1 / 12

Intermolecular Forces

Intermolecular Forces. Chemistry. Generally, inter molecular forces are much weaker than intra molecular forces. Intermolecular Forces. Intermolecular forces are attractive forces between molecules. Intramolecular forces hold atoms together in a molecule.

dorian-garrison
Download Presentation

Intermolecular Forces

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript

  1. Intermolecular Forces Chemistry

  2. Generally, intermolecular forces are much weaker than intramolecular forces. Intermolecular Forces Intermolecular forces are attractive forces between molecules. Intramolecular forces hold atoms together in a molecule. • Intermolecular vs Intramolecular • 41 kJ to vaporize 1 mole of water (inter) • 930 kJ to break all O-H bonds in 1 mole of water (intra) “Measure” of intermolecular force boiling point melting point DHvap DHfus DHsub

  3. or … … H H B A A A Types of Intermolecular Forces 1. Hydrogen Bond (strongest) The hydrogen bond is a special dipole-dipole interaction between the hydrogen atom in a polar N-H, O-H, or F-H bond and an electronegative O, N, or F atom. IT IS NOT A BOND. A & B are N, O, or F

  4. Hydrogen Bond 11.2

  5. Decreasing molar mass Decreasing boiling point Why is the hydrogen bond considered a “special” dipole-dipole interaction?

  6. Ion-Dipole Interaction Types of Intermolecular Forces 2. Ion-Dipole Forces Attractive forces between an ion and a polar molecule

  7. Orientation of Polar Molecules in a Solid Types of Intermolecular Forces 3. Dipole-Dipole Forces Attractive forces between polar molecules

  8. Types of Intermolecular Forces 4. Dispersion Forces – van der Walls forces/London forces (weakest) Attractive forces that arise as a result of temporary dipoles induced in atoms or molecules ion-induced dipole interaction dipole-induced dipole interaction

  9. Dispersion forces usually increase with molar mass. Intermolecular Forces 4. Dispersion Forces Continued Polarizability is the ease with which the electron distribution in the atom or molecule can be distorted. • Polarizability increases with: • greater number of electrons • more diffuse electron cloud

  10. O O S What type(s) of intermolecular forces exist between each of the following molecules? HBr HBr is a polar molecule: dipole-dipole forces. There are also dispersion forces between HBr molecules. CH4 CH4 is nonpolar: dispersion forces. SO2 SO2 is a polar molecule: dipole-dipole forces. There are also dispersion forces between SO2 molecules.

  11. Comparing Intermolecular Forces

More Related