednesday at 5 pm, here Next Monday at 7 pm, TBA EXTRA CREDIT (10 PTS) Find the error in the hydrogen car article.
Today’s Factoids Population of China: 1,300,000,000 (20% of global population) Population of USA: 300,000,000 Log10(China) = 9.1 Log10(USA) = 8.5 U.S. –awarded Ph.D.’s in science & engineering: ~25,000/year
A sample case 2Na + 2H2O 2Na+ + H2 + 2OH- Na was oxidized: Na Na+ + e- (electron lost) H was reduced: lost oxygen O no change: lost H but gained e- Remember…we actually ran this reaction by dumping some sodium into water.
Another one 2 CH3OH 2 CH2O + H2 C: ??? H: ??? H: ??? O: ???
CH3CH2CH2CH=CHCH2CH3 + H2 CH3CH2CH2CH-CHCH2CH3 H H Still another one (related to “butter vs. margarine”) C ????? H ?????
Secret Agents: all part of the semantics nightmare that is RedOx • Something that promotes reduction: reducing agent • Example: K, Na, H, LiAlH4 • Something that promotes oxidation: oxidizing agent • Example, O, F, Br, K2Cr2O7
Main Applications of RedOx Recovery of metals from ores Corrosion Prevention of corrosion Batteries
Steel! And the sons ofPullman porters & the sons of engineersRide their fathers' magic carpet made of steel Mothers with their babes asleep, rockin' to the gentle beatAnd the rhythm of the rails is all they feel City of New Orleans—Steve Goodman
Reducing Iron Ore to Make Steel:from rust to riches 2 Fe2O3 + 3C 4 Fe + 3CO2 From Coal Rust i.e., ore How steel is really made: http://www.sidmar.be/CONTENT/2c.htm
RedOx & Geography IRON ORE CARS COAL
Electro-reduction for Aluminum 2Al2O3 4Al + 3O2 Electrons out Power Plant Electrons in
Hydroelectric Power Aircraft Industry Hydroelectric Power
Corrosion 2 Fe 2 Fe+2 + 4 e- 4e- + 2H2O + O2 4OH- Electrons travel down nail
Batteries! What if we could trap those electrons, make ‘em do some work before the reduction step?
We are reliant on foreign oil. http://www.worldfuturefund.org/wffmaster/Charts-HTML/Energy/us-oil.htm U.S. oil imports as a percentage of consumption
http://www.saudi-us-relations.org/newsletter/saudi-relations-12.htmlhttp://www.saudi-us-relations.org/newsletter/saudi-relations-12.html
Hybrid VehiclesRedOx Chemistry Galore “The car Detroit wants you to believe cannot be built.” But is that fair???
Cool Fuel Cell Links How Stuff Works Link: http://science.howstuffworks.com/fuel-cell1.htm http://science.howstuffworks.com/framed.htm?parent=fuel-cell.htm&url=http://education.lanl.gov/resources/h2/gottesfeld/education.html
More Announcements Pick up your HW4 papers!! HW5 due 5 pm—no exceptions. HW5 answers by e-mail Monday evening help session, 5 pm Tuesday 7:30 am Final Exam (300 pts) Remember, only 5” x 7” cheat sheet No-calculator bribe raised to 17% for final.