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Drill: Draw & Name Reactants & Products of:

Drill: Draw & Name Reactants & Products of:. Oxidations of 1-butanol in 2 steps:. Drill: Draw & Name Reactants & Products of:. Oxidation of 2-butanol:. Drill: Draw & Name 3 isomers containing carboxyl groups of:. C 5 H 10 O 2. Drill: Draw & Name 4 isomers containing carboxyl groups of:.

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Drill: Draw & Name Reactants & Products of:

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  1. Drill: Draw & Name Reactants & Products of: • Oxidations of 1-butanol in 2 steps:

  2. Drill: Draw & Name Reactants & Products of: Oxidation of 2-butanol:

  3. Drill: Draw & Name 3 isomers containing carboxyl groups of: C5H10O2

  4. Drill: Draw & Name 4 isomers containing carboxyl groups of: C6H12O2

  5. Acid Derivatives

  6. Acid Anhydrides

  7. Acid Anhydrides • O O • R1-C-O-C-R2

  8. Acid Anhydrides • Formed through the dehydration synthesis of two carboxylic acids

  9. Making Anhydrides • O O • R1-C-OH + HO-C-R2

  10. General Anhydride • O O • R1-C-O-C-R2 • + H2O

  11. Determine All • O • CH3-C-OH + • O • HO-C-CH3

  12. O CH3-C-OH + HO-C-CH3 O

  13. Diacetic Anhydride • O O • CH3-C-O-C-CH3 • + H2O

  14. Succinic Acid O C C O H2C OH H2C OH Heat

  15. Succinic Acid O C C O H2C O H H H2C O Heat

  16. Succinic Anhydride O C C O H2C O + H2O H2C

  17. Phthalic Acid O C C O OH OH Heat

  18. Phthalic Anhydride O C C + H2O O O

  19. Drill: Draw the reactants, then predict, draw, & name the organic product in the dehydration of propanoic acid & butanoic acids.

  20. Anhydride Hydrolysis • The reverse of the anhydride formation reaction

  21. Anhydride Hydrolysis • The hydrolysis of an anhydride forms 2 acids

  22. Anhydride Hydrolysis • O O • R1-C-O-C-R2 • + H2O

  23. Anhydride Hydrolysis • O O • R1-C-O-C-R2 • + H-O H

  24. Two Acids • O O • R1-C-OH + HO-C-R2

  25. Drill: • Draw the reactants, then draw, & name the product of the dehydration synthesis of butanoic acid & propanoic acid.

  26. Esters

  27. Esters • O • R1-C-O-R2

  28. Esterification • The formation of esters

  29. Ester Formation • Dehydration synthesis of alcohols & acids

  30. Esterification • O • R1-C-OH + HO-R2 Acid

  31. Ester • O • R1-C-O-R2 • + H2O

  32. Name R & P O CH3-C-OH + • HO-CH3 Acid

  33. Name R & P O CH3-C-OH + • HO-CH3 Acid

  34. O CH3-C + H2O • O-CH3

  35. Blah Blah Blah 15.5 days left O Methanol OH + HO-CH3 OH DHA Salicylic Acid

  36. O Methanol OH + HO-CH3 OH DHA Salicylic Acid

  37. Methyl Salicate O O-CH3 OH + H2O Oil of Wintergreen

  38. Esterification Acetic Anhydride O OH O C-CH3 C-CH3 OH + O O Salicylic Acid

  39. Acetyl salicylic A O Acetic acid OH O + C-CH3 HO O C-CH3 O Aspirin

  40. Drill: Draw & name 5 esters that are isomers of C6H12O2

  41. Organic HW • Draw & Name reactants & products in the dehydration synthesis between the following: • Phenol & acetic acid • Cyclohexanol & formic acid

  42. Common Esters

  43. Ethyl Formate • O • H-C-O-CH2-CH3 • Rum

  44. Octyl acetate • O • H3C-C-O-(CH2)7-CH3 • Oranges

  45. Pentyl acetate • O • H3C-C-O-(CH2)4-CH3 • Bananas

  46. Ethyl butyrate • O • H2C-C-O-CH2-CH3 • CH2-CH3 • Pineapples

  47. Pentyl butyrate • O • H2C-C-O-(CH2)4-CH3 • CH2-CH3 • Apricots

  48. Methyl butyrate • O • H2C-C-O-CH3 • CH2-CH3 • Apples

  49. Predict Product • O CH3-CH2-CH2-C-OH O + HO-C-CH3 + Heat

  50. Drill: • Draw the reactants, then predict & draw the products of dehydration synthesis when phenol is added to formic acid.

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