Class 5.1 Oxidising Agents Learning Tool T-1000

1. Class 5.1 Oxidising Agents Learning Tool T-1000 This work has been produced by DGL (Aust) Pty Ltd This Learner’s Tool is about the skills and knowledge required to store and warehouse Class 5.1 Oxidising Agents at DGL (Aust) facilities. This includes operational requirements for the safe and efficient control of all functions and effective management of hazardous situations.

2. Before you get started • It is important that you complete all sections in this learning tool as it has been designed so that • You can abide by the procedures of our organization. • You can apply what you have learnt in this package in your day to day activities • This Learning Tool is designed to be relevant only to DGL (Aust) Pty Ltd employees and only applied whilst employed with DGL (Aust) Pty Ltd • You may have already acquired knowledge in the area identified in this package as you may have completed some specialized training. Or you may have been working within the industry for some time. Should you identify any improvement opportunities in the information contained in this package or have difficulties completing the package please contact National Training and Compliance Manager DGL (Aust) Pty Ltd PO BOX 1594 EAGLE FARM QLD 4009 Ph 07 3868 1001 Fax 07 3868 1055

3. Definition of a Class 5.1 • A class 5.1 product is defined as • Class 5.1 dangerous goods are those substances which, although not necessarily combustible themselves, may readily liberate oxygen, or be the cause of oxidation of other materials. As a result, they may start or contribute to the start of a fire and increase the violence of a fire. • (Note 1) • Note (1) NT Worksafe Bulletin – Storage of minor quantities of class 5.1 oxidising agents

4. Properties of Class 5.1 • Oxidising agents may also react violently or even explosively with other substances, a well known example of this being calcium hypochlorite and brake fluid. Oxidising agents must be kept away from all flammable and combustible materials, and most other dangerous goods. Since oxidising agents supply oxygen to a fire, it is not usually possible to fight fires involving Class 5.1 substances by depriving the fire of air eg, the use of fire blankets, carbon dioxide and Halon fire extinguishers. Another hazard posed by oxidising agents is their ability to cause corrosion of many materials, and stores for Class 5.1 dangerous goods should be designed with this in mind. • Many oxidising agents are also hazardous to people through inhalation of dusts and vapours, skin and eye contact and ingestion. • (Note 1) • Note (1) NT Worksafe Bulletin - Storage of minor quantities of class 5.1 oxidising agents

5. Class 5.1 Label for Oxidising Agents Note 1 * Hazard description on No. 5.1 label (Division 5.1) may alternatively read “OXIDISING AGENT” Note(1) Source the Australian Dangerous Goods Code 7th Edition page 426

6. Classification of Class 5.1 Products • Oxidising Solids • A solid substance is classified in Division 5.1 if the 4:1 or 1:1 sample-to-cellulose ratio (by mass) tested, exhibits a mean burning time equal to or less than the mean burning time of a 3:7 mixture (by mass) of potassium bromate and cellulose. • Oxidising Liquids • A liquid substance is classified in Division 5.1 if the 1:1 mixture, by mass, of substance and cellulose tested, exhibits a mean pressure rise time less than or equal to the mean pressure rise time of a 1:1 mixture, by mass, of 65% aqueous nitric acid and cellulose. • (Note 1) • Note (1) Source the Australian Dangerous Goods Code 7th Edition page 76 & 77

7. Storage • STACKS • Where packages of oxidizing agents are kept in stacks (i.e. pallet racking is not used), the maximum capacities of such stacks shall be as set out in Table 4.1. Where pallet racking is not used— • (a) stacks of packages shall be limited to 3 m in height; and • (b) a free air space of not less than 1.2 m shall be maintained between stacks of oxidizing agents and the outer walls of the building. • The requirements of Items (a) and (b) do not apply where pallet racking is used. • NOTE: Where containers are to be stacked, the relevant MSDS or the supplier of the oxidizing agent should be consulted for further advice on maximum stacking heights. Stacks shall be separated from each other by at least 3 m or by concrete walls of not less than 100 mm thickness.

