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Sussex NNC. Ferrocene/C 60 complex. Sussex NNC. Jon Crane, Roger Taylor, David Walton. C 60 -Ferrocene complex Jon Crane Roger Taylor David Walton. Sussex NNC. C 60 Cl 6 Paul Birkett Roger Taylor David Walton. Sussex NNC.
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Ferrocene/C60 complex Sussex NNC Jon Crane, Roger Taylor, David Walton
C60 -Ferrocene complex Jon Crane Roger Taylor David Walton Sussex NNC
C60Cl6 Paul Birkett Roger Taylor David Walton Sussex NNC
C60Ph5H Paul Birkett, Roger Taylor, David Walton(Sussex) Sussex NNC
Mass spectrum of carbon in which C60 and C70 were first recognised as special Rice Sussex NNC
C60 C70 C50 C40 What are the other clusters? Rice Sussex NNC
C28 Sussex NNC
Exxon Data Cox et al JACS 110 1588 (1988) C20 ? Assignment Sussex NNC
C20 Dodecahedrane C20H20, synthesised by Paquette’s group in 1983 (2 years before C60 was discovered) can now be recognised as the fully hydrogenated derivative of the lest stable fullerene C20 Sussex NNC
Note that C20H20 dodecahedrane is the fully hydrogenated derivative of the smallest fullerene C20
C28 ”superatom” analogue of sp3 carbon atom Suggests Td C28H4 Nature 329 529 (1987) Support U @ C28 U tetravalent (Smalley and coworkers) C28H4 Sussex NNC
C50H10 Sussex NNC
C50H10 Sussex NNC
C50Cl10 Sussex NNC
Oxides of Carbon CO :C=O CO2 O=C=O C2O :C=C=O C3O :C=C=C=O C3O2 O=C=C=C=O C60O
Simulation of a collision of C60 with a crystal surface • C60 is very strong • Stresses are distributed geodesically throughout the framework • It bounces when other molecule break • ucla
Simulation of a collision of C60 with a crystal surface • C60 is very strong • Stresses are distributed geodesically throughout the framework • It bounces when other molecule break • ucla