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AUT 236 – Automotive HVAC. Cpt 4 – Heat Movement Theory. OBJECTIVES. After studying Chapter 4, the reader should be able to: Discuss how heat can be transferred from one location to another. Describe the three states of matter and the effect that heat has on them.
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AUT 236 – Automotive HVAC Cpt 4 – Heat Movement Theory
OBJECTIVES After studying Chapter 4, the reader should be able to: • Discuss how heat can be transferred from one location to another. • Describe the three states of matter and the effect that heat has on them. • Discuss what latent heat is and why it is important to A/C. • Discuss how pressure is measured. • Discuss the effect that pressure has on boiling points.
INTRODUCTION • In practical terms, an HVAC system moves heat. • The A/C system simply transfers the heat out of a place where it is not wanted, and the heating system moves the heat into a place where it is wanted. • Heat always moves from hot to cold. • Remember that heat is energy, and cold is lack of energy. • The rate or speed that heat moves, then, is simply a factor of the difference in the temperature between the hot and cold areas.
FIGURE 4-1 Heat always moves from hot to cold. In this example, it will travel from the fire to the cooler water and from the hand to the cooler ice. INTRODUCTION
FIGURE 4-2 Heat can enter a vehicle’s passenger compartment from several sources. The A/C system allows us to move excess heat out of the vehicle. (Courtesy of Toyota Motor Sales USA, Inc.) INTRODUCTION
HEAT MOVEMENT • Heat can travel on one or more of three paths as it moves from hot to cold: conduction, convection, or radiation. • Heat travel can be beneficial and intentional, or it can be detrimental. • Conduction • Convection • Radiation
HEAT MOVEMENT • The transfer of heat directly through a material is called conduction.
HEAT MOVEMENT • We move heat from the heater to the passengers or from the passengers to the A/C system by convection. Heat movement from the engine to the radiator using circulating coolant is also an example of convection.
HEAT MOVEMENT • Heated air next to the stove will rise and cooler air will move in to replace it. This creates a convection current to move the air and heat.
HEAT MOVEMENT • Heat is transferred from the sun to things on Earth through radiation.
HEAT MOVEMENT • Radiant heat entering a vehicle through the windows can add a lot of heat to a car’s interior
STATES OF MATTER • The air-conditioning process works through a fluid, called a refrigerant, that continuously changes state from liquid to gas and back to liquid. • These changes of state are where the movement of heat needed for cooling occurs. • All basic materials exist in one of the states of matter—solid, liquid, or gas—and most of them can be changed from one state to another by adding or removing heat. • Solid • Liquid • Gas
STATES OF MATTER • We can cause matter to change state by adding or removing heat.
STATES OF MATTER • A water molecule contains two oxygen atoms and one hydrogen atom; • R-12 is a combination of one carbon, two chlorine, and two fluorine atoms; • R-134a is a combination of two carbon, four fluorine, and two hydrogen atoms; and • R-152a has two more hydrogen and two less fluorine atoms than R-134a.
STATES OF MATTER • Ice is a solid form of water with a low temperature and slow molecular action.
STATES OF MATTER • Water is warmer than ice and has a much freer molecular action. • Liquid: H2O at temperatures between 32deg and 212deg F (0 and 100 dec C ) • Liquid/Fluid takes the shape of the container • Exerts pressure downward and to the sides
STATES OF MATTER • Adding heat to water produces steam, the gas state, with a much freer molecular action. • GAS • H20 at temperatures above 212 deg F, 100 deg C • Gas has no shape • Can exert pressure in all directions.
LATENT AND SENSIBLE HEAT • Sensible heat makes sense; it can be felt and measured on a thermometer. • If we have 1 lb of water at 40°F and add 1 Btu of heat to it, the temperature will increase to 41°F; adding another Btu of heat will increase the temperature to 42°F; and adding another 170 Btu (212 – 42) will increase the temperature to 212°F, the boiling point.
