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Drill: Draw, Predict, & Name R & P

Drill: Draw, Predict, & Name R & P. Phenylbromide + Methylamine + KOH. Br +. + KOH. H 3 C-N-H. H. Br +. + KOH. H 3 C-N-H. H. H. N-CH 3. N-methylanaline. + KBr + HOH. Potassium bromide + water. Amides. Amides. O R-C NH 2 Alkanoamide.

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Drill: Draw, Predict, & Name R & P

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  1. Drill: Draw, Predict, & Name R & P Phenylbromide + Methylamine + KOH

  2. Br + + KOH H3C-N-H H

  3. Br + + KOH H3C-N-H H

  4. H N-CH3 N-methylanaline + KBr + HOH Potassium bromide + water

  5. Amides

  6. Amides • O • R-C • NH2 • Alkanoamide

  7. Common Amides

  8. Formamide • O • H-C • NH2 • Methanoamide

  9. Acetamide • O • CH3-C • NH2 • Ethanoamide

  10. Amides • O • CH3-CH2-C • NH2 • Propanoamide

  11. Amides • O • -C • NH2 • Benzoamide

  12. N-methylbenzoamide • O • -C • NH • CH3

  13. Making Amides

  14. Add Acids & Amines • O • R-C-OH + :NH3 • O • R-C-O- + NH4+

  15. Dehydration Syn • O • R-C-O- + NH4+ • O • R-C-NH2 + H2O Heat

  16. Net Reaction for Amide ProductionDehydration Syn • O R-C-OH + H-NH2 DHA

  17. Dehydration Syn • O • R-C-OH + H-NH2 • O • R-C-NH2 + H2O Heat

  18. Add Acids & Amines • O • H-C-OH + H-NH2 Formic Acid + Ammonia

  19. Add Acids & Amines • O • H-C-OH + H-NH2 • O • H-C-NH2+ H2O DHA

  20. Dehydrating Agents • H2SO4 • P2O5

  21. Drill: • Draw the organic reactant; then, draw & name the organic product of the dehydration synthesis of propanoic acid + ammonia.

  22. Acetic acid + Met amine • O • H3C C OH • + N-CH3 H H

  23. Acetic acid + Met amine • O • H3C C OH • + NCH3 H H

  24. N-methylacetamide • O CH3 • H3C-C-NH+ H2O

  25. Predict Products • Dehydration synthesis of benzoic acid + cyclopropylamine

  26. O C OH H N H

  27. O C OH H N H

  28. O C H N N-cyclopropyl benzoamide

  29. Esters + Amines • O • R1-C-O-R2 • + • :NH3

  30. Amides + Alcohols O • R1-C-N + • HO-R2 H H

  31. Methyl benzoate + A • O • -C-O-CH3 • + • :NH3

  32. Benzoamide & MeOH • O • -C-NH2 • + • HO-CH3

  33. Anhydrides + Amines • O O • R1-C-O-C-R2 • + • :NH3

  34. Amides + Acids • O • R1-C-NH2 • O + • R2-C-OH

  35. Organic HW; Draw reactants, then draw & name products of: • DHS of acetic acid & NH3 • DHS of benzoic acid & NH3 • AM of methylbenzoate & NH3

  36. Polyamides

  37. AA + HDA • O O • n HO-C-(CH2)4-C-OH • + • n H2N-(CH2)6-NH2 -water

  38. Nylon 66 • O O • -(-C-(CH2)4-C • NH • -(HN-(CH2)6 n

  39. 6-aminohexanoic acid • O • x HO-C-(CH2)5-NH2 -water

  40. Nylon 6 • O • x -(-(CH2)5-C-NH-)-

  41. COOH + COOH H2N H2N

  42. C=O + H2O C O HN HN

  43. Nitriles

  44. Making Nitriles • O • R-C-NH2 Heat Dehydration Dehydrate amides

  45. Nitrile + Water • R-C-N: + H2O

  46. CommonNitriles • R-C=N

  47. Acetonitrile • CH3-C=N

  48. Hydrogen Cyanide • H-C=N

  49. Benzonitrile • -C=N

  50. Draw & name 10 Isomers ofC4H7NO2

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