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Chapter 2. Atoms, Molecules and Properties of Water. Matter Element 25 of the 92 elements are essential to life. Atoms. Atoms are electrically neutral An element’s properties depends on structure of its atoms Atomic number Mass number (Atomic mass).
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Chapter2 Atoms, Molecules and Properties of Water
Matter • Element • 25 of the 92 elements are essential to life
Atoms are electrically neutral • An element’s properties depends on structure of its atoms • Atomic number • Mass number (Atomic mass)
Atoms of an element have same number of protons • Isotopes • Radioactive isotopes
Energy • Potential energy • Electron shells
Valence electrons • Determines chemical behavior Bohr models of atoms
Most elements need 8 electrons to fill valence shell • Rule of octet • Full valence shell - inert or stable • Vacancies – reactive
chemical bonds • Atoms share or transfer valence electrons • Molecules and Compounds • emergent properties
Ionic Bonds • transfer of electrons • Ions • cation • anion • Salts
Covalent bond • shared electrons • Single, double, triple
Electronegativity • Polar vs non-polar bonds Unequal sharing of electrons causes partial charges
Hydrogen Bonds • Polar covalent molecules • Positive hydrogen attracted to a negative oxygen or nitrogen • Weak and temporary
Why is Water important to Life? • Life on earth probably originated in water • Water covers 75% of the earth • Living organisms are 60 - 90% water • Hydrogen bonds give water several unique properties that support life
The polarity of water results in hydrogen bonds • polar molecule • Oxygen very electronegative • Attractions exist between partially charged poles Polar covalent bonds Hydrogen bonds
Emergent properties of water contribute to life • Cohesive and Adhesive nature • Ability to moderate temperature • Solid form lighter than liquid form • Versatility as a solvent • Influence on pH
Cohesion • Water molecules tend to stick to each other • Surface tension
Adhesion • Water molecules stick to other polar molecules
Moderation of Temperature • Heat is transferable energy • Objects exchange heat until they are achieve an equal temperature • Water has a high specific heat • Absorbs/releases great amounts of heat
Water has a high heat of vaporization • Evaporative cooling
Water Expands when it freezes • Ice floats in liquid water • Hydrogen bonds are more “ordered,” making ice less dense • Floating ice insulates bodies of water
Water interacts with many other molecules • Many molecules dissolve easily in water • Solvent vs. Solute • Hydrophillic vs. Hydrophobic
Water molecules can dissociate • Hydrogen ion (H+) and Hydroxide ion (OH-) • H2O H+ + OH- • The resulting ions are highly reactive! • Results in acidic and basic solutions • Measured as pH
Acid • increases [H+]of a solution • Base • decreases[H+]or increases [OH-]of a solution • Salt • has no impact on [H+]of a solution
[H+] is measured using a pH scale (0-14) • pH calculated by: • pH = -log [H+] • Each number represents a tenfold difference in [H+]
Buffers • minimize changes in [H+] and [OH-] • Prevent large shifts in pH • pH of living cells maintained close to 7 (neutral)
Blood always contains a combination of some carbonic acid and some bicarbonate ions. When [H+] in blood is too high: When [OH−] in blood is too high: