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ENGINEERING ORGANIC SOLAR CELLS USING A NOVEL TRI-LAYER ARCHITECTURE. Michael Crump 2008–2009. ORGANIC SOLAR CELLS. http://www.inhabitat.com/wp-content/uploads/solarprint2.jpg. SOLAR CELL STRUCTURE STUDIED BY PEUMANS et al. (2003). [500 Å]. [100 Å]. [400 Å]. [200 Å]. [1500 Å].
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ENGINEERING ORGANIC SOLAR CELLS USING A NOVEL TRI-LAYER ARCHITECTURE Michael Crump 2008–2009
ORGANIC SOLAR CELLS http://www.inhabitat.com/wp-content/uploads/solarprint2.jpg
SOLAR CELL STRUCTURE STUDIED BY PEUMANS et al. (2003) [500 Å] [100 Å] [400 Å] [200 Å] [1500 Å]
OSC EXPERIMENTAL ARCHITECTURE 1 [500 Å] [100 Å] [400 Å] [200 Å] [10–100 Å] [1500 Å]
KUSHTO et al. (2005) ARCHITECTURE [500 Å] [100 Å] [400 Å] [200 Å] [1500 Å] NPD
OSC EXPERIMENTAL ARCHITECTURE 1 [500 Å] [100 Å] [400 Å] [200 Å] [10–100 Å] [1500 Å] NPD (donor)
ENERGY GRAPH CuPc (Donor) C60 (Acceptor) donor donor
RATIONALE FOR USING NPD(RAND et al. 2005) NPD (Donor) donor CuPc (Donor) C60 (Acceptor) donor donor
FABRICATING BILAYERORGANIC SOLAR CELLS Pressure Gauge 0 atm 1 atm
TESTING ORGANIC SOLAR CELLS Computer Solar Cell Current Diode Current JMAX x VMAX JSC x VOC Photocurrent Light
DETERMINING EFFICIENCY Efficiency = Voltage x Current x Fill Factor
NPD RESULTS Efficiency vs. NPD thickness control
NPD RESULTS Fill Factor vs. NPD Thickness control control Current vs. NPD thickness
NPD RESULTS Voltage vs. NPD thickness control
NPD ENERGY GRAPH CuPc (Donor) C60 (Acceptor) donor donor NPD (Donor) donor
OSC EXPERIMENTAL ARCHITECTURE 2 [500 Å] [100 Å] [400 Å] [200 Å] [10–100 Å] [1500 Å]
HOLMES et al. (2008) ARCHITECTURE [500 Å] [100 Å] [400 Å] [200 Å] [1500 Å] PtOEP
RATIONALE FOR USING PTOEP PtOEP (Donor) CuPc (Donor) C60 (Acceptor) donor donor donor
PTOEP RESULTS Efficiency vs. PtOEP Thickness control
Fill Factor vs. PtOEP Thickness PTOEP RESULTS control control Current vs. PtOEP Thickness
PTOEP RESULTS Voltage vs. PtOEP Thickness control
YANG et al. (2008) CuPc (Donor) Donor C60 (Acceptor) Acceptor donor donor donor donor PtOEP (Donor) donor
CONCLUSIONS • Voltage depends only on energy gap between electron donor and electron acceptor (Yang) • Low current
FUTURE WORK • Dope NPD or PtOEP(Maenniget al. (2004)) • Find optimal balance between electron donor and NPD
FUTURE WORK Pressure Gauge 0 atm 1 atm
ACKNOWLEDGMENTS • Dr. Russell Holmes • University of Minnesota • Kai-Yuan Cheng, Grant Lodden, Wade Luhman, and Richa Pandey • Dr. Marla Feller andMs. Lois Fruen • The Breck Research Team http://www.cems.umn.edu/about/people/facdetail.php?cemsid=20785
ENGINEERING ORGANIC SOLAR CELLS USING A NOVEL TRI-LAYER ARCHITECTURE Michael Crump 2008–2009
RATIONALE FOR USING NPD(RAND et al. 2005) NPD (Donor) donor CuPc (Donor) C60 (Acceptor) donor donor
DETERMINING EFFICIENCY Efficiency = Voltage x Current x Fill Factor