Office Hour tomorrow…

1. Office Hour tomorrow… • 1~3pm

2. ME 350 – Lecture 10 – Chapter 13 SHAPING PROCESSES FOR PLASTICS • Properties of Polymer Melts • Injection Molding • Extrusion • Extrudate Production • Other Molding Processes • Thermoforming • Casting • Polymer Foam Processing • Product Design Considerations

3. Polymer Melt - Viscosity Shear rate and viscosity: thinner at higher shear rates Temperature & viscosity: thinner at higher temperature

4. Die Swell, aka: Viscoelasticity Extruded polymer "remembers" its previous shape when in the larger cross section of the extruder, tries to return to it after leaving the die orifice Swell ratio: rs = Dx / Dd Die swell, a manifestation of viscoelasticity in polymer melts.

5. Extrusion Heated plastic is forced to flow through a die orifice to provide a long continuous product (tube, sheet, etc.) whose cross‑sectional shape is determined by the die orifice. The extrudate is then cut into desired lengths. Three zones in an extruder: feed, compression, & metering.

6. Die End of Extruder • Progress of polymer melt through barrel leads ultimately to the die zone • Before the die, the melt passes through a series of wire meshes supported by a stiff plate containing small axial holes called a: screen pack • Functions: • Filter(remove contaminants and any hard lumps) • Build pressurein the metering section • Straighten flow- remove "memory" of circular motion from screw

7. Melt Flow in Extruder • Archimedian screw forces polymer melt toward die • Principal transport mechanism is Qd, resulting from friction between the viscous liquid and the rotating screw: drag flow • Compressing the polymer melt through the die creates a back pressure that reduces drag flow transport, Qb called: back pressure flow • Resulting flow in extruder is: Qx = Qd – Qb

8. Extruder Screw Melt Flow Qd = 0.5 π2 D2 N dc sinA cosA Where, D – flight screw diameter N – screw rotational speed dc – screw channel depth A – flight angle Qb ≈ Where, p – head pressure (die) η – melt viscosity L – length of the barrel Assumes leakage flow is negligible Qx = Qd - Qb Drag Flow Qd→ Back Pressure Flow Qb ← Flight angle ‘A’? tan A = p / πD

9. Extruder Screw Melt Flow • Boundary Conditions: • With no back pressure • Qx = Qmax = Qd • 2) With no flow • Qx = 0 = Qd – Qb, • pmax = Extruder characteristic Qx = Qmax – (Qmax/pmax)p Qmax Die characteristic Qx = Ksp Melt flow Ks = (for round opening) Dd – effective die opening Ld – effective die opening length Head pressure pmax Intersection (Qx,p) known as the operating point

10. Extrusion Die for Solid Cross Sections • The shape of the die orifice determines the cross sectional shape of the extrudate. • Solid shapes: rods, beams, bars, plates, sheets, etc.

11. Extrusion Die for Hollow Shapes • Hollow profiles require a “spider” mandrel: • Polymer melt flows around legs supporting the mandrel to reunite into a monolithic tube wall due to: die swell • Mandrel includes an air channel through which air is blown to maintain hollow form of extrudate during hardening

12. Extrusion Die for Coating Wire • Polymer melt is applied to bare wire as it is pulled at high speed through a die • A slight vacuum is drawn between wire and polymer to promote adhesion of coating

13. Sheet and Film Production via: Calendering Feedstock is passed through a series of rolls to reduce thickness to desired gage • Process is noted for good surface finish and high gage accuracy • Products: PVC floor covering, shower curtains, vinyl table cloths, pool liners, etc.

