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Learn about the fabrication process and thermal analysis of PLGA microspheres using paraffin and octadecane as phase change materials. Explore techniques such as SEM imaging and DSC analysis for evaluation. Discover the potential applications in heat transfer technologies.
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G Love Kristin Brodie Jeff Colton Colin Galbraith Bushra Makiya Tiffany Santos
Fabrication of Microspheres • Used protocol learned at beginning of semester to fabricate PLGA microspheres • Homogenizer speed: • Paraffin: 3.5, 5 • Octadecane: 4, 5 • Pipette used to separate water and paraffin • Filter used for octadecane (0.22m)
SEM of Microspheres • Paraffin Wax • Homogenizer speed 5 • Average size: 150m • Range: 50 – 300m
SEM of Microspheres (2) • Paraffin Wax • Homogenizer speed 3.5 • Average size: 200m • Range: 50 – 400m
DSC for Octadecane and PEG • Octadecane • PEG
Heat Flow Model for a Finger • Finger assumed to be a cylinder • Power = 2rLq = 2L(T1-T3)/R • R = Fabric Resistance + BL Resistance • FR = 1/kc * ln (rc/rw) • BLR = 1/(rc*h) • h = 1.22*(T/D)^(1/4) for a horizontal pipe • Approximating values: • h~10 W/m2K • Power~2.5 W • A hand can be assumed to be a cylinder • rhand = 2*rfinger
Heat Transfer Through Gloves • Heating element in the glove (73cm) • Thermistor in and out of the glove • Power: 3.6V • Current: 0.55A • Weight to reduce air flow into glove
I*V/A = h (T[in] – T[out]) I = 0.55A V = 3.6V A = 0.05m2 T[in] = 317.42K T[out] = 294.98K h = 1.765 W/m2K Heat Flow Results
Results • Ni:Cr 80:20wt% chosen for large elastic region • Octadecane preferred over PEG for Heat of crystallization properties • Experimental thermal coefficient is similar to theoretical value
What Will We Do Next? • Phase Change Material • Test integrity of PVA • Fabricate microspheres of PEG • Incorporation of phase change material into fabric • DSC of microspheres • Heating Elements • Test battery with Prof Ceder • Incorporation of thermal switch • Choose a fabric to get specific thermal properties