8. Storage Continued • IBC STORAGE • IBCs may be kept in accordance with the requirements of this Section as if they were packages, provided that— • (a) their capacity does not exceed 1600 kg or 1600 L; • (b) they remain closed while in storage; and • (c) they do not contain oxidizing agents of PG I. • The following requirements and considerations are specific to the storage of oxidizing agents in IBCs: • (a) IBCs may be kept in accordance with the requirements of the Standard, as if they were packages, provided that— • (i) their capacity does not exceed 1600 kg or 1600 L; and • (ii) they remain closed while in storage; and • (iii) they do not contain oxidizing agents of PG I. • (b) Where the capacity of IBCs exceeds 1600 kg or 1600 L— • (i) in the case of storage of PG III substances, the maximum capacities of individual stacks and stores shall be as set out in Table 4.1; • (ii) in the case of storage of liquids of other than PG III, Section 7 of the Standard shall apply; and • (iii) in the case of storage of solids of other than PG III, Section 6 of the Standard shall apply. • (c) Where liquids are kept, the requirements relating to bunds and compounds apply to storage in IBCs, except that, where an IBC is shielded with a compatible material, the distance specified in the standard does not apply. • (d) Separation and segregation distances for IBCs shall comply with the AS 4326—2008, as appropriate. • (e) Where IBCs are to be kept in a factory— • (i) the capacity of the IBCs shall not exceed 1600 kg or 1600 L; and • (ii) the separation distances in Item (d) above shall be measured to any areas that are not associated with the use of the oxidizing agent. • (f) IBCs designed for single-trip use shall not be reused for dangerous goods. IBCs designed for multi-trip use shall be inspected prior to filling, to ensure that they are free from contamination or damage and have sufficient strength for their further use. • (g) Where IBCs are connected to a process, the relevant clauses of Section 7 of the AS 4326—2008 shall apply. • (h) Where IBCs containing ammonium nitrate are kept, the requirements of Section 9 of • the AS 4326—2008 apply in addition to those above. • Note (1) Source the Australian AS 1940—2004 The storage and handling of Flammable and combustible liquids page 51

9. Storage Continued • STORAGE IN CABINETS • Types of substances kept • Cabinets for the storage of oxidizing agents shall not be used for the storage of other types of substances. Where more than one oxidizing agent is kept in a cabinet, the oxidizing agents shall be compatible. • Maximum quantities to be kept • The maximum quantity of Packing Group I substances kept in a single storage cabinet shall not exceed 50 kg or 50 L. The maximum quantity of Packing Group II substances kept in a single storage cabinet shall not exceed 250 kg or 250 L. • Subject to these provisions, the maximum quantity of all oxidizing agents kept in a single storage cabinet shall be— • (a) 250 kg or 250 L if the cabinet is indoors; or • (b) 850 kg or 850 L if the cabinet is outdoors. • NOTE: Units of kilograms apply to solids and units of litres to liquids. • OUTDOOR STORAGE • Packaged oxidizing agents shall only be stored outdoors if— • (a) the storage area complies with - • (i) An open-air, unroofed enclosure. • (b) the product, container and label will not be adversely affected by exposure to the elements; • (c) the enclosure is located away from any building; and • (d) the crystalline structure of the oxidizing agents is not crucial, or will not be affected by the storage conditions. • (Note 1) • Note (1) Source the Australian AS 1940—2004 The storage and handling of Flammable and combustible liquids page 51

10. Management of Leaks • General • Every endeavour shall be made to prevent leaks or spills, and to control them if they do occur. Clean-up action shall be initiated immediately. Leaked or spilled oxidizing agents shall be kept and disposed of in accordance with Local & State legislation • NOTE: Entry into the affected area should always be under supervision. • Clean-up materials and equipment • The following items of clean-up materials and equipment shall be readily available on premises where oxidizing agents are kept or handled: • (a) An adequate supply of water. • (b) Suitable non-combustible, inert absorbents, e.g. clean vermiculite or sand, shall always be available where liquid oxidizing agents, other than hydrogen peroxide or mixtures containing hydrogen peroxide, are kept or handled. These absorbents shall be clearly identified. • NOTE: Such absorbents may be required to prevent liquid oxidizing agents from entering drains or watercourses. • (c) Equipment suitable for sweeping up leaks and spills of solid oxidizing agents, and for sweeping up absorbent that has been used to absorb leaks and spills of liquid oxidizing agents, e.g. a broom or brush. • (d) Clean, sealable (and, where appropriate, vented) waste bins, made of plastics or other appropriate material compatible with the oxidizing agents being dealt with, for the containment of absorbed spills. It is advisable that such waste bins be filled to not more than two-thirds of their capacity. • (e) Appropriate personal protective equipment

11. Management of Leaks Continued • Actions for dealing with leaks and spills • At every occurrence of a leak or spill, the emergency plan shall be implemented and disposal shall be carried out without delay. Leaking packages shall be positioned in such a manner as to stop or minimize the leak and, if necessary and safe to do so, be moved to a safe location. Either the package should be placed in a suitable container, e.g. a plastic bag or an oversize drum, or its contents should be transferred to a clean packaging. The exterior of the clean packaging shall be clearly marked. • NOTE: Any new package that is formed as described above may need to be vented. • Small spills on the floor, or on the walls or structures of a building, should be collected, absorbed or diluted, as appropriate. Where spills are absorbed, the used absorbent shall be placed in a suitable waste drum for immediate disposal in accordance Local & State legislation. • Note (1) • Note (1) Source the Australian AS 4326—2008 The storage and handling of oxidizing agents • page 73 & 74

12. Personal Habits • The following directions shall be followed by all persons whose work involves the handling of oxidizing agents: • (a) Do not introduce, keep, prepare or consume any food or drink, or use tobacco, in any area where oxidizing agents are kept or handled. • (b) After handling oxidizing agents, always wash your hands before eating, drinking, smoking or using the toilet, and after work. • (c) Immediately attend to injuries caused by contact, or suspected contact, with oxidizing agents. • The above directions, or wording to the same effect, shall be prominently displayed in the work area. • Note (1) • Note (1) Source the Australian AS 4326—2008 The storage and handling of oxidizing agents • page 70 & 71

13. First Aid • A first aid station shall be provided, and maintained, in a clean area. It shall comprise, as a minimum— • (a) an appropriate first aid kit; • (b) a readily-available supply of water; and • (c) a poster detailing the correct method of resuscitation. It is recommended that— • (i) at least one person on the premises is trained in first aid; and • (ii) a list of persons trained in, and designated as being responsible for the administering of, first aid should be shown on all notice boards on the premises. • Note (1) • Note (1) Source the Australian AS 4326—2008 The storage and handling of oxidizing agents • page 71

14. Test your knowledge • Through the following slides you will be asked an number of questions to show that you have understood the content of this learning tool • Please record your answer on the training form F-260. • You will be required to submit the answers to the DGL HSEQ unit

15. Question 1 • What can oxidising agents start to produce? • a) Organisms • b) Oxygen • c) rust • d) Carbon Dioxide

16. Question 2 • What should oxidising agents be kept away from? • a) Corrosive substances, and most other dangerous goods • b) Gases, and most other dangerous goods • c) Flammable solids, and most other dangerous goods • d) Flammables & Combustibles, and most other dangerous goods

17. Question 3 • According to the Class 5.1 Placard what are it’s distinctive features of the symbol located on the top of the placard? • a) Flame over a diamond • b) Circle over the Flame • c) Flame over a circle • d) Flame over a square

18. Question 4 • According to the Australian Standard (AS 4326—2008) IBCs can be treated like packaged goods for storage if the don’t contain what? • a) Packing Group I, 1600lt or 1600kg • b) 1500lt or 1500kg , Packing Group II • c) 1300lt or 1300kg, Packing Group III • d) Packing Group I, 1000lt or 1000kg

19. Question 5 • What is the maximum amount of solid oxidising agents or liquid oxidising agents that can be stored in a cabinet outdoors? • a) 250lt or 250kg • b) 350lt or 350kg • c) 1600lt or 1600kg • d) 850lt or 850kg

20. Question 6 • What should you have an adequate supply of when you need to clean up a spill? • a) Sand • b) Water • c) vermiculite • d) inert absorbents

21. Question 7 • What is the maximum amount of 5.1 packing group I can be stored in a cabinet either inside or outside at any given time? • a) 250lt or 250kg • b) 1600lt or 1600kg • c) 50lt or 50kg • d) 900lt or 900kg

22. Question 8 • How should a packaged or IBC remain in storage? • a) Closed • b) partially open • c) on it’s side • d) open

23. Additional information • For more information on Class 5.1 products the following sources may be of assistance • Australian Dangerous Goods Code 7th Edition • Available to all DGL employees via the company’s intranet • AS 4326—2008 The storage and handling of oxidizing agents • Available to all DGL employees via the company’s intranet