14. Injection Molding Polymer is heated to a highly plastic state and forced to flow under high pressure into a mold cavity where it solidifies and the molding is then removed. • Produces discrete components almost always to net shape or near net shape • Typical cycle time ~1 to 30 sec • Mold may contain multiple cavities, so multiple moldings are produced each cycle • Some thermosets and elastomers are injection molded, but equipment and operating parameters must be modified to avoid: premature cross‑linking

15. Injection Molding Machine Two principal components: • Injection unit (operates similar to an extruder) • Melts and delivers polymer melt (plunger for injection) • Clamping unit • Opens and closes mold each injection cycle

16. Injection Molding

17. 1. Mold Closes 2. Inject Plastic 3. Cooling Time 4. Mold Opens

18. Two‑Plate Mold • Cavity – slightly oversized to allow for shrinkage • Distribution channel • Sprue - leads from nozzle into mold • Runners - lead from sprue to cavity (or cavities) • Gates - constricts flow to: decrease viscosity • Ejection system – pins built into moving half of mold • Cooling system – typically water • Air vents – at end of flow path

19. Three‑Plate Mold • Advantages over two-plate mold: • As mold opens, runner and parts disconnect and drop into two separate containers under mold • Allows automatic operation of molding machine • Allows material to be injected at the mold base or middle, rather than side injection, which a two-plate mold must do.

20. Hot‑Runner Mold • Heaters are located around the runner channels which eliminates solidification of the: sprue and runner • This type of mold improves mold flow as material is heated right up to when in enters the cavity.

21. Shrinkage • Polymers have high thermal expansion coefficients, so significant shrinkage occurs during solidification • Typical shrinkage values: PlasticShrinkage, mm/mm (in/in) Nylon‑6,6 0.020 Polyethylene 0.025 Polystyrene 0.004 PVC 0.005 • Dimensions of mold cavity must be larger than specified part dimensions: Dc= Dp + DpS + DpS2 where Dc = dimension of cavity; Dp = molded part dimension, and S = shrinkage value and the third term on right hand side corrects for shrinkage in the shrinkage

22. Shrinkage Factors • Fillers in the plastic tend to: reduce shrinkage • Injection pressure – higher pressures in the mold cavity tend to: reduce shrinkage • Compaction time – longer time tends to: reduce shrinkage • Molding temperature - higher temperatures lower polymer melt viscosity, which tends to: reduce shrinkage

23. Thermoplastic Foam Injection Molding Molding of thermoplastic parts that possess dense outer skin surrounding lightweight foam center • Part has high stiffness‑to‑weight ratio suited to structural applications • Produced either by introducing a gas into molten plastic in injection unit or by mixing a gas‑producing ingredient with starting pellets • A small amount of melt is injected into mold cavity, where it expands to fill cavity • Foam in contact with cold mold surface collapses to form dense skin, while core retains cellular structure

24. Injection Molding of Thermosets • Temperatures in the injector are generally: lower • The barrel length of the injection unit is generally: shorter • Melt is injected into a heated mold, where cross‑linking occurs to cure the plastic • The most time‑consuming step in the cycle: curing in the mold

25. Compression Molding • A widely used molding process for thermosets • Also used for rubber tires and polymer composites • Molding compound available in several forms: powders or pellets, liquid, or preform • Amount of charge must be precisely controlled (1) charge is loaded, (2) and (3) charge is compressed and cured, and (4) part is ejected and removed.

26. Molds for Compression Molding • Simpler than injection molds • As opposed to injection molding, there is no: sprue and runner system • Limited to simpler part geometries due to lower flow capabilities of TS materials • Mold must be heated, usually by electric resistance, steam, etc • Typical molding materials: phenolics, melamine, epoxies, urethanes, and elastomers • Typical compression-molded products: • Electric plugs, sockets, and housings; pot handles, and dinnerware plates

27. Transfer Molding TS charge is loaded into a heated chamber; pressure is applied to force the soft polymer into the heated mold. • Pot transfer molding: charge is injected from a "pot" through a vertical sprue channel into cavity • Plunger transfer molding: plunger injects charge from a heated well through channels into cavity

