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Properties of Alkanes Long, unbranched alkanes tend to have higher melting points, boiling points, and enthalpies of vaporization than their branched isomers. Cycloalkanes : ring alkanes; made up of CH 2 groups General formula: C n H 2n. cyclohexane. “boat”. “chair”.
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Properties of Alkanes Long, unbranched alkanes tend to have higher melting points, boiling points, and enthalpies of vaporization than their branched isomers
Cycloalkanes: ring alkanes; made up of CH2 groups General formula: CnH2n
cyclohexane “boat” “chair”
Unsaturated Aliphatic Hydrocarbons Alkenes: carbon-carbon double bond (sp2 hybridized) Alkynes: carbon-carbon triple bond (sp hybridized) CHCH (acetylene) CH2=CH2 (ethylene)
IUPAC Nomenclature for Aliphatic Hydrocarbons Straight-chain alkanes - name ends in -ane Branched alkane - side chain is a “substituent” name the substituent formed by the removal of one H atom from an alkane by changing the ending from -ane to -yl name of the alkane is derived from the longest continuous carbon chain to indicate the position of the substituent, the C atoms in the longest chain are numbered, starting at the end that will give the lowest number for the position of the first attached group
use prefixes di-, tri-, tetra-, penta-, etc. to indicate the number substituents are listed in alphabetical order (disregard the prefix) 2,2,4-trimethylpentane 2-ethyl-1,1-dimethylcyclohexane (sum of the numbers is lowest)
Alkenes and Alkynes Double bonds - change the “ane” suffix to “ene” Triple bonds - change the “ane” to “yne” Position of the multiple bond is given by the number of the first C atom in the multiple bond CH3-CH2-CH=CH-CH3 2-pentene CH3-CH2-CH2-CCH3 1-pentyne CH2=CH-CH=CH2 1,3-butadiene
Reactions of Alkanes Alkanes are not very reactive Strong C-C and C-H bonds mean bond enthalpy (kJ/mol) C-C 348 C-H 412 1) Oxidation Reactions CH4(g) + 2 O2(g) CO2(g) + 2H2O(g) DHo = -890 kJ Break the strong C-H bond, but replaced by two C=O bonds (mean bond enthalpy of C=O is 743 kJ/mol). Also O-H bond is strong (463 kJ/mol)
light or heat CH4(g) + Cl2(g) CH3Cl(g) + HCl(g) light or heat Cl-Cl 2 Cl initiation step 2) Substitution Reactions Cl + CH4 CH3 + HCl propagation steps CH3+ Cl2 CH3Cl+ Cl Cl + Cl Cl2 termination steps CH3+ CH3 CH3CH3 CH3+ Cl CH3Cl
catalyst CH3CH3(g) CH2=CH2(g) + H2(g) Alkenes Prepration - Elimination Reactions 1) From alkanes by dehyrogenation 2) From haloalkanes - dehydrohalogenation CH3CH2Cl + KOH CH2=CH2 + KCl + H2O 3) Dehydration of alcohols H2SO4 CH3CH2OH CH2=CH2(g) + H2O http://www.whfreeman.com/chemicalprinciples/con_index.htm?18
Reactions 1) Addition reactions Double bonds are more reactive than single bonds http://www.whfreeman.com/chemicalprinciples/con_index.htm?18
1-chloropropane 2-chloropropane 2-chloropropane is the product The H atom always goes to the C atom of the double bond that already has the most H atoms - Markovnikov addition
1-propanol Markovnikov’s rule holds - 2-propanol is favored 2-propanol
catalyst Polymerization reactions n CH2=CH2 -[CH2-CH2]-n cis geometry
Aromatic Hydrocarbons Parent compound of aromatic hydrocarbons - benzene (C6H6) C is sp2 hybridized, ring is planar As a substituent - phenyl (C6H5)
Phenol (C6H5OH) Toluene 2,4,6-trinitrotoluene (TNT)
Resonance Stablization p-bonding electrons are delocalized over all C atoms Resonance imparts stability to benzene with respect to hydrogenation and oxidation
Substitution Reactions - p-bonds in the ring are left intact; substituent replaces an H atom