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Honors Chemistry Chapter 4. The Structure of the Atom. Early Theories of Matter. Atomic Theory Democritus Dalton. Dalton’s Atomic Theory. Based on experimental results Matter consists of atoms All the atoms of an element are alike
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Honors Chemistry Chapter 4 The Structure of the Atom
Early Theories of Matter • Atomic Theory • Democritus • Dalton
Dalton’s Atomic Theory • Based on experimental results • Matter consists of atoms • All the atoms of an element are alike • Atoms of one element differ from atoms of other elements • Atoms are indestructible and only rearranged during chemical reactions
Atoms can combine in simple, whole-number ratios to form compounds • Pg. 102
Discovery of the electron • Cathode ray tube (Crooke’s tube) • Pg. 105 picture • Cathode rays • Particles with negative charge
JJ Thompson • Used cathode ray tube to determine charge/mass ratio of particles • Identified the particles as electrons
Robert Millikan • Calculated the charge and mass of an electron • “Oil drop” experiment • Electron carries exactly one unit of negative charge • Mass is 1/1840 the mass of a hydrogen atom
Each electron carries one unit of negative charge • Proposed “plum pudding” model of the atom • “chocolate chip cookie” model • Electrons stuck in positive “dough”
Rutherford’s Gold Foil Experiment • pg. 107
IMPORTANT RESULTS!!!! • New atomic model • Atom mostly empty space • Tiny, dense central core – nucleus
Contains all the atoms positive charge • Volume of space in which the electrons move huge compared to volume of the nucleus
Book analogy: • If an atom had a diameter of 2 football fields, the nucleus would be the size of a nickel!
NUCLEONS – particles located within the nucleus • Protons and neutrons • Protons • Positive charge • Mass of 1 amu (atomic mass unit)
Neutrons • No charge (neutral) • Mass = 1 amu
Electrons • Located outside the nucleus in “shells” • Each carries one unit of negative charge • Mass 1/1840 amu • Pg. 106 chart for subatomic particles
Atomic number • Number of protons in the nucleus • Identifies the atom as an atom of a particular element • Determines its position on the Periodic Table • Atomic # = #protons = #electrons
MASS NUMBER • Number of protons + number of neutrons • Number of neutrons = mass number – atomic number Isotopes
Isotope Notation • Pg. 112 Sample and practice
Average atomic mass • Weighted average of the naturally occurring isotopes of that element • Is a decimal because of the existence of isotopes • Pg. 114 Table 4.3 • Pg. 116-117 #21-24 • Video: How to Calculate an Average Atomic Weight.
Periodic Table • Arrangement of elements where the elements are separated into groups bases on a set of repeating properties • Can compare properties of elements based on their position on the table
Arranged according to increasing atomic number • Horizontal rows – periods • Vertical columns – groups (families) • Elements within a group have similar chemical and physical properties