LATENT AND SENSIBLE HEAT • Heat that causes a temperature increase is called sensible heat.
LATENT AND SENSIBLE HEAT • If we add 970 Btu of heat to 1 lb of water at 212°F, we will have 1 lb of steam at the same temperature.
LATENT AND SENSIBLE HEAT • To change 1 lb of water at 212°F into 1 lb of steam at 212°F, we must add 970 Btu’s of heat. Using metric terms, to change 1 g of water at 100°C into 1 g of steam at 100°C, we must add 540 calories of heat. This is called the latent heat of evaporation. • To reverse this and change 1 lb of steam back into 1 lb of water, we have to remove this same 970 Btu of heat; this is called the latent heat of condensation.
LATENT AND SENSIBLE HEAT • If we start with 1 lb of water at 32°F, adding 180 Btu will increase the temperature to 212°F. It will take another 970 Btu (the latent heat of evaporation) to boil that pound of water.
LATENT AND SENSIBLE HEAT • In an A/C system, the refrigerant changes state and absorbs heat in the evaporator and releases heat as it changes state again in the condenser.
LATENT AND SENSIBLE HEAT • If we start with a 1-lb block of ice at 32°F, it will take 144 Btu (the latent heat of fusion) to melt all of the ice.
LATENT AND SENSIBLE HEAT • The amount of heat movement required to change 0°F ice to steam, or vice versa. • Adding 16 BTU will warm ice from 0 deg F to 32 deg F. • Adding 144 BTU more will change the ice to water with no temp change • Adding 180 BTU will raise the water from 32 deg F to 212 deg F. • Adding 970 BTU will change the water to steam with no temperature change.
LATENT AND SENSIBLE HEAT • A refrigeration cycle absorbs heat as the refrigerant boils in the evaporator and removes heat as it changes state back to a liquid in the condenser.
BOILING POINTS • Boiling points can be increased or decreased by raising or lowering the pressure on the liquid. • With water, the boiling point will rise about 2 1/2°F for each pound per square inch (psi) of pressure, or about 1°C for each 5 kPa. • Critical Temperature • The critical temperature is the maximum point at which a gas can be liquefied or condensed by raising the pressure. • The critical pressure is the pressure that is necessary to liquefy a gas at that temperature.
BOILING POINTS • The boiling point of a liquid changes as the pressure changes. • Water will boil at 183°F with a pressure of 13 psi on a mountain. • It will boil at 212°F at an atmospheric pressure of 14.7 psi. • In a radiator at a pressure of 30 psi (absolute), it will boil at 250°F.
SATURATED VAPORS AND THE PRESSURE–TEMPERATURE RELATIONSHIP • Saturated vapor, also called a saturated liquid, is the term used to describe a liquid and gas inside a closed chamber, which is the condition in an A/C system. • When discussing saturated vapors, we need to learn two additional terms: subcool and superheat. • Subcool refers to a liquid whose temperature is well below its boiling point. • Superheat refers to the temperature increases of a vapor above its boiling point.
SATURATED VAPORS AND THE PRESSURE–TEMPERATURE RELATIONSHIP • R-12 in a container is a saturated vapor with gas in contact with a liquid. The pressure in the container is in direct relation to the temperature (a); • a chart can be used to determine the temperature if we know the pressure, or vice versa (b).
PRESSURE: GAUGE AND ABSOLUTE • Pressure is defined as a certain amount of force exerted on a unit area. • Traditionally in the United States, pressure is given in pounds and the unit area in square inches, so pressure has been given in pounds per square inch (psi). • Most pressure gauges disregard atmospheric pressure and are calibrated to read 0 at their starting point, which is the normal atmospheric pressure surrounding us. • The pressure created by the weight of the air in our atmosphere generates a pressure of 14.7 psi at sea level, which is often rounded off to 15 psi
PRESSURE: GAUGE AND ABSOLUTE • The weight of the air in our atmosphere generates a pressure of about 15 psi at sea level. • Atmospheric pressure and the boiling point of water are lower at higher altitudes .
PRESSURE: GAUGE AND ABSOLUTE • As shown on this compound gauge, pressures below atmospheric are commonly called a vacuum (a). • A perfect vacuum is 29.92 inches of mercury (b)
PRESSURE: GAUGE AND ABSOLUTE • The boiling point of water drops as pressure is reduced. At a near-perfect vacuum of 29.9199 δHg or 2.54 microns, the boiling point is -90°F
PRESSURE: GAUGE AND ABSOLUTE • The relative pressures between seven different measuring systems.
REFRIGERANTS • The working fluid of an A/C system is refrigerant. Refrigerants were first developed by the Du Pont Corporation using the name Freon. • Depending on the combination of carbon, chlorine, fluorine, or hydrogen, a refrigerant is classed as an HFC, CFC, or HCFC
REFRIGERANTS • Comparison of the physical characteristics of R-12 and R-134a.
REFRIGERANTS • R-12 • R-22 • R-134a • R-152a • HFO-1234yf • R-290,Propane, and R-600 Butane • R-744,CO2 • Blends • Refrigerant Oils
REFRIGERANTS • Refrigerant is commonly available in small or large (30- or 50-lb) containers. A 30-pound, disposable container of R-12 and small, 12-ounce can of R-134a is shown.
REFRIGERANTS • A refrigerant and its oil must be completely compatible with all of the materials and chemicals in the system.
REFRIGERANTS • The boiling points for R-12, R-22, and R-134a vary depending on the pressure.
SUMMARY • Heat travels by either conduction, convection, or radiation. • Many compounds can be found as a solid, liquid, or vapor. • Adding heat will cause water to change from a solid to a liquid or from a liquid to a vapor. • Removing heat will cause water to change from a liquid to a solid or from a vapor to a liquid. • Sensible heat changes the temperature, and latent heat causes a change of state.
SUMMARY • The boiling points of liquids can be changed by changing pressure. • Changing the temperature of a saturated vapor will change the pressure. • Pressure is measured in psi, bar, or kPa. • Refrigerants have very low boiling points and are either a CFC, HFC, HCFC, or HFO.
REVIEW QUESTIONS Heat • We must move _________ to the outside of the vehicle in order to cool it. • Heat transfer from one molecule to the one next to it is called _________, and moving heat by circulating hot air or water is called _________. • The three states of matter are _________, _________, and _________. • If we add enough heat to solid matter, it will change to a(n) _________. • Heat that is added to change water to gas is called _________, _________ of _________. Conduction Convection Liquid Solid Gas Liquid Latent Heat Evaporation
REVIEW QUESTIONS Boiling • Adding pressure to a hot liquid will increase the _________ _________. • A liquid gas mixture in a closed container is called a(n) _________ _________, and heating this container will _________ the internal pressure. • Ten psi is equal to _________ kPa. • A pressure lower than atmospheric is called a(n) _________, and this pressure is measured in _________ or _________. • Most vehicle and compressor manufacturers recommend using _________ oil in R-134a systems. Point Saturated Vapor Raise 69.85 Vacuum HG, microns Mm, Hg PAG
CHAPTER QUIZ • Which of the following is true about heat? • Heat always travels from something warm to something cold. • Heat is a form of energy. • Cold is the lack of heat. • All of these are true.
CHAPTER QUIZ 2. _________ occurs when heat travels through a material, from one molecule to the one next to it. • Radiation • Convection • Conduction • None of these
CHAPTER QUIZ 3. The process of transferring heat by circulating the heated media is called _________. • Radiation • Convection • Conduction • None of these
CHAPTER QUIZ 4. The movement of heat through heat rays is called _________. • Radiation • Convection • Conduction • None of these
CHAPTER QUIZ 5. Molecules are composed of_________. • Atoms • Protons • Electrons • compounds