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Why do Titration Curves Look Like THAT ????. Calculate the pH when the following quantities of 0.100 M NaOH solution have been added to 50.0 mL of 0.100 M HCl solution: A. 30.0 mL B, 49.0 mL C. 49.5 mL D. 50.0 mL E. 50.5 mL F. 60.0 mL. Solution for 30.0 mL NaOH.
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Calculate the pH when the following quantities of 0.100 M NaOH solution have been added to 50.0 mL of 0.100 M HCl solution: A. 30.0 mL B, 49.0 mL C. 49.5 mL D. 50.0 mL E. 50.5 mL F. 60.0 mL
Solution for 30.0 mL NaOH • Both Na+ and Cl- are spectator ions. • Find how many moles H+ and moles OH- present, then calculate how many mole of each ion remain after neutralization.
New pH now… • Remaining H+ mole / new soln volume
New pH now… • Remaining H+ mole / new soln volume
New pH now… • Remaining H+ mole / new soln volume
New pH now… • [H+] = [OH-] = 0 M • Neutral • pH = 7
New pH now… • Remaining OH- mole / new soln volume
New pH now… • Remaining OH- mole / new soln volume
Titration curve for a strong acid by a strong base Any indicator that changes color along the steep portion of the titration curve is suitable for the titration. Methyl violet changes color too soon, and alizarin yellow R too late.
Subtle vocabulary point • Equivalence point: where equal moles of acid and base are present. • End Point: where an indicator chemical changes color. It may not be exactly at the equivalence point, but generally very close.