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Heat and Power Integration. CHEN 4460 – Process Synthesis, Simulation and Optimization Dr. Mario Richard Eden Department of Chemical Engineering Auburn University Lecture No. 9 – Heat and Power Integration: Targeting October 23, 2012
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Heat and Power Integration CHEN 4460 – Process Synthesis, Simulation and Optimization Dr. Mario Richard EdenDepartment of Chemical EngineeringAuburn University Lecture No. 9 – Heat and Power Integration: Targeting October 23, 2012 Contains Material Developed by Dr. Daniel R. Lewin, Technion, Israel
Lecture 8 – Objectives Given data on the hot and cold streams of a process, you should be able to: • Compute the pinch temperatures • Compute the Maximum Energy Recovery (MER) targets using graphical and/or algebraic methods
Motivating Example • What is wrong with this process from an energy viewpoint? No integration of energy!!!!
Short Bibliography • Early pioneers • Rudd @ Wisconsin (1968) • Hohmann @ USC (1971) • Central figure • Linnhoff @ ICI/UMIST (1978) • Currently: President, Linnhoff-March • Recommended text • Seider, Seader and Lewin (2004): Product and Process Design Principles, 2 ed. Wiley and Sons, NY • Linnhoff et al. (1982): A User Guide on Process Integration for the Efficient Use of Energy, I. Chem. E., London • Most comprehensive review: • Gundersen, T. and Naess, L. (1988): The Synthesis of Cost Optimal Heat Exchanger Networks: An Industrial Review of the State of the Art, Comp. Chem. Eng., 12(6), 503-530
Capital vs. Energy 1:3 • The design of Heat Exchanger Networks (HENs) deals with the following problem: • Given: • NH hot streams, with given heat capacity flowrate, each having to be cooled from supply temperature THS to targets THT • NC cold streams, with given heat capacity flowrate, each having to be heated from supply temperature TCS to targets TCT Design: An optimum network of heat exchangers, connecting between the hot and cold streams and between the streams and cold/hot utilities (furnace, hot-oil, steam, cooling water or refrigerant, depending on the required duty temperature)
Capital vs. Energy 2:3 • Optimality • Implies a trade-off between CAPITAL COSTS (cost of equipment) and ENERGY COSTS (cost of utilities). • Network for minimal equipment cost ? • Network for minimal energy cost ?
Capital vs. Energy 3:3 • Numerical Example • Design A: (AREA) = 13.3 • [ A = Q/UTlm ] • Design B: (AREA) = 20.4 [ A = Q/UTlm ]
Some Definitions 1:3 TS= Supply temperature (oC)TT= Target temperature (oC) H = Stream enthalpy (MW) CP = Heat capacity flowrate (MW/ oC) = Flowrate x specific heat capacity = m x Cp(MW/ oC)
20o • 30o • 10o • 20o Some Definitions 2:3 • Minimum Allowable Temperature Driving Force DTmin • Which of the two counter-current heat exchangers illustrated below violates DT 20°F (i.e. DTmin = 20°F) ? Clearly, exchanger A violates the Tmin constraint
Some Definitions 3:3 Exchanger Duty (Q): Data: Hot stream CP = 0.3 MW/ oC Cold stream CP = 0.4 MW/ oC Check: T1 = 40 + (100 - 60)(0.3/0.4) = 70oC Q = 0.4(70 - 40) = 0.3(100 - 60) = 12 MW Heat Transfer Area (A): Data: Overall heat transfer coefficient, U=1.7 kW/m2oC (Alternative formulation in terms of film coefficients) Tlm = (30 - 20)/loge(30/20) = 24.66 So, A = Q/(UTlm) = 12000/(1.724.66) = 286.2 m2
Simple Example Utilities:Steam @ 150 oC, CW @ 25oC Design a network of steam heaters, water coolers and exchangers for the process streams. Where possible, use exchangers in preference to utilities.
Simple Example - Targets Units: 4Steam: 60 kWCooling water: 18 kWAre these numbers optimal??
Temperature-Enthalpy Diagram Correlation between Tmin, QHmin and QCminMore in, More out! QHmin + x QCmin + x
The Composite Curve 1:2 Three (3) hot streams
The Composite Curve 2:2 Three (3) hot streams
Simple Ex. – Hot Composite Not to scale!! Not to scale!!
Simple Ex. – Cold Composite Not to scale!! Not to scale!!
Thermal Pinch Diagram Move cold composite horizontally until the two curves are exactly ΔTmin apart
Simple Ex. - Pinch Diagram QHmin = 48 kW QCmin = 6 kW Maximum Energy Recovery (MER) Targets! THpinch = 70 TCpinch = 60
x The Pinch • +x • +x • The “pinch” separates the HEN problem into two parts: • Heat sink - above the pinch, where at least QHmin utility must be used • Heat source - below the pinch, where at least QCmin utility must be used.
Significance of the Pinch • Do not transfer heat across pinch • Do not use cold utilities above the pinch • Do not use hot utilities below the pinch
Algebraic Targeting Method • Temperature scales • Hot stream temperatures (T) • Cold stream temperatures (t) • Thermal equilibrium • Achieved when T = t • Inclusion of temperature driving force ΔTmin • T = t + ΔTmin • Thus substracting ΔTmin from the hot temperatures will ensure thermal feasibility at all times
Algebraic Targeting Method • Exchangeable load of the u’th hot stream passing through the z’th temperature interval: • Exchangeable capacity of the v’th cold stream passing through the z’th temperature interval:
Algebraic Targeting Method • Collective load of the hot streams passing through the z’th temperature interval is: • Collective capacity of the cold streams streams passing through the z’th temperature interval is:
Algebraic Targeting Method • Heat balance around each temperature interval:
Algebraic Targeting Method • The enthalpy cascade • r0 is zero (no hot streams exist above the first interval) • Feasibility is insured when all the rz's are nonnegative • The most negative rz corresponds to the minimum heating utility requirement (QHmin) of the process • By adding an amount (QHmin) to the top interval a revisedenthalpy cascade is obtained
Algebraic Targeting Method • The revised enthalpy cascade • On the revised cascade the location of rz=0 corresponds to the heat-exchange pinch point • Overall energy balance for the network must be realized, thus the residual load leaving the last temperature interval is the minimum cooling utility requirement (QCmin) of the process
Algebraic Targeting Method • Example • Two hot streams and two cold streams • ΔTmin = 10°F • Step 1: Temperature intervals • Substract ΔTmin from hot temperatures • 250°F 240°F 235°F 180°F 150°F 120°F
Algebraic Targeting Method • Step 2: Interval heat balances • For each interval calculate the enthalpy load • Hi = (Ti Ti+1)(CPHotCPCold )
Algebraic Targeting Method Step 3: Enthalpy cascade QHmin Most negative residual TCpinch = 180°F QCmin
Summary – Heat Integration On completion of this part, given data on the hot and cold streams of a process, you should be able to: • Compute the pinch temperatures • Compute the Maximum Energy Recovery (MER) targets using graphical and/or algebraic methods
Other Business • No lecture next week (October 30) • I will be in Pittsburgh for the AIChE Annual Meeting • Next Lecture – November 6 • Heat and Power Integration: Network Design (SSLW p. 261-280)