28. Compression vs. Transfer Molding • In both processes, scrap is produced each cycle as leftover material, called the: cull • The TS scrap cannot be recovered • Transfer molding is capable of molding more intricate part shapes than compression molding but not as intricate as injection molding • Transfer molding lends itself to molding with inserts, in which a metal or ceramic insert is placed into cavity prior to injection, and the plastic bonds to insert during molding

29. Blow Molding • Molding process in which air pressure is used to inflate soft plastic into a mold cavity • Material limited to: thermoplastics • Accomplished in two steps: • Fabrication of a starting tube, called a: parison • Inflation of the tube to desired final shape • Two methods: • Extrusion blow molding • Injection blow molding

30. Extrusion Blow Molding (1) extrusion of parison; (2) parison is pinched at the top and sealed at the bottom around a metal blow pin as the two halves of the mold come together; (3) the parison is inflated; and (4) mold is opened to remove the solidified part.

31. Injection Blow Molding (1) parison is injection molded around a blowing rod; (2) injection mold is opened and parison is transferred to a blow mold; (3) parison is inflated; and (4) blow mold is opened and product removed.

32. Vacuum Thermoforming • Starting material:thermoplastic sheetor film • To soften, heat is supplied by radiant electric heaters located on one or both sides Products: bathtubs, contoured skylights, door liners for refrigerators, boat hulls, shower stalls, advertising displays and signs, etc.

33. Polymer Casting Pouring liquid resin into a mold, using gravity to fill cavity, where polymer hardens • Both thermoplastics and thermosets are cast • Thermoplastics: acrylics, polystyrene, polyamides (nylons) and PVC • Thermosetting polymers: polyurethane, unsaturated polyesters, phenolics, and epoxies • Simpler mold • Suited to low quantities

34. Polymer Foams • A polymer‑and‑gas mixture, with gas added by: • physical mixing or injection (air, nitrogen, CO2) • chemical blowing agent that decomposes at elevated temperatures • Two types: • closed cell (a) • open cell (b) • Product methods: • make the beads first, then feed the beads into a cavity to be fused together (e.g. styrofoam cups) • injection mold using a chemical blowing agent • extrude sheets (least expensive method)

35. Product Design Guidelines: General • Strength and stiffness • Plastics are not as strong or stiff as metals • Avoid applications where high stresses will be encountered • Creep resistance is also a limitation • Strength‑to‑weight ratios for some plastics are competitive with metals in certain applications

36. Product Design Guidelines: General • Impact Resistance • Capacity of plastics to absorb impact is generally good; plastics compare favorably with most metals • Service temperatures • Limited relative to metals and ceramics • Thermal expansion • Dimensional changes due to temperature changes much more significant than for metals

37. Product Design Guidelines: General • Many plastics are subject to degradation from sunlight and other forms of radiation • Some plastics degrade in oxygen and ozone atmospheres • Plastics are soluble in many common solvents • Plastics are resistant to conventional corrosion mechanisms that afflict many metals

38. In-class Exercise Q in plastic extrusion The diameter, D, of an extruder barrel is 65 mm and its length, L, = 1.75 m. The screw rotates at 55 rev/min. The screw channel depth, dc, = 5.0 mm, and the flight angle = 18°. The head pressure, p, at the die end of the barrel is 5.0 x 106 Pa. The viscosity of the polymer melt is given as 100 Pas. Find the volume flow rate (cm3/s) of the plastic in the barrel. • D=65mm, L=1.75m, N=55rev/min, dc=5mm, A=18°, p=5x106Pa, η=100 Pas • Qx = Qd – Qb, where, • Qd = 0.5 π2 D2 N dc sinA cosA = 28.08×10-5 m3/s= 28.08 cm3/s • Qb = 5.803×10-6m3/s = 5.804 cm3/s • Qx = Qd – Qb = 28.08 – 5.804 = 22.28 cm3/s Qd = 0.5 π2 D2 N dc sinA cosA

39. Next Lecture – Composite Materials • Exam grade distribution • Exam 1